Interference by Nitrous Acid Decomposition in the Kinetic Study of Nitrosation Reactions

2014 ◽  
Vol 46 (6) ◽  
pp. 321-327 ◽  
Author(s):  
Jorge Arenas-Valgañón ◽  
Rafael Gómez-Bombarelli ◽  
Marina González-Pérez ◽  
Mario González-Jiménez ◽  
Emilio Calle ◽  
...  
Keyword(s):  
Kinetic Study ◽  
Nitrous Acid ◽  
Acid Decomposition ◽  
Nitrosation Reactions

A kinetic study of phenol nitration and nitrosation with nitrous acid in the dark

2004 ◽  
Vol 2 (3) ◽  
pp. 135-139 ◽  
Author(s):  
Davide Vione ◽  
Simone Belmondo ◽  
Lorenzo Carnino
Keyword(s):  
Kinetic Study ◽  
Nitrous Acid

A method for the kinetic study of amino acid nitrosation reactions

Polyhedron ◽  
2003 ◽  
Vol 22 (8) ◽  
pp. 1059-1066 ◽  
Author(s):  
Marı́a del Pilar Garcı́a Santos ◽  
Emilio Calle ◽  
Julio Casado
Keyword(s):  
Amino Acid ◽  
Kinetic Study ◽  
Nitrosation Reactions

ChemInform Abstract: Kinetic Study of the Phenylurea-Nitrous Acid Reaction: Evidence for an O-Nitrosation Initial Step.

ChemInform ◽  
1988 ◽  
Vol 19 (14) ◽  
Author(s):  
F. MEIJIDE ◽  
J. VAZQUEZ TATO ◽  
J. CASADO ◽  
A. CASTRO ◽  
M. MOSQUERA
Keyword(s):  
Kinetic Study ◽  
Nitrous Acid ◽  
Initial Step ◽  
Acid Reaction

A kinetic study of the oxidation of N(III) by ClO2− in aqueous acidic media

1980 ◽  
Vol 58 (2) ◽  
pp. 159-163 ◽  
Author(s):  
Samir S. Emeish ◽  
Keith E. Howlett
Keyword(s):  
Kinetic Study ◽  
Rate Equation ◽  
Nitrous Acid ◽  
Hypochlorous Acid ◽  
Chloride Ion ◽  
Acidic Media ◽  
Kinetics Of

Kinetics of the reaction between nitrous acid and chlorite have been studied spectrophotometrically. The rate equation involves terms [HNO2]1.5 and [ClO2−]0.5, and both an uncatalysed and a chloride ion-catalysed path have been identified. A mechanism involving peroxonitrite and hypochlorous acid as intermediates is shown to be consistent with the observations.

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