Stress corrosion cracking of copper in swollen bentonite simulating nuclear waste disposal environment

2020 ◽  
Vol 72 (1-2) ◽  
pp. 333-338
Author(s):  
Shinji Fujimoto ◽  
Hiroaki Tsuchiya ◽  
Soma Ogawa ◽  
Yoshihisa Iida ◽  
Naoki Taniguchi
CORROSION ◽  
1990 ◽  
Vol 46 (12) ◽  
pp. 954-963 ◽  
Author(s):  
P. S. Maiya ◽  
W. J. Shack ◽  
T. F. Kassner

2011 ◽  
Vol 110-116 ◽  
pp. 321-327
Author(s):  
Yin Jin Janin ◽  
Stuart B. Lyon ◽  
John Wintle ◽  
Briony Holmes ◽  
Chi Ming Lee

There are approximately 45,000 Intermediate Level Nuclear Waste (ILW) containers currently stored in the UK at Sellafield and elsewhere. These stainless steels containers should last up to 150 years of surface storage. In this study the general structural integrity of 500L ILW containers were investigated. The associated degradation issue under ambient conditions known as atmospheric-induced stress corrosion cracking (AISCC) has been studied. Preliminary investigation included profiling of residual stress distribution in parent and weld specimens, atmospheric exposure testing under various salts. So far residual stress profile shows high degree of complexity. No cracks have been observed until this moment in time.


Author(s):  
Poh-Sang Lam ◽  
Craig S. Stripling ◽  
Donald L. Fisher ◽  
James B. Elder

The evaporator recycle streams of nuclear waste tanks may contain waste in a chemistry and temperature regime that exceeds the current corrosion control program, which imposes temperature limits to mitigate caustic stress corrosion cracking (CSCC). A review of the recent service history found that two of these A537 carbon steel tanks were operated in highly concentrated hydroxide solution at high temperature. Visual inspections, experimental testing, and a review of the tank service history have shown that CSCC has occurred in uncooled/un-stress relieved tanks of similar construction. Therefore, it appears that the efficacy of stress relief of welding residual stress is the primary corrosion-limiting mechanism. The objective of this experimental program is to test A537 carbon steel small scale welded U-bend specimens and large welded plates (30.48 × 30.38 × 2.54 cm) in a caustic solution with upper bound chemistry (12 M hydroxide and 1 M each of nitrate, nitrite, and aluminate) and temperature (125 °C). These conditions simulate worst-case situations in these nuclear waste tanks. Both as-welded and stress-relieved specimens have been tested. No evidence of stress corrosion cracking was found in the U-bend specimens after 21 days of testing. The large plate test was completed after 12 weeks of immersion in a similar solution at 125 °C except that the aluminate concentration was reduced to 0.3 M. Visual inspection of the plate revealed that stress corrosion cracking had not initiated from the machined crack tips in the weld or in the heat affected zone. NDE ultrasonic testing also confirmed subsurface cracking did not occur. Based on these results, it can be concluded that the environmental condition of these tests was unable to develop stress corrosion cracking within the test periods for the small welded U-bends and for the large plates, which were welded with an identical procedure as used in the construction of the actual nuclear waste tanks in the 1960s. The absence of evidence of stress corrosion cracking and general corrosion in the laboratory-scaled specimens indicate that this type of nuclear waste tank is not susceptible to highly caustic solutions up to 12 M hydroxide at 125 °C when sufficient nitrite inhibitor is present.


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