Kinetics of the oxidation of U (IV) by hydrogen peroxide in sulfuric acid medium

1981 ◽  
Vol 13 (4) ◽  
pp. 385-401 ◽  
Author(s):  
P. K. Bhattacharyya ◽  
R. D. Saini ◽  
P. B. Ruikar
1967 ◽  
Vol 39 (6) ◽  
pp. 600-605 ◽  
Author(s):  
Robert L. Habig ◽  
Harry L. Pardue ◽  
James B. Worthington

1985 ◽  
Vol 40 (4) ◽  
pp. 368-372 ◽  
Author(s):  
H. D. Försterling ◽  
H. J. Lamberz ◽  
H. Schreiber

The reaction of Ce3+ with BrO2 in sulfuric acid solution (which is the starting step in the inorganic reaction subset of the Belousov-Zhabotinsky-reaction) is followed spectroscopically in a reaction mixture containing BrO2 at constant concentration. From first order kinetics (Br02 in excess) the rate constant for this reaction is evaluated.


2021 ◽  
Vol 5 (3) ◽  
pp. 52
Author(s):  
Gerardo León ◽  
Beatriz Miguel ◽  
Laura Manzanares ◽  
María Isabel Saavedra ◽  
María Amelia Guzmán

The effect of ultrasound on the degradation of the dye Acid Brown 83 by seven different degradation methods (blank test using only ultrasound, hydrogen peroxide in a neutral medium, hydrogen peroxide in a sulfuric acid medium and hydrogen peroxide in a sulfuric acid medium in the presence of Fe(II), both without and with ultrasonic irradiation) is studied in this paper. The effectiveness of these methods is compared by analyzing the degradation percentages of the dye and its initial degradation rate. The application of ultrasound leads to a significant increase in the efficiency of any of the degradation method studied. Kinetic study of Acid Brown 83 degradation by the above-mentioned methods is carried out by using four kinetic models (first order, second order, Behnajady and pseudo-first order). The pseudo-first order model is the one that best fits the experimental data in all the used degradation methods. Although when the degradation is performed in the presence of Fe(II), the Behnajady model presents correlation coefficients slightly higher than those of the pseudo-first order, the maximum experimental conversions obtained fit much better in all cases to the pseudo first order model.


2014 ◽  
Vol 150 ◽  
pp. 167-172 ◽  
Author(s):  
Liangshi Wang ◽  
Ying Yu ◽  
Xiaowei Huang ◽  
Feng Hu ◽  
Jinshi Dong ◽  
...  

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