Electrically Conducting Gels Formed From Polyaniline/Ethylcellulose/m-Cresol Ternary Solutions

2004 ◽  
Vol 205 (10) ◽  
pp. 1379-1384 ◽  
Author(s):  
Ignacio González ◽  
Mónica Vecino ◽  
M. Eugenia Muñoz ◽  
Anton Santamaría ◽  
J. Adolfo Pomposo
2014 ◽  
Vol 8 (1) ◽  
pp. 1457-1463
Author(s):  
Salah Abdulla Hasoon

Novel electrically conducting polymeric materials are prepared in this work. Polythiophene (PT) and poly (3-Methelthiophene) (P3MT) films were prepared by electro-polymerization method using cyclic voltammetry in acetonitrile as a solvent and lithium tetrafluoroborate as the electrolyte on a gold electrode. Electrical properties of P3MT have been examined in different environments using UV-Vis absorption spectroscopy and quantum mechanical ab initio calculations, The observed absorption peaks at 314 and 415 nm, were attributed to the n-π* and π-π* transitions, respectively in the conjugated polymer chain, in contrast, the observed absorbance peak at 649 nm, is responsible for electric conduction. The temperature dependence of the conductivity can be fitted to the Arrhenius and the VTF equations in different temperature ranges.


Author(s):  
Andre Mähringer ◽  
Markus Döblinger ◽  
Matthias Hennemann ◽  
Christoph Gruber ◽  
Dominik Fehn ◽  
...  

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Tasawar Hayat ◽  
Ikram Ullah ◽  
Ahmad Alsaedi ◽  
Shaher Momani

Abstract Our intention in this article is to investigate entropy optimization in nonlinear mixed convective unsteady magnetohydrodynamic flow of nanomaterials in porous space. An exponentially stretched sheet creates the liquid flow. Nanomaterial is considered electrically conducting. The concentration and energy expressions comprise viscous dissipation, Joule heating, thermophoresis and Brownian motion aspects. Arrhenius activation energy is considered. Computation of entropy generation based upon the second law of thermodynamics is made. Nonlinear partial expressions are obtained via suitable dimensionless variables. Resultant expressions are tackled by the OHAM technique. Features of numerous variables on entropy, temperature, velocity and concentration are graphically visualized. Skin friction and the temperature gradient at the surface are also elaborated. Comparative analysis is deliberated in tabulated form to validate the previously published outcomes. Velocity is reduced significantly via the suction parameter. The entropy rate increases for higher values of Brinkman, Biot and Hartmann numbers.


1973 ◽  
Vol 28 (9-10) ◽  
pp. 533-554 ◽  
Author(s):  
Lothar Rafflenbeul ◽  
Wa-Ming Pang ◽  
Hansjürgen Schönert ◽  
Klaus Haberle

Abstract Isopiestic vapor pressure measurements and calorimetric determination of the heat of dilution have been performed and evaluated with respect to enthalpy, entropy and free enthalpy in the ternary solutions water+ glycin+ urea and water+ alanin + urea. The free enthalpy of transfer for the process: Amino acid from water to water+ urea, which can be derived from these measurements, does not agree with the value calculated from solubility measurements. The reason for this discrepancy and the values of entropy and enthalpy in terms of hydrophobic interaction are discussed. Supplementary measurements of the proton magnetic resonance in these solutions are included.


RSC Advances ◽  
2021 ◽  
Vol 11 (14) ◽  
pp. 7873-7885
Author(s):  
Maciej Dębowski ◽  
Zbigniew Florjańczyk ◽  
Andrzej Ostrowski ◽  
Piotr A. Guńka ◽  
Janusz Zachara ◽  
...  

Electrically conducting or electroresponsive smart materials derived from newly synthesized and characterized 1D/2D (nano)particles of zinc phenylphosphates are reported.


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