Characterization of the Organic Matter in Wood Ash from Biomass Power Plants in Relation to the Potential Use as Amendments in Agriculture

2017 ◽  
Vol 28 (7) ◽  
pp. 2166-2175 ◽  
Author(s):  
Agustín Merino ◽  
Beatriz Omil ◽  
Claudia Hidalgo ◽  
Jorge D. Etchevers ◽  
Miguel A. Balboa
2013 ◽  
Vol 52 (6) ◽  
pp. 296-304 ◽  
Author(s):  
E. Menéndez ◽  
A. M. Álvaro ◽  
C. Argiz ◽  
J. L. Parra ◽  
A. Moragues
Keyword(s):  

2013 ◽  
Vol 748 ◽  
pp. 304-308 ◽  
Author(s):  
Yotsakit Ruangtaweep ◽  
Nattapon Srisittipokakun ◽  
Kitipun Boonin ◽  
Patarawagee Yasaka ◽  
Jakrapong Kaewkhao

The recycling of rice straw fly ash (RSA) obtained from the biomass power plants has been studied. RSA was calcined at 400, 600, 800 and 1,000 °C for 3 h and investigated their compositions and structures by X-rays fluorescence spectrometer (XRF) and X-rays diffractometer (XRD) respectively. The results show that, the major compositions of RSA are SiO2 and CaO, MgO, K2O and P2O5. The XRD patterns exhibited the peak of sylvite potassium chloride phase (KCl) up to 600 °C. Since 800 °C tridymite phase SiO2 was obtained and the KCl phase was disappeared. The glasses from RSA (RSA-glass) were prepared by melt-quenched technique and investigated their optical and physical properties, compared with the glass prepared from high purity SiO2 (SiO2-glass) using the same glass formula and preparation conditions. The density and refractive index of the RSA-glass were higher than SiO2-glasses. Similar optical absorption spectra of both glasses were obtained. In addition the shoulder peak were appeared at 450 nm due to Fe3+ ion from contamination in RSA.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Andreea Baricz ◽  
Erika A. Levei ◽  
Marin Șenilă ◽  
Simona Cîntă Pînzaru ◽  
Mihaela Aluaş ◽  
...  

AbstractIn this study we aimed to compare the mineralogical, thermal, physicochemical, and biological characteristics of recent organic carbon-rich sediments (‘sapropels’) from three geographically distant Romanian lakes (Tekirghiol and Amara, SE Romania, and Ursu, Central Romania) with distinct hydrogeochemical origins, presently used for pelotherapy. The investigated lakes were classified as inland brackish Na-Cl-sulfated type (Amara), coastal moderately saline and inland hypersaline Na-Cl types (Tekirghiol and Ursu, respectively). The settled organic matter is largely composed of photosynthetic pigments derived from autochthonous phytoplankton. Kerogen was identified in the sapropel of coastal Tekirghiol Lake suggesting its incipient maturation stage. The mineral composition was fairly similar in all sapropels and mainly consisted of quartz, calcite, and aragonite. Smectite, illite, mixed layer smectite/illite appeared as major clay components. Potentially toxic elements were found in low concentrations. The physical properties (i.e., specific heat, thermal conductivity and retentivity) and cation exchange capacity are comparable to other peloids used for therapy. This study is the first comprehensive multi-approached investigation of the geochemical nature of recent sapropels in Romanian saline lakes and thus contributes to expanding our knowledge on the origin and physicochemical qualities of organic matter-rich peloids with therapeutic uses.


2021 ◽  
Vol 14 (1) ◽  
pp. 99
Author(s):  
Karine Dufossé ◽  
Marine Marie-Charlotte ◽  
Vincent Augiseau ◽  
Thierry Henrion ◽  
Hayet Djelal

