Reactive Compatibilization of Melt Mixed PA6/SWNT Composites: Mechanical Properties and Morphology

2005 ◽  
Vol 206 (20) ◽  
pp. 2084-2095 ◽  
Author(s):  
Arup R. Bhattacharyya ◽  
Petra Pötschke ◽  
Liane Häußler ◽  
Dieter Fischer
Keyword(s):  
Mechanical Properties ◽  
Reactive Compatibilization

Improved morphology and mechanical properties of UPA6/TPEE blends by reactive compatibilization

2017 ◽  
Vol 50 (2) ◽  
pp. 124-139 ◽  
Author(s):  
Shumin Peng ◽  
Xi Ren ◽  
Wei Zhang ◽  
Chunwang Yi ◽  
Shengpei Su ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Reactive Compatibilization ◽  
Morphology And Mechanical Properties

Compatibilization of Polypropylene/Corn Starch Plasticized with Diethanol Amine

2012 ◽  
Vol 610-613 ◽  
pp. 475-479
Author(s):  
Jia Hao Qiu ◽  
Pin Gan Song ◽  
Shen Yuan Fu ◽  
Xian Xun Ge ◽  
Bing Huang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Corn Starch ◽  
Intermolecular Hydrogen Bonding ◽  
Starch Granules ◽  
Reactive Compatibilization ◽  
Hydrogen Bonding Interactions ◽  
Potential Applications ◽  
Plasticized Starch ◽  
Reduction Effect

In the presented paper, diethanol amine is employed to plasticize corn starch, and plasticized starch is incorporated into polypropylene to create semibio-based composites with the aid of compatibilizer, maleic anhydride-grafted PP (PPMA). Compared with PP/starch blend, the presence of diethanol amine changes the morphology and increases the plasticity of starch due to the reduction effect of intermolecular hydrogen bonding interactions. Adding PPMA could reduce the dispersed size of starch granules in the polymer matrix due to in situ reactive compatibilization. Addition of 30 wt% PPMA decreases the starch granules size from ~10 μm to ~5 μm, and increases the tensile strength from 16 MPa for PP/plasticized starch to 30 MPa, increased by 87.5%. Thus, as-created bio-composites with improved mechanical properties will find many potential applications such as packaging.

scholarly journals Effect of Diisocyanates as Compatibilizer on the Properties of BF/PBAT Composites by In Situ Reactive Compatibilization, Crosslinking and Chain Extension

Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 806 ◽  
Author(s):  
Xiwei Xie ◽  
Caili Zhang ◽  
Yunxuan Weng ◽  
Xiaoqian Diao ◽  
Xinyu Song
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Phenyl Isocyanate ◽  
Chain Extension ◽  
Hydroxyl Group ◽  
Reactive Compatibilization ◽  
Carbamate Group ◽  
Bamboo Powder ◽  
Reactive Compatibilizer

Due to the hydrophobic nature of poly (butylene terephthalate) (PBAT), and the hydrophilic nature of bamboo flour (BF), a BF/PBAT (50/50) blend shows low mechanical properties, and especially shows poor impact strength. In order to increase the interfacial adhesion between BF and PBAT, diisocyanate was used as a reactive compatibilizer to modify bamboo powder. A series of BF/PBAT composites were prepared by the method of mixing and melting in an internal mixer. After adding reactive compatibilizer 4,4′-methylenebis(phenyl isocyanate) (MDI), BF/PBAT (50/50) composites with high mechanical properties were successfully prepared. The tensile strength, elongation at break, and impact strength of the BF/MDI-2/PBAT composite with 2 wt % MDI content were increased by 1.9, 6.8, and 4.3 times respectively over the BF/PBAT blend without the added MDI. The higher toughening effect of MDI in BF/PBAT composites can be mainly ascribed to the improved interface bonding between BF and PBAT. The isocyanate group of MDI can react with the hydroxyl group on the BF surface and in situ formation of the carbamate group on the BF surface. The residual isocyanate can then react with the hydroxyl group of PBAT and form carbamate groups. The rheological behaviors demonstrate that addition of appropriate amounts of MDI, 1 wt % and 2 wt %, can promote the flowability of the molten BF/PBAT composites due to the decrease in interparticle interaction between bamboo powder and the increase in the thermal motion of the molecules.

Direct Reactive Compatibilization of GMA on PE/Wood-Flour Composite

2011 ◽  
Vol 378-379 ◽  
pp. 735-739
Author(s):  
Yue Wen Li ◽  
Xin Hua Chen
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Flexural Strength ◽  
Wood Flour ◽  
Reactive Extrusion ◽  
Rupture Surface ◽  
Elongation At Break ◽  
Reactive Compatibilization ◽  
Anchoring Strength

Reactive compatibilization between high-density polyethylene(HDPE) and wood-flour was achieved via direct reactive extrusion of glycidyl methacrylate(GMA), initiator, HDPE and wood-flour. Impact rupture surface of the composite was observed by scanning electron microscope(SEM), and its load deformation temperature(HDT) and mechanical properties were tested. Effect of GMA dosage and extrusion temperature on reactive compatibilization of the composite was analysed. The result indicated that the anchoring strength of interface in the composite was obviously strengthened, and its HDT, tensile strength, flexural strength, notched impact strength and elongation at break of the composite were distinctly improved due to the addition of GMA and dicumyl peroxide(DCP). When the composite was extruded at 180°C, the peak values of its HDT, tensile strength, flexural strength, elongation at break and notched impact strength respectively were 84°C, 40Mpa, 45Mpa, 11% and 6.6KJ.m-2, which respectively increased by 17°C, 74%, 36%, 83% and 69% than that of the composite without reactive compatibilization, and when the composite was extruded at 190°C, the peak values of its HDT, tensile strength, flexural strength, elongation at break and notched impact strength respectively were 84°C, 40Mpa, 44Mpa, 11% and 6.6KJ.m-2, which respectively increased by 20°C, 60%, 26%, 83% and 83% than that of the composite without reactive compatibilization. When GMA usage increased, the HDT and mechanical properties of the composite increased first, then descended, and the optimum usage of GMA was 1wt%-3wt%.

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