Catalytic behavior in the olefin oxidation and characterization of polyacrylonitrile-palladium complexes

1994 ◽  
Vol 195 (2) ◽  
pp. 751-758 ◽  
Author(s):  
Cheng-Guo Jia ◽  
Feng-You Jin ◽  
Hui-Quan Pan ◽  
Mei-Yu Huang ◽  
Ying-Yan Jiang
Keyword(s):  
Palladium Complexes ◽  
Catalytic Behavior ◽  
Olefin Oxidation

Synthesis and Characterization of Silver and Palladium Complexes with Xanthene-Based N-Heterocyclic Carbene−Oxazoline Ligands

2010 ◽  
Vol 29 (23) ◽  
pp. 6291-6297 ◽  
Author(s):  
Takeshi Makino ◽  
Ryu Yamasaki ◽  
Isao Azumaya ◽  
Hyuma Masu ◽  
Shinichi Saito
Keyword(s):  
Palladium Complexes ◽  
Synthesis And Characterization ◽  
Oxazoline Ligands

Synthesis and Characterization of Novel PEPPSI type Pd–BICAAC Complexes

2022 ◽  
Author(s):  
Márton Nagyházi ◽  
Balázs Almási ◽  
Ádám Lukács ◽  
Attila Bényei ◽  
Tibor Nagy ◽  
...  
Keyword(s):  
High Activity ◽  
Coupling Reaction ◽  
Kinetic Studies ◽  
Elemental Mercury ◽  
Palladium Complexes ◽  
Synthesis And Characterization ◽  
Heck Coupling ◽  
Moisture Resistant

A series of bicyclic alkylamino carbenes (BICAAC) (where N-aryl = dipp, mes, 2,6-dimethyl-4-(dimethylamino)phenyl, 5a-d) and their novel air- and moisture-resistant pyridine (pyridine, 4 dimethylaminopyridine) containing palladium PEPPSI-type Pd(II) complexes (6a-e) were synthetized and characterized. The new palladium complexes have shown high activity in Mizoroki–Heck coupling reaction even at as low as 100 ppm loading (TON up to 10000). Kinetic studies revealed that reactions carried out in the presence of elemental mercury resulted in decrease in activity. It indicates that the coupling reaction may have both molecular and Pd(0)-mediated catalytic paths.

Synthesis and Solid State and Solution Characterization of Mono- and Di-(η1-C) Carbamoyl−Palladium Complexes. New Efficient Palladium-Catalyzed Routes to Carbamoyl Chlorides:  Key Intermediates to Isocyanates, Carbamic Esters, and Ureas

2000 ◽  
Vol 19 (19) ◽  
pp. 3879-3889 ◽  
Author(s):  
Michele Aresta ◽  
Potenzo Giannoccaro ◽  
Immacolata Tommasi ◽  
Angela Dibenedetto ◽  
Anna Maria Manotti Lanfredi ◽  
...  
Keyword(s):  
Solid State ◽  
Palladium Complexes ◽  
Palladium Catalyzed ◽  
Carbamic Esters
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