Kinetics of reaction of copper with substituted benzyl chlorides in dipolar aprotic solvents

2007 ◽  
Vol 39 (10) ◽  
pp. 547-555 ◽  
Author(s):  
Anatoly M. Egorov ◽  
Svetlana A. Matyukhova
Keyword(s):  
Aprotic Solvents ◽  
Benzyl Chlorides ◽  
Kinetics Of Reaction ◽  
Kinetics Of ◽  
Dipolar Aprotic Solvents

The kinetics of reaction of copper with substituted benzyl bromides in dipolar aprotic solvents

2005 ◽  
Vol 37 (8) ◽  
pp. 496-501 ◽  
Author(s):  
Anatoly M. Egorov ◽  
Svetlana A. Matyukhova ◽  
Alexander V. Anisimov
Keyword(s):  
Aprotic Solvents ◽  
Kinetics Of Reaction ◽  
Kinetics Of ◽  
Dipolar Aprotic Solvents

Solvation of ions by dipolar aprotic solvents and water. A CNDO/2 study

1985 ◽  
Vol 50 (11) ◽  
pp. 2493-2508 ◽  
Author(s):  
Petr Kyselka ◽  
Zdeněk Havlas ◽  
Ivo Sláma
Keyword(s):  
Binary Mixtures ◽  
Quantum Chemical ◽  
Chemical Method ◽  
Molecular Structures ◽  
Dimethyl Sulphoxide ◽  
Ternary Mixtures ◽  
Aprotic Solvents ◽  
Quantum Chemical Method ◽  
Solvation Of Ions ◽  
Dipolar Aprotic Solvents

Solvation of Li+, Be2+, Na+, Mg2+, and Al3+ ions has been studied in binary mixtures with dimethyl sulphoxide, dimethylformamide, acetonitrile and water, and in ternary mixtures of the organic solvents with water. The CNDO/2 quantum chemical method was used to calculate the energies of solvation, molecular structures and charge distributions for the complexes acetonitrile...ion (1:1, 2:1, 4:1), dimethyl sulphoxide...ion (1:1), dimethylformamide...ion (1:1), and acetonitrile (dimethyl sulphoxide, dimethylformamide)...ion...water (1:1:1).

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