Living Polymerization by Bis(phenolate) Zirconium Catalysts: Synthesis of Isotactic Polystyrene-block -Polybutadiene Copolymers

2014 ◽  
Vol 215 (20) ◽  
pp. 2001-2006 ◽  
Author(s):  
Christiane Hohberger ◽  
Thomas P. Spaniol ◽  
Jun Okuda
2021 ◽  
Author(s):  
Fang Ge ◽  
Sun Li ◽  
Zhe Wang ◽  
Wenzhong Zhang ◽  
Xiaowu Wang

Developing different synthetic approaches to realize controlled or living polymerization are aspirational to achieve polymers with defined molecular weight, narrow molecular weight distribution and unambiguous structures by polymer chemists. Herein,...


2019 ◽  
Vol 141 (25) ◽  
pp. 10039-10047 ◽  
Author(s):  
Jung-Ah Song ◽  
Bohyun Park ◽  
Soohyung Kim ◽  
Cheol Kang ◽  
Dongwhan Lee ◽  
...  

1960 ◽  
Vol 17 (180) ◽  
pp. 231-235 ◽  
Author(s):  
Hiroyuki Tadokoro ◽  
Tohru Kitazawa ◽  
Shun-ichi Nozakura ◽  
Shunsuke Murahashi

2013 ◽  
Vol 705 ◽  
pp. 115-119
Author(s):  
Bao Yong Tian ◽  
Er Jun Tang ◽  
Miao Yuan ◽  
Rui Xia Hao ◽  
Cun Man Li ◽  
...  

The well-defined block copolymer PMMA-b-PS was prepared by two-step ATRP in emulsion system. GPC results indicate that Mn increased linearly with conversion and polydispersity remained relatively narrow. It presents the characteristics of living polymerization in emulsion system. FT-IR demonstrated that block copolymer PMMA-b-PS could be successfully synthesized by ATRP with macroinitiator PMMA-Cl in emulsion system. The morphological characteristic of the self-assembly depends on the block copolymer concentration and transforms between spheres and rodlike micelles. The property indicates a perfect potential application in drug delivery materials.


Polymers ◽  
2017 ◽  
Vol 9 (12) ◽  
pp. 131 ◽  
Author(s):  
Huajin Wang ◽  
Xinwei Wang ◽  
Yanjie Sun ◽  
Hailong Cheng ◽  
Takeshi Shiono ◽  
...  

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