Tribochemical effect of impurities in zinc dialkyldithiophosphate in engine oil

2003 ◽  
Vol 15 (4) ◽  
pp. 351-360 ◽  
Author(s):  
Xianguo Hu ◽  
Hengzhou Wo ◽  
Guopei Han ◽  
Yaling Lu
Keyword(s):  
Engine Oil ◽  
Zinc Dialkyldithiophosphate ◽  
Effect Of Impurities

Effects of phosphorus-free antioxidants on oxidation stability and high-temperature tribological properties of lubricants

2017 ◽  
Vol 231 (12) ◽  
pp. 1527-1536 ◽  
Author(s):  
Wang Liping ◽  
Zhang Dongya ◽  
Wu Hongxing ◽  
Xie Youbai ◽  
Dong Guangneng
Keyword(s):  
Tribological Properties ◽  
Ternary Complex ◽  
Oxidation Stability ◽  
Service Performance ◽  
Engine Oil ◽  
Zinc Dialkyldithiophosphate ◽  
Scanning Calorimetry ◽  
Base Oil ◽  
Hindered Phenol ◽  
Standard Tests

Oxidation stability plays an important role on the engine oil service performance. In this paper, the phosphorus-free antioxidants of diphenylamine, hindered phenol and dibutyldithiocarbamate, combined with zinc dialkyldithiophosphate were added as antioxidants in the base oil and the fully formulated 5W-30 oil, and the oxidation stabilities were evaluated by pressurized differential scanning calorimetry and Romaszewski oil bench oxidation standard tests. Meanwhile, the tribological properties of the fresh and aged oils were evaluated by a SRV tribo-meter. The results indicated that (i) an optimal ternary complex antioxidant of dibutyldithiocarbamate: diphenylamine: hindered phenol (ratio of 2:1:2) displayed good antioxidation property, and (ii) the fully formulated 5W-30 oil containing optimized ratio phosphorus-free antioxidants had better tribological properties than the commercial SN 5W-30 oil.

scholarly journals Engine Oil Degradation Induced by Biodiesel: Effect of Methyl Oleate on the Performance of Zinc Dialkyldithiophosphate

ACS Omega ◽  
2019 ◽  
Vol 4 (14) ◽  
pp. 16166-16170 ◽  
Author(s):  
Jiu Wang ◽  
Tianxi He ◽  
Chunyu Song ◽  
Xiaoqing Li ◽  
Boshui Chen
Keyword(s):  
Methyl Oleate ◽  
Engine Oil ◽  
Oil Degradation ◽  
Zinc Dialkyldithiophosphate

Influence of Chemical and Physical Contaminants on the Antiwear Performance of Model Automotive Engine Oil

2006 ◽  
Vol 220 (5) ◽  
pp. 455-462 ◽  
Author(s):  
M Masuko ◽  
A Suzuki ◽  
T Ueno
Keyword(s):  
Carbon Black ◽  
Cumene Hydroperoxide ◽  
Corrosive Wear ◽  
Engine Oil ◽  
Zinc Dialkyldithiophosphate ◽  
Chemical Contamination ◽  
Automotive Engine ◽  
Engine Oils ◽  
Carbon Soot ◽  
Chemical Contaminant

The antiwear performance of simulated used-engine-oil that contained a chemical contaminant (degraded zinc dialkyldithiophosphate (ZnDTP)) was studied with and without physical contamination (carbon black) using a four-ball tribometer. By reacting with cumene hydroperoxide, sec-C6-ZnDTP was degraded and produced many compounds containing both phosphorous and sulphur. The simulated used-oils were found to promote wear. This wear was considered to be due to corrosive wear by the excess reaction of surfaces with the sulphur contained in the degraded compounds. Carbon black was used to model carbon soot, which is another key substance of degraded engine oils, especially in diesel engines, to study the synergism between chemical contamination (ZnDTP degradation) and physical contamination (carbon soot contamination). Carbon black increased wear irrespective of the level of ZnDTP degradation, and the acceleration was much greater in the degraded oils. The wear acceleration by carbon black was observed even when the antiwear film from ZnDTP was already present on the surface. It was suggested that the wear acceleration by carbon black was due to abrasion.

Development of thickened semi-synthetic engine oil M-5z / 20 AERO for four-stroke gasoline engines aircraft piston of unmanned aerial vehicles (UAVs)

2020 ◽  
Vol 06 ◽  
pp. 44-47
Author(s):  
A.A. Moykin ◽  
◽  
A.S. Medzhibovsky ◽  
S.A. Kriushin ◽  
M.V. Seleznev ◽  
...  
Keyword(s):  
Unmanned Aerial Vehicles ◽  
Engine Oil ◽  
Motor Oil ◽  
Gasoline Engines ◽  
State Research Institute ◽  
Technical Requirements ◽  
Aerial Vehicles ◽  
State Research ◽  
Industrial Batch ◽  
The Russian Federation

Nowadays, the creation of remotely-piloted aerial vehicles for various purposes is regarded as one of the most relevant and promising trends of aircraft development. FAU "25 State Research Institute of Chemmotology of the Ministry of Defense of the Russian Federation" have studied the operation features of aircraft piston engines and developed technical requirements for motor oil for piston four-stroke UAV engines, as well as a new engine oil M-5z/20 AERO in cooperation with NPP KVALITET, LLC. Based on the complex of qualification tests, the stated operational properties of the experimental-industrial batch of M-5z/20 AERO oil are generally confirmed.

Controlling porosity and density of nanocellulose aerogels for superhydrophobic light materials

TAPPI Journal ◽  
2018 ◽  
Vol 17 (03) ◽  
pp. 145-153 ◽  
Author(s):  
Chengua Yu ◽  
Feng Wang ◽  
Shiyu Fu ◽  
Lucian Lucia
Keyword(s):  
Contact Angle ◽  
Freeze Drying ◽  
Engine Oil ◽  
High Porosity ◽  
Water Mixture ◽  
Waste Engine Oil ◽  
Hydrophobically Modified ◽  
Static Contact ◽  
Oil Water ◽  
Hydrophobic Material

A very low-density oil-absorbing hydrophobic material was fabricated from cellulose nanofiber aerogels–coated silane substances. Nanocellulose aerogels (NCA) superabsorbents were prepared by freeze drying cellulose nanofibril dispersions at 0.2%, 0.5%, 0.8%, 1.0%, and 1.5% w/w. The NCA were hydrophobically modified with methyltrimethoxysilane. The surface morphology and wettability were characterized by scanning electron microscopy and static contact angle. The aerogels displayed an ultralow density (2.0–16.7 mg·cm-3), high porosity (99.9%–98.9%), and superhydrophobicity as evidenced by the contact angle of ~150° that enabled the aerogels to effectively absorb oil from an oil/water mixture. The absorption capacities of hydrophobic nanocellulose aerogels for waste engine oil and olive oil could be up to 140 g·g-1 and 179.1 g·g-1, respectively.

DETERMINATION OF GLYCOL CONTAMINATION IN ENGINE OIL BY INFRARED AND UV-VIS SPECTROSCOPY

2018 ◽  
Author(s):  
Torrey Holland ◽  
Dennis Watson ◽  
P Sivakumar ◽  
Ali Abdul-Munaim ◽  
Robinson Karunanithy
Keyword(s):  
Engine Oil ◽  
Vis Spectroscopy
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