The very-low-pressure study of the kinetics and equilibrium: Cl + CH4 ? CH3 + HCl at 298 K. The heat of formation of the CH3 radical

1979 ◽  
Vol 11 (2) ◽  
pp. 147-154 ◽  
Author(s):  
Mohammad H. Baghal-Vayjooee ◽  
Agustin J. Colussi ◽  
Sidney W. Benson
Author(s):  
L.H. Bolz ◽  
D.H. Reneker

The attack, on the surface of a polymer, by the atomic, molecular and ionic species that are created in a low pressure electrical discharge in a gas is interesting because: 1) significant interior morphological features may be revealed, 2) dielectric breakdown of polymeric insulation on high voltage power distribution lines involves the attack on the polymer of such species created in a corona discharge, 3) adhesive bonds formed between polymer surfaces subjected to such SDecies are much stronger than bonds between untreated surfaces, 4) the chemical modification of the surface creates a reactive surface to which a thin layer of another polymer may be bonded by glow discharge polymerization.


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