Magnetic mesoporous nanoparticles modified with poly(ionic liquids) with multi‐functional groups for enrichment and determination of pyrethroid residues in apples

2019 ◽  
Vol 42 (10) ◽  
pp. 1896-1904 ◽  
Author(s):  
Bihong Zhao ◽  
Dan Wu ◽  
Huiyuan Chu ◽  
Chaozhan Wang ◽  
Yinmao Wei
Keyword(s):  
Ionic Liquids ◽  
Functional Groups ◽  
Mesoporous Nanoparticles

Dispersive Liquid-Liquid Microextraction Based on Ionic Liquid and Spectrophotometric Determination of Bilirubin in Biological Samples

2020 ◽  
Vol 16 (5) ◽  
pp. 652-659
Author(s):  
Asiye A. Avan ◽  
Hayati Filik
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Biological Samples ◽  
Urine Samples ◽  
Spectrophotometric Detection ◽  
Full Color ◽  
Dispersive Liquid Liquid Microextraction ◽  
Urine And Serum ◽  
Liquid Microextraction

Background: An Ionic Liquid-based based Dispersive Liquid-Liquid Microextraction (IL-DLLME) method was not applied to preconcentration and determination of bilirubin. Ionic Liquids (ILs) are new chemical compounds. In recent years, Ionic Liquids (ILs) have been employed as alternative solvents to toxic organic solvents. Due to these perfect properties, ILs have already been applied in many analytical extraction processes, presenting high extraction yield and selectivity for analytes. Methods: In this study, IL-DLLME was applied to biological samples (urine and serum) for the spectrophotometric detection of bilirubin. For bilirubin analysis, the full-color development was based on the reaction with periodate in the presence of hydrochloric acid. The high affinity of bilirubin for the ionic liquid phase gave extraction percentages above 98% in 0.3 M HCl solution. Results: Several IL-extraction parameters were optimized and room temperature ionic liquid 1-butyl- 1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide and ethanol were used as extraction and disperser solution. The linear range was found in the range of 0.5-6.0 μM (0.3-3.5 μg mL-1) and the limits of detection of the proposed method was 0.5 μM (0.3 μg mL-1). The proposed method was applied for the preconcentration and separation of trace bilirubin in real urine samples. Also, the recoveries for bilirubin in spiked biological samples (urine and serum) were found to be acceptable, between 95-102%. Conclusion: The proposed IL-DLLMEapproach was employed for the enrichment and determination of trace levels of bilirubin in urine samples using NaIO4 as an oxidizing agent and Uv-vis spectrophotometric detection. The periodate oxidation of bilirubin is rapid, effective, selective, and simple to perform. The method contains only HCl, NaOI4, and an anionic surfactant. The method may be useful for economizing in the consumption of reagents in bilirubin determining. The IL-DLLMEmethod ensures a high yield and has a low toxicity no skin sensitization, no mutagenicity and no ecotoxicity in an aquatic environment since only very low quantities of an IL is required. For full-color formation, no any extra auxiliary reagents are required. Besides, the IL-DLLME technique uses a low-cost instrument such as Uv-vis which is present in most of the medical laboratories.

Sorption of Lead by the Selective Ion Exchanger Ostsorb DETA

1992 ◽  
Vol 57 (7) ◽  
pp. 1393-1404 ◽  
Author(s):  
Ladislav Svoboda ◽  
Jan Uhlíř ◽  
Zdeněk Uhlíř
Keyword(s):  
Phosphoric Acid ◽  
Aqueous Solutions ◽  
Functional Groups ◽  
Ion Exchanger ◽  
Preconcentration Procedure ◽  
Bead Cellulose

The properties of Ostsorb DETA, a selective ion exchanger based on modified bead cellulose with chemically bonded diethylenetriamine functional groups, were studied, and its applicability to the preconcentration of trace amounts of lead from aqueous solutions was verified. The conditions of the preconcentration procedure in the column and batch modes were optimized for this purpose. The results obtained were applied to the determination of lead in phosphoric acid.

Rapid determination of total metals: synergic effect of ultrasound energy and ionic liquids on the digestion of sediment samples

2021 ◽  
Author(s):  
Silvana M. Álvarez ◽  
Natalia E. Llamas ◽  
Mónica B. Álvarez ◽  
Jorge E. Marcovecchio ◽  
Mariano Garrido ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Rapid Determination ◽  
Synergic Effect ◽  
Sediment Samples ◽  
Ultrasound Energy

scholarly journals Voltammetric sensor based on long alkyl chain tetraalkylammonium ionic liquids comprising ascorbate anion for determination of nitrite

2021 ◽  
Vol 188 (2) ◽  
Author(s):  
Tomasz Rębiś ◽  
Michał Niemczak ◽  
Patrycja Płócienniczak ◽  
Juliusz Pernak ◽  
Grzegorz Milczarek
Keyword(s):  
Ionic Liquids ◽  
Electrostatic Interactions ◽  
Film Surface ◽  
Modified Electrodes ◽  
Voltammetric Sensor ◽  
Nitrite Oxidation ◽  
Alkyl Chains ◽  
Modified Surface ◽  
Influence Of Ph

AbstractAn electrochemical sensor was fabricated utilizing ionic liquids possessing cations with long alkyl chains such as trimethyl octadecylammonium and behenyl trimethylammonium and ascorbate anion. The ionic liquids were drop-coated onto the electrode. Thin modifying layers were prepared. Cyclic voltammetric investigations revealed electrostatic interactions between the electrochemical probes and the modified surface, proving that a positive charge was established at the film surface. Hence, negatively charged species such as nitrite can be pre-concentrated on the surface of presented modified electrodes. The fabricated electrodes have been used as a voltammetric sensor for nitrite. Due to the electrostatic accumulation properties of long alkyl cation, the assay exhibits a remarkable improvement in the voltammetric response toward nitrite oxidation. The influence of pH on the electrode response was thoroughly investigated, and the mechanism of the electrode was established. The developed sensor showed a linear electrochemical response in the range 1.0–50 μM with a detection limit of 0.1 μM. The electrode revealed good storage stability, reproducibility, and anti-interference ability. The determination of nitrite performed in curing salts brought satisfactory results. Graphical abstract

Application of ionic liquids based on imidazole to the electrophoretic determination of amino acids in urine

2015 ◽  
Vol 70 (11) ◽  
pp. 1354-1359 ◽  
Author(s):  
E. A. Kolobova ◽  
L. A. Kartsova ◽  
E. A. Bessonova
Keyword(s):  
Amino Acids ◽  
Ionic Liquids

Determination of Hydrocarbon Functional Groups by Infrared Spectroscopy

1952 ◽  
Vol 24 (4) ◽  
pp. 612-618 ◽  
Author(s):  
S. H. Hastings ◽  
A. T. Watson ◽  
R. B. Williams ◽  
J. A. Anderson
Keyword(s):  
Infrared Spectroscopy ◽  
Functional Groups

scholarly journals HPLC Determination of Chlorophenols in Water with Separation by Ionic Liquids [Bmim]BF4 Aqueous Two-phase Solvent Sublation

2013 ◽  
Vol 25 (4) ◽  
pp. 2129-2134 ◽  
Author(s):  
Liang Wang ◽  
Hong Zhu ◽  
Chunhong Ma ◽  
Yongsheng Yan
Keyword(s):  
Ionic Liquids ◽  
Hplc Determination ◽  
Two Phase
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