A kinetic study of the autocatalytic permanganate oxidation of formic acid

1990 ◽  
Vol 22 (3) ◽  
pp. 261-287 ◽  
Author(s):  
Joaquin F. Perez-Benito ◽  
Conchita Arias ◽  
Enrique Brillas
Keyword(s):  
Formic Acid ◽  
Kinetic Study ◽  
Permanganate Oxidation

ChemInform Abstract: A Kinetic Study of the Autocatalytic Permanganate Oxidation of Formic Acid.

ChemInform ◽  
1990 ◽  
Vol 21 (25) ◽  
Author(s):  
J. F. PEREZ-BENITO ◽  
C. ARIAS ◽  
E. BRILLAS
Keyword(s):  
Formic Acid ◽  
Kinetic Study ◽  
Permanganate Oxidation

Kinetic study of the photo-Fenton degradation of formic acid

2009 ◽  
Vol 144 (1-2) ◽  
pp. 117-123 ◽  
Author(s):  
Jorgelina Farias ◽  
Enrique D. Albizzati ◽  
Orlando M. Alfano
Keyword(s):  
Formic Acid ◽  
Kinetic Study

Kinetics of the permanganate oxidation of formic acid in aqueous solution

1987 ◽  
Vol 19 (8) ◽  
pp. 741-755 ◽  
Author(s):  
Isidro S. Monzó ◽  
Juan Palou ◽  
Joaquín Peñalver ◽  
Rosa Valero
Keyword(s):  
Aqueous Solution ◽  
Formic Acid ◽  
Permanganate Oxidation ◽  
Kinetics Of

scholarly journals Theoretical kinetic study of the formic acid catalyzed Criegee intermediate isomerization: multistructural anharmonicity and atmospheric implications

2018 ◽  
Vol 20 (16) ◽  
pp. 10806-10814 ◽  
Author(s):  
M. Monge-Palacios ◽  
Matti P. Rissanen ◽  
Zhandong Wang ◽  
S. Mani Sarathy
Keyword(s):  
Carbon Atom ◽  
Formic Acid ◽  
Kinetic Study ◽  
Theoretical Study ◽  
Isomerization Reaction ◽  
Hydrogen Shift ◽  
Acid Catalyzed ◽  
Double Hydrogen

We performed a theoretical study on the double hydrogen shift isomerization reaction of a six carbon atom Criegee intermediate (C6-CI), catalyzed by formic acid (HCOOH), to produce vinylhydroperoxide (VHP), C6-CI + HCOOH → VHP + HCOOH.

A kinetic study of the reaction between formic acid and HoBr

1982 ◽  
Vol 14 (5) ◽  
pp. 479-485 ◽  
Author(s):  
M. A. Brusa ◽  
A. J. Colussi
Keyword(s):  
Formic Acid ◽  
Kinetic Study

Reductive Kinetic Study of Oxidized Cu Surface by Catalyzed Formic Acid Vapor

2016 ◽  
Author(s):  
P.W. Chou ◽  
J.M. Song ◽  
M. Akaike ◽  
M. Fujino ◽  
T. Suga ◽  
...  
Keyword(s):  
Formic Acid ◽  
Kinetic Study ◽  
Acid Vapor

THE ISOBUTYL GROUP IN SPRUCE AND BIRCH LIGNINS

1949 ◽  
Vol 27b (6) ◽  
pp. 572-579 ◽  
Author(s):  
Alan Bell ◽  
George F Wright
Keyword(s):  
Acetic Acid ◽  
Formic Acid ◽  
Hydroxyl Group ◽  
Acid Extraction ◽  
Acid Extract ◽  
Permanganate Oxidation ◽  
Perbenzoic Acid ◽  
Acetic Acid Extraction ◽  
Acid Titration

Acetone has been isolated by permanganate oxidation of birch and spruce lignins extracted from wood by acetic or formic acid. Acetone was obtained also when the formic acid lignins were ozonized but not from the acetic acid – extracted lignins. This difference was confirmed when perbenzoic acid titration indicated unsaturation in the formic acid extract which was not present in the acetic acid extract. It is suggested that an α-hydroxy-β-methoxyisobutyl group is present in lignin; during acetic acid extraction the hydroxyl group is acetylated but during formic acid extraction the formic acid reduces the group to isobutenyl, which will give acetone when it is ozonized.

Sign in / Sign up

Export Citation Format

Share Document