Theoretical and experimental studies of the kinetics of the reaction of 1‐chloropropane and fully deuterated 1‐chloropropane with atomic chlorine

2021 ◽  
Author(s):  
Łukasz Fojcik ◽  
Dariusz S. Sarzyński ◽  
Andrzej Dryś ◽  
Zdzisław Latajka
Keyword(s):  
Experimental Studies ◽  
Kinetics Of ◽  
Atomic Chlorine

Kinetics of hypso anhydrites dissolution in water. Experimental studies

2019 ◽  
pp. 93-96
Author(s):  
A. L. Lebedev ◽  
I. V. Avilina
Keyword(s):  
Experimental Data ◽  
Experimental Study ◽  
Riccati Equation ◽  
Balance Equation ◽  
Experimental Studies ◽  
Common Ion ◽  
The Common ◽  
Common Ion Effect ◽  
Kinetics Of Dissolution ◽  
Kinetics Of

Experimental study of kinetics of dissolution of hypso anhydrites at 25 ᵒC made it possible to formulate model of the process in the form of a balance equation for the kinetics of dissolution of gypsum, anhydrite (first and second orders, respectively) and kinetics of precipitation of gypsum (second order). The processing of the experimental data were carried out on the basis of the solution of the Riccati equation. When taking into account the common-ion effect on the solubility of gypsum and anhydrite, the calculated values turned out to be more comparable with the experimental ones.

Kinetics study of spreading processes of epoxy binders on carbon cloth surface with metal coating

2021 ◽  
Vol 0 (3) ◽  
pp. 34-38
Author(s):  
D.E. Grechushkina ◽  
◽  
V.A. Nelyub ◽  
Keyword(s):  
Considerable Increase ◽  
Experimental Studies ◽  
Copper Coating ◽  
Metal Coating ◽  
Carbon Cloth ◽  
Kinetics Study ◽  
Carbon Tape ◽  
Epoxy Binders ◽  
Kinetics Of ◽  
Spreading Processes

The results of experimental studies of kinetics of spreading processes of epoxy binders on the surface of a carbon (cloth) tape depending on a reinforcement pattern are presented. A copper coating of 100 nm thickness was deposited on reinforced materials by magnetron sputtering. It has been found out that a metal coating on the surface of a carbon tape and cloth leads to a considerable increase in the rate of spreading processes only for the laying-out pattern 0°, when binder movement in capillaries is provided. The deposition of a copper coating on the surface of the carbon tape and cloth has considerably the bigger influence on kinetics of the spreading processes, increasing it by 35%.

Cooling of Fruit with Arbitrary Shape: Simulation Using Galerkin-Based Integral Method

2017 ◽  
Vol 10 ◽  
pp. 1-15
Author(s):  
P. Morais Pessôa ◽  
A.G. Barbosa de Lima ◽  
R. Swarnakar ◽  
J.P. Gomes ◽  
W.M.P. Barbosa de Lima
Keyword(s):  
Integral Method ◽  
Arbitrary Shape ◽  
Heat Conduction Equation ◽  
Low Cost ◽  
Experimental Studies ◽  
Volume Ratio ◽  
Transient Heat Conduction ◽  
Cooling Time ◽  
Time Required ◽  
Kinetics Of

Cooling has been used for the preservation of fresh produce such as fruit and vegetables due to its low cost and high effectiveness in maintaining the product quality. Recently, several researchers have conducted theoretical and experimental studies for obtaining the kinetics of cooling and cooling time for fruits with different geometries. Present work, therefore, aims to simulate the cooling of fruits with particular reference to banana, orange, strawberry and Tahiti lemon. The transient heat conduction equation and its analytical solution using Galerkin based integral method are presented. It has been found that the strawberry has lower dimensionless cooling time compared with time required to cool other fruits, which is due to its higher surface area/volume ratio value. In orange and lemon the temperature distribution was found to be homogeneous in the angular direction, while in banana and strawberry it was two-dimensional due to shape of the fruits.

Application of Galvanic Zinc-Iron Coating in the Repair of Transport and Technological Machines

2021 ◽  
Vol 1022 ◽  
pp. 181-193
Author(s):  
Dmitry M. Rozhkov ◽  
Evgenia V. Eltoshkina ◽  
Petr I. Ilyin ◽  
Olga A. Svirbutovich
Keyword(s):  
Experimental Studies ◽  
Iron Alloy ◽  
Resource Saving ◽  
Experimental Base ◽  
Optimal Resource ◽  
Iron Coating ◽  
Saving Mode ◽  
Relationship Of ◽  
The Relationship ◽  
Kinetics Of

The article presents the results of experimental studies to determine the relationship between the electrolysis modes and the properties of electroplating coatings for mathematical modeling of the dynamics of the electrolytic process (MDEP), described by a system of ordinary differential equations due to the complex relationship of the kinetics of chemical reactions, hydrodynamics and mass transfer in the electrolyte flow, the kinematics of electrode plates, and the influence of the electric field of the "anode-cathode" pair on all these processes. At the same time, the experimental base was a series of full-scale experiments to restore the seats of the root supports of cylinder blocks with electroplated coatings. The final result of the research is the procedure for constructing an optimal resource-saving mode of electroplating, which is a zinc-iron alloy.

