Kinetics and mechanism of the alkali metal ions promoted electron transfer between 12-tungstocobaltate(III) and citric acid

1988 ◽  
Vol 20 (9) ◽  
pp. 699-712 ◽  
Author(s):  
Swapan K. Saha ◽  
Manik C. Ghosh ◽  
Pradyot Banerjee
Keyword(s):  
Electron Transfer ◽  
Citric Acid ◽  
Alkali Metal ◽  
Metal Ions ◽  
Kinetics And Mechanism ◽  
Alkali Metal Ions

The Formation of Fluorescent Alkali Metal and Alkaline Earth Complexes by 1-(2-{10-[2-Piperazinoethyl]-9-anthryl}ethyl)piperazine and Alkaline Earth Complexes by 4-(2-{10-[2-(1,4-Thiazinan-4-yl)ethyl]-9-anthryl}ethyl)thiomorpholine in Acetonitrile

2003 ◽  
Vol 56 (9) ◽  
pp. 917 ◽  
Author(s):  
Jason P. Geue ◽  
Nicholas J. Head ◽  
A. David Ward ◽  
Stephen F. Lincoln
Keyword(s):  
Electron Transfer ◽  
Quantum Yield ◽  
Alkali Metal ◽  
Metal Ions ◽  
Photoinduced Electron Transfer ◽  
Alkaline Earth ◽  
Alkali Metal Ions ◽  
Sandwich Complex ◽  
Complexation Constant ◽  
Typical Data

The formation of fluorescent alkali metal and alkaline earth complexes of 1-(2-{10-[2-piperazinoethyl]-9-anthryl}ethyl)piperazine (1) and alkaline earth complexes by 4-(2-{10-[2-(1,4-thiazinan-4-yl)ethyl]-9-anthryl}ethyl)thiomorpholine (2) in acetonitrile is reported. Both (1) and (2) have ‘fluorophore–spacer–receptor’ structures in the sequences ‘anthracene–dimethylene–piperazine’ and ‘anthracene–dimethylene–thiomorpholine’, respectively. Complexation by alkali metal ions and alkaline earth ions, Mm+, modulate photoinduced electron transfer (PET) to increase the fluorescence of (1) and complexation of alkaline earth ions similarly increases the fluorescence of (2). The two receptors of (1) and (2) may either complex Mm+ singly to form [ML]m+ or cooperatively to form a ‘sandwich’ complex [ML′]m+ characterized together by complexation constant K1 and quantum yield φ1. They may also complex two Mm+ in [M2L]2m+ characterized by K2 and φ2. Typical data are exemplified for (1) and Mm+ = Na+ by K1 = 1.33 × 105 dm3 mol–1 (φ1 = 0.02) and K2 = 4.20 × 102 dm3 mol–1 (φ1 = 0.07), for (1) and Mm+ = Ca2+ by K1 = 3.2 × 106 dm3 mol–1 (φ1 = 0.34) and K2 = 1.32 × 104 dm3 mol–1 (φ2 = 0.54), and for (2) and Mm+ = Ca2+ by K1 = 2.29 × 104 dm3 mol–1 (φ1 = 0.20) and K2 = 8.0 × 102 dm3 mol–1 (φ2 = 0.57) at 298.2 K and I = 0.05 mol dm–3 (NEt4ClO4). These data are compared with those for the alkaline earth complexes of 4-{2-[10-(2-morpholinoethyl)-9-anthryl]ethyl}morpholine. In 40 : 60 (v/v) 1,4-dioxan/water, protonation modulates PET to increase the fluorescence of (1)H44+ and (2)H22+. (The pKa values of (1)H44+ are 9.02, 8.06, 4.32, and 2.96 at 298.2 K and I = 0.05 mol dm–3 (NEt4ClO4).) The syntheses of (1) and (2) are reported.

Activating Inert Alkali-Metal Ions by Electron Transfer from Manganese Oxide for Formaldehyde Abatement

2017 ◽  
Vol 24 (3) ◽  
pp. 681-689 ◽  
Author(s):  
Jiayi Gao ◽  
Zhiwei Huang ◽  
Yaxin Chen ◽  
Jing Wan ◽  
Xiao Gu ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Alkali Metal ◽  
Metal Ions ◽  
Manganese Oxide ◽  
Alkali Metal Ions
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