Determination of trace amounts of aromatic amines after magnetic solid‐phase extraction using silver‐modified Fe 3 O 4 /graphene nanocomposite

2019 ◽  
Vol 42 (9) ◽  
pp. 1777-1785 ◽  
Author(s):  
Mohammad Reza Kashefi Alasl ◽  
Mahmoud Reza Sohrabi ◽  
Mehran Davallo
Keyword(s):  
Solid Phase Extraction ◽  
Aromatic Amines ◽  
Solid Phase ◽  
Magnetic Solid Phase Extraction ◽  
Phase Extraction ◽  
Magnetic Solid ◽  
Graphene Nanocomposite

scholarly journals Determination of Aflatoxin B1 and B2 in Vegetable Oils Using Fe3O4/rGO Magnetic Solid Phase Extraction Coupled with High-Performance Liquid Chromatography Fluorescence with Post-Column Photochemical Derivatization

Toxins ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 621 ◽  
Author(s):  
Li Yu ◽  
Fei Ma ◽  
Liangxiao Zhang ◽  
Peiwu Li
Keyword(s):  
High Performance Liquid Chromatography ◽  
Solid Phase Extraction ◽  
Vegetable Oils ◽  
High Performance ◽  
Solid Phase ◽  
Magnetic Solid Phase Extraction ◽  
Phase Extraction ◽  
Magnetic Solid ◽  
Graphene Nanocomposite

In this study, magnetic graphene nanocomposite Fe3O4/rGO was synthesized by facile one-pot solvothermal method. The nanocomposite was successfully used as magnetic solid phase extraction (MSPE) adsorbents for the determination of aflatoxins in edible vegetable oils through the π–π stacking interactions. MSPE parameters including the amount of adsorbents, extraction and desorption time, washing conditions, and the type and volume of desorption solvent were optimized. Under optimal conditions, good linear relationships were achieved. Limits of detection of this method were as low as 0.02 µg/kg and 0.01 µg/kg for aflatoxin B1 and B2, respectively. Finally, the magnetic graphene nanocomposite was successfully applied to aflatoxin analysis in vegetable oils. The results indicated that the recoveries of the B-group aflatoxins ranged from 80.4% to 106.0%, whereas the relative standard deviations (RSDs) were less than 8.1%. Owing to the simplicity, rapidity and efficiency, Fe3O4/rGO magnetic solid phase extraction coupled with high-performance liquid chromatography fluorescence with post-column photochemical derivatization (Fe3O4/rGO MSPE-HPLC-PCD-FLD) is a promising analytical method for routine and accurate determination of aflatoxins in lipid matrices.

Ultrasound-assisted magnetic solid-phase extraction for the determination of some transition metals in Orujo spirit samples by capillary electrophoresis

2016 ◽  
Vol 190 ◽  
pp. 263-269 ◽  
Author(s):  
Rosa M. Peña Crecente ◽  
Carlha Gutiérrez Lovera ◽  
Julia Barciela García ◽  
Carlos Herrero Latorre ◽  
Sagrario García Martín
Keyword(s):  
Capillary Electrophoresis ◽  
Transition Metals ◽  
Solid Phase Extraction ◽  
Solid Phase ◽  
Magnetic Solid Phase Extraction ◽  
Phase Extraction ◽  
Magnetic Solid ◽  
Ultrasound Assisted
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