An evaluation of the combined application of hammett reaction constant and primary kinetic isotope effects to hydride equivalent transfer reactions

R. Srinivasan

doi:10.1002/kin.550240806

An evaluation of the combined application of hammett reaction constant and primary kinetic isotope effects to hydride equivalent transfer reactions

International Journal of Chemical Kinetics ◽

10.1002/kin.550240806 ◽

1992 ◽

Vol 24 (8) ◽

pp. 727-734

Author(s):

R. Srinivasan

Keyword(s):

Isotope Effects ◽

Kinetic Isotope Effects ◽

Transfer Reactions ◽

Combined Application ◽

Kinetic Isotope ◽

Reaction Constant

Download Full-text

Interpretation of Primary Kinetic Isotope Effects for Adiabatic and Nonadiabatic Proton-Transfer Reactions in a Polar Environment

Isotope Effects In Chemistry and Biology ◽

10.1201/9781420028027.ch21 ◽

2005 ◽

pp. 549-578 ◽

Cited By ~ 3

Author(s):

Philip Kiefer ◽

James Hynes

Keyword(s):

Proton Transfer ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Transfer Reactions ◽

Kinetic Isotope ◽

Polar Environment ◽

Proton Transfer Reactions

Download Full-text

Substituent Effects on Temperature Dependence of Kinetic Isotope Effects in Hydride-Transfer Reactions of NADH/NAD+ Analogues in Solution: Reaction Center Rigidity Is the Key

Organic Letters ◽

10.1021/acs.orglett.0c02049 ◽

2020 ◽

Vol 22 (15) ◽

pp. 5963-5967

Author(s):

Peter Maness ◽

Shailendra Koirala ◽

Pratichhya Adhikari ◽

Nasim Salimraftar ◽

Yun Lu

Keyword(s):

Temperature Dependence ◽

Reaction Center ◽

Isotope Effects ◽

Substituent Effects ◽

Hydride Transfer ◽

Kinetic Isotope Effects ◽

Transfer Reactions ◽

Kinetic Isotope ◽

Solution Reaction ◽

Hydride Transfer Reactions

Download Full-text

Ab initio predictions and experimental confirmation of large tunneling contributions to rate constants and kinetic isotope effects for hydrogen atom transfer reactions

Journal of the American Chemical Society ◽

10.1021/ja00272a061 ◽

1986 ◽

Vol 108 (12) ◽

pp. 3515-3516 ◽

Cited By ~ 51

Author(s):

Bruce C. Garrett ◽

Donald G. Truhlar ◽

Joel M. Bowman ◽

Albert F. Wagner ◽

Daniel. Robie ◽

...

Keyword(s):

Hydrogen Atom ◽

Ab Initio ◽

Rate Constants ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Hydrogen Atom Transfer ◽

Experimental Confirmation ◽

Transfer Reactions ◽

Atom Transfer ◽

Kinetic Isotope

Download Full-text

ChemInform Abstract: KINETIC ISOTOPE EFFECTS FOR NITROALKANES AND THEIR RELATIONSHIP TO TRANSITION-STATE STRUCTURE IN PROTON-TRANSFER REACTIONS

Chemischer Informationsdienst ◽

10.1002/chin.197534129 ◽

1975 ◽

Vol 6 (34) ◽

pp. no-no

Author(s):

F. G. BORDWELL ◽

WILLIAM J. JUN. BOYLE

Keyword(s):

Proton Transfer ◽

Transition State ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Transfer Reactions ◽

State Structure ◽

Transition State Structure ◽

Kinetic Isotope ◽

Proton Transfer Reactions

Download Full-text

Kinetic isotope effects for nitroalkanes and their relation to transition-state structure in proton-transfer reactions

Journal of the American Chemical Society ◽

10.1021/ja00845a028 ◽

1975 ◽

Vol 97 (12) ◽

pp. 3447-3452 ◽

Cited By ~ 49

Author(s):

F. G. Bordwell ◽

William J. Boyle

Keyword(s):

Proton Transfer ◽

Transition State ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Transfer Reactions ◽

State Structure ◽

Transition State Structure ◽

Kinetic Isotope ◽

Proton Transfer Reactions

Download Full-text

Does the pressure dependence of kinetic isotope effects report usefully on dynamics in enzyme H‐transfer reactions?

FEBS Journal ◽

10.1111/febs.13193 ◽

2015 ◽

Vol 282 (16) ◽

pp. 3243-3255 ◽

Cited By ~ 6

Author(s):

Robin Hoeven ◽

Derren J. Heyes ◽

Sam Hay ◽

Nigel S. Scrutton

Keyword(s):

Pressure Dependence ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Transfer Reactions ◽

Kinetic Isotope

Download Full-text

Steric Effects on the Primary Isotope Dependence of Secondary Kinetic Isotope Effects in Hydride Transfer Reactions in Solution: Caused by the Isotopically Different Tunneling Ready State Conformations?

Journal of the American Chemical Society ◽

10.1021/jacs.5b03085 ◽

2015 ◽

Vol 137 (20) ◽

pp. 6653-6661 ◽

Cited By ~ 11

Author(s):

Binita Maharjan ◽

Mahdi Raghibi Boroujeni ◽

Jonathan Lefton ◽

Ormacinda R. White ◽

Mortezaali Razzaghi ◽

...

Keyword(s):

Isotope Effects ◽

Hydride Transfer ◽

Kinetic Isotope Effects ◽

Transfer Reactions ◽

Steric Effects ◽

Kinetic Isotope ◽

Hydride Transfer Reactions

Download Full-text

Kinetic Isotope Effects for Proton-Coupled Electron Transfer Reactions

ChemInform ◽

10.1002/chin.200631263 ◽

2006 ◽

Vol 37 (31) ◽

Cited By ~ 2

Author(s):

Sharon Hammes-Schiffer

Keyword(s):

Electron Transfer ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Proton Coupled Electron Transfer ◽

Kinetic Isotope

Download Full-text

ChemInform Abstract: PROTON-TRANSFER REACTIONS. 4. NEAR-UNITY KINETIC ISOTOPE EFFECTS FOR HYDRON EXCHANGE AND DEHYDROFLUORINATION REACTIONS

Chemischer Informationsdienst ◽

10.1002/chin.198331123 ◽

1983 ◽

Vol 14 (31) ◽

Author(s):

H. F. KOCH ◽

D. B. DAHLBERG ◽

G. LODDER ◽

K. S. ROOT ◽

N. A. TOUCHETTE ◽

...

Keyword(s):

Proton Transfer ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Transfer Reactions ◽

Kinetic Isotope ◽

Proton Transfer Reactions

Download Full-text

Solvent effects on the temperature dependence of the primary kinetic isotope effects for hydride transfer reactions in solution

10.1021/scimeetings.0c05537 ◽

2020 ◽

Author(s):

Pratichhya Adhikari ◽

Shailendra Koirala

Keyword(s):

Temperature Dependence ◽

Solvent Effects ◽

Isotope Effects ◽

Hydride Transfer ◽

Kinetic Isotope Effects ◽

Transfer Reactions ◽

Kinetic Isotope ◽

Hydride Transfer Reactions

Download Full-text