KINETICS OF EVAPORATION OF A MODEL SOLUTION OF DISTILLERY DREGS CONTAINING PROTEIN, OIL AND SUGAR

2021 ◽  
Author(s):  
А.С. ДАНИЛЬЧЕНКО ◽  
Т.Г. КОРОТКОВА ◽  
С.Ю. КСАНДОПУЛО
Keyword(s):  
Evaporation Rate ◽  
Experimental Studies ◽  
Petri Dish ◽  
Model Solution ◽  
Soluble Carbohydrates ◽  
Drying Process ◽  
Sugar Water ◽  
Oil Water ◽  
Drying Model ◽  
Kinetics Of

Рассмотрена кинетика сушки послеспиртовой барды при 60°С. Объектом исследований была модельная смесь, состоящая из воды, белков, жиров и растворимых углеводов. Представлены результаты исследований кинетики испарения воды и смесей вода–масло, вода–белок, вода–сахар, вода–масло–белок–сахар, помещенных в чашку Петри. Процесс испарения в изотермических условиях протекал в сушильном шкафу Memmert. Установлено, что добавление вещества в воду снижает скорость испарения воды в периоде постоянной скорости сушки, в периоде падающей скорости сушки продолжительность испарения возрастает. По результатам кинетики сушки модельных смесей можно определять коэффициенты активности компонентов и проводить исследование процесса сушки реальных смесей при проектировании сушилок. The kinetics of drying of the distillery dregs at 60°C is considered. The model mixture containing water, proteins, oils and soluble carbohydrates was the object of research. The results of experimental studies of the kinetics of evaporation of water and mixtures of water-oil, water-protein, water-sugar, water-oil-protein-sugar, placed in a Petri dish, are presented. Evaporation under isothermal conditions was carried out in a Memmert drying cabinet. It is established that the addition of the substance into the water reduces the evaporation rate of water in the period of constant drying speed, the duration of evaporation in the period of falling drying speed increases. According to the results of the kinetics of drying model mixtures, it is possible to determine the activity coefficients of the components and conduct a study of the drying process of real mixtures in the design of dryers.

scholarly journals New chemical scheme for giant planet thermochemistry

2020 ◽  
Vol 634 ◽  
pp. A78 ◽  
Author(s):  
O. Venot ◽  
T. Cavalié ◽  
R. Bounaceur ◽  
P. Tremblin ◽  
L. Brouillard ◽  
...  
Keyword(s):  
Experimental Studies ◽  
Giant Planet ◽  
Brown Dwarfs ◽  
Planetary Atmospheres ◽  
Atmospheric Composition ◽  
Planetary Formation ◽  
Hot Jupiters ◽  
Chemical Scheme ◽  
High Level ◽  
Kinetics Of

Context. Several chemical networks have been developed to study warm (exo)planetary atmospheres. The kinetics of the reactions related to the methanol chemistry included in these schemes have been questioned. Aims. The goal of this paper is to update the methanol chemistry for such chemical networks based on recent publications in the combustion literature. We also aim to study the consequences of this update on the atmospheric compositions of (exo)planetary atmospheres and brown dwarfs. Methods. We performed an extensive review of combustion experimental studies and revisited the sub-mechanism describing methanol combustion in a scheme published in 2012. The updated scheme involves 108 species linked by a total of 1906 reactions. We then applied our 1D kinetic model with this new scheme to the case studies HD 209458b, HD 189733b, GJ 436b, GJ 1214b, ULAS J1335+11, Uranus, and Neptune; we compared these results with those obtained with the former scheme. Results. The update of the scheme has a negligible impact on the atmospheres of hot Jupiters. However, the atmospheric composition of warm Neptunes and brown dwarfs is modified sufficiently to impact observational spectra in the wavelength range in which James Webb Space Telescope will operate. Concerning Uranus and Neptune, the update of the chemical scheme modifies the abundance of CO and thus impacts the deep oxygen abundance required to reproduce the observational data. For future 3D kinetics models, we also derived a reduced scheme containing 44 species and 582 reactions. Conclusions. Chemical schemes should be regularly updated to maintain a high level of reliability on the results of kinetic models and be able to improve our knowledge of planetary formation.

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