The increasing demand for energy is leading to the increasing use of renewable resources, such as biomass, resulting in the significant development of the wood energy sector in recent years. On the one hand, and to a certain extent, the sector has generated many benefits. On the other hand, the challenges related to wood ash (WA) management such as increasing tonnages, landfilling, restrictive regulations for reuse, etc., have been weighing more heavily in the debate related to the wood energy sector. However, all studies have assumed that no environmental impacts can be attributed to WA production. This study aims at discussing this assumption, whether the WA is a waste or a co-product of heat generation. In the first place, WA deposits were estimated using the biomass database and ash content from the literature regarding the collective, industrial and tertiary biomass power plants (BPP) in the French region of Brittany. Then, the impacts of the generated WA were estimated using the attributional life cycle assessment (LCA) method through two different impact allocation procedures (IAP), “from cradle to gate” (excluding the waste treatment). In Brittany, for the year 2017, an estimated amount of 2.8 to 8.9 kilotons of WA was generated, and this production should increase to 5 to 15.7 kilotons by 2050. The LCA conducted through this study gave an emission of 38.6 g CO2eq /kW h, with a major contribution from the production of the wood chips. Considering the environmental aspect, the IAP analysis indicated that energy and economic allocations were not relevant, and that, using the mass allocation, the environmental production of WA could represent 1.3% of the impacts of the combustion process in BPP. Therefore, WA, and especially the fly ash, can be considered as a waste from BPP heat production, without any environmental impact attributed to its generation.


2010 ◽  
Vol 59 (1) ◽  
pp. 99-108 ◽  
Author(s):  
M. Takács ◽  
Gy. Füleky

The Hot Water Percolation (HWP) technique for preparing soil extracts has several advantages: it is easily carried out, fast, and several parameters can be measured from the same solution. The object of this study was to examine the possible use of HWP extracts for the characterization of soil organic matter. The HPLC-SEC chromatograms, UV-VIS and fluorescence properties of the HWP extracts were studied and the results were compared with those of the International Humic Substances Society (IHSS) Soil Humic Acid (HA), IHSS Soil Fulvic Acid (FA) and IHSS Suwannee Natural Organic Matter (NOM) standards as well as their HA counterparts isolated by traditional extraction methods from the original soil samples. The DOM of the HWP solution is probably a mixture of organic materials, which have some characteristics similar to the Soil FA fractions and NOM. The HWP extracted organic material can be studied and characterized using simple techniques, like UV-VIS and fluorescence spectroscopy.


Agronomy ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1067
Author(s):  
Aleksandra Ukalska-Jaruga ◽  
Romualda Bejger ◽  
Guillaume Debaene ◽  
Bożena Smreczak

The objective of this paper was to investigate the molecular characterization of soil organic matter fractions (humic substances (HS): fulvic acids-FAs, humic acids-HAs, and humins-HNs), which are the most reactive soil components. A wide spectrum of spectroscopic (UV–VIS and VIS–nearIR), as well as electrochemical (zeta potential, particle size diameter, and polydispersity index), methods were applied to find the relevant differences in the behavior, formation, composition, and sorption properties of HS fractions derived from various soils. Soil material (n = 30) used for the study were sampled from the surface layer (0–30 cm) of agricultural soils. FAs and HAs were isolated by sequential extraction in alkaline and acidic solutions, according to the International Humic Substances Society method, while HNs was determined in the soil residue (after FAs and HAs extraction) by mineral fraction digestion using a 0.1M HCL/0.3M HF mixture and DMSO. Our study showed that significant differences in the molecular structures of FAs, Has, and HNs occurred. Optical analysis confirmed the lower molecular weight of FAs with high amount of lignin-like compounds and the higher weighted aliphatic–aromatic structure of HAs. The HNs were characterized by a very pronounced and strong condensed structure associated with the highest molecular weight. HAs and HNs molecules exhibited an abundance of acidic, phenolic, and amine functional groups at the aromatic ring and aliphatic chains, while FAs mainly showed the presence of methyl, methylene, ethenyl, and carboxyl reactive groups. HS was characterized by high polydispersity related with their structure. FAs were characterized by ellipsoidal shape as being associated to the long aliphatic chains, while HAs and HNs revealed a smaller particle diameter and a more spherical shape caused by the higher intermolecular forcing between the particles. The observed trends directly indicate that individual HS fractions differ in behavior, formation, composition, and sorption properties, which reflects their binding potential to other molecules depending on soil properties resulting from their type. The determined properties of individual HS fractions are presented as averaged characteristics over the examined soils with different physico-chemical properties.


Sign in / Sign up

Export Citation Format

Share Document