Living Alternating Copolymerization of a Methylenecyclopropane Derivative with CO to Afford Polyketone with Dihydrophenanthrene-1,10-diyl Groups

Daisuke Takeuchi; Takeshi Okada; Junpei Kuwabara; Kohtaro Osakada

doi:10.1002/macp.200600217

Living Alternating Copolymerization of a Methylenecyclopropane Derivative with CO to Afford Polyketone with Dihydrophenanthrene-1,10-diyl Groups

Macromolecular Chemistry and Physics ◽

10.1002/macp.200600217 ◽

2006 ◽

Vol 207 (17) ◽

pp. 1546-1555 ◽

Cited By ~ 9

Author(s):

Daisuke Takeuchi ◽

Takeshi Okada ◽

Junpei Kuwabara ◽

Kohtaro Osakada

Keyword(s):

Alternating Copolymerization

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Isospecific Alternating Copolymerization of Unprotected Polar Styrenes and Ethylene by the C Symmetric Scandium Precursor via Synergistic Effects of Two Substituent Groups

Giant ◽

10.1016/j.giant.2021.100061 ◽

2021 ◽

pp. 100061

Author(s):

Tiantian Wang ◽

Chunji Wu ◽

Baoli Wang ◽

Dongmei Cui

Keyword(s):

Synergistic Effects ◽

Alternating Copolymerization

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Chiral salenCo(iii) complexes with bulky substituents as catalysts for stereoselective alternating copolymerization of racemic propylene oxide with carbon dioxide and succinic anhydride

Polymer Chemistry ◽

10.1039/d0py01562h ◽

2021 ◽

Vol 12 (12) ◽

pp. 1776-1786

Author(s):

Zhou Wang ◽

Ying Mu

Keyword(s):

Carbon Dioxide ◽

Propylene Carbonate ◽

Propylene Oxide ◽

Succinic Anhydride ◽

Poly Propylene ◽

Alternating Copolymerization

Stereoregular poly(propylene carbonate)s and poly(propylene succinate-block-carbonate)s were synthesized with new chiral salenCo(iii) catalysts carrying bulky substituents.

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Alternating copolymerization through the complexes of conjugated vinyl monomers-alkylaluminum halides

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.1996.850 ◽

1996 ◽

Vol 34 (12) ◽

pp. 1381-1396 ◽

Cited By ~ 1

Author(s):

Masaaki Hirooka ◽

Hiroshi Yabuuchi ◽

Jiro Iseki ◽

Yasuto Nakai

Keyword(s):

Vinyl Monomers ◽

Alternating Copolymerization

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Synthesis of Chiral Functionalized Polymers by Alternating Copolymerization of Propene and CO Using the Pd(OAc)2/(S)-P-PHOS Catalyst

Chinese Journal of Catalysis ◽

10.1016/s1872-2067(10)60161-1 ◽

2011 ◽

Vol 32 (1-2) ◽

pp. 65-69 ◽

Cited By ~ 1

Author(s):

Lailai WANG ◽

Xiaojing JIA ◽

Bo WAN

Keyword(s):

Functionalized Polymers ◽

Alternating Copolymerization

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Mechanistic aspects of the alternating copolymerization of carbon monoxide with olefins catalyzed by cationic palladium complexes

Organometallics ◽

10.1021/om00041a004 ◽

1992 ◽

Vol 11 (5) ◽

pp. 1766-1769 ◽

Cited By ~ 53

Author(s):

Antonio Batistini ◽

Giambattista Consiglio

Keyword(s):

Carbon Monoxide ◽

Palladium Complexes ◽

Alternating Copolymerization ◽

Cationic Palladium

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Alternating Copolymerization of Cyclohexene Oxide and CO2 Catalyzed by Zinc Complexes with New 3-Amino-2-cyanoimidoacrylate Ligands

Advanced Synthesis & Catalysis ◽

10.1002/adsc.200505113 ◽

2005 ◽

Vol 347 (10) ◽

pp. 1325-1328 ◽

Cited By ~ 46

Author(s):

Mario Kröger ◽

Cristina Folli ◽

Olaf Walter ◽

Manfred Döring

Keyword(s):

Zinc Complexes ◽

Cyclohexene Oxide ◽

Alternating Copolymerization

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Homopolymerization and copolymerization of methyl methacrylate in the presence of complexing agents—II. On the mechanism of alternating copolymerization of methyl methacrylate and styrene in the presence of ethylaluminium sesquichloride

European Polymer Journal ◽

10.1016/0014-3057(85)90216-2 ◽

1985 ◽

Vol 21 (12) ◽

pp. 1067-1073 ◽

Cited By ~ 12

Author(s):

J Afchar-Momtaz ◽

A Polton ◽

M Tardi ◽

P Sigwalt

Keyword(s):

Methyl Methacrylate ◽

Complexing Agents ◽

Alternating Copolymerization

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Photocrosslinking of EPDM Elastomers. Photocrosslinkable Compositions

Rubber Chemistry and Technology ◽

10.5254/1.3536262 ◽

1989 ◽

Vol 62 (4) ◽

pp. 592-608 ◽

Cited By ~ 13

Author(s):

J. Hilborn ◽

B. Rånaby

Keyword(s):

Crosslinking Agent ◽

Side Reaction ◽

Uv Absorption ◽

Good Match ◽

Good Solubility ◽

Uv Emission ◽

Alternating Copolymerization

Abstract EFDM rubbers can be efficiently crosslinked using multifunctional monomers. Several factors must be taken into consideration: 1. Good solubility of the crosslinking agent in the rubber is essential. 2. It is favorable to have a mechanism of crosslinking which gives an alternating addition of rubber and crosslinking agent, as in the case of the stepwise radical thiol-ene system or alternating copolymerization of bis-maleimide with the olefinic rubber. These systems utilize each radical of the photoinitiator to form crosslinks, enhance the rate of crosslinking and prevent homopolymerization of the crosslinking agent. 3. A good match of the UV absorption of the photoinitiator, the UV transmission of the rest of the system, and the UV emission from the lamp is essential. 4. Since disproportionation of photoinitiator radicals in cage is an unwanted side reaction in the rigid rubber system, it is better to choose photoinitiators that mainly recombine to reform a photoactive molecule as before scission.

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