Preparation and application of hollow molecularly imprinted polymers with a super-high selectivity to the template protein

2013 ◽  
Vol 36 (20) ◽  
pp. 3449-3456 ◽  
Author(s):  
Yang Chen ◽  
Xi-Wen He ◽  
Jie Mao ◽  
Wen-You Li ◽  
Yu-Kui Zhang
Keyword(s):  
Molecularly Imprinted Polymers ◽  
High Selectivity ◽  
Molecularly Imprinted ◽  
Imprinted Polymers ◽  
Template Protein

Molecularly imprinted polymers’ application in pesticide residue detection

The Analyst ◽  
2018 ◽  
Vol 143 (17) ◽  
pp. 3971-3989 ◽  
Author(s):  
Saqib Farooq ◽  
Jiyun Nie ◽  
Yang Cheng ◽  
Zhen Yan ◽  
Jing Li ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Pesticide Residue ◽  
Molecular Imprinting ◽  
Molecularly Imprinted Polymers ◽  
High Selectivity ◽  
High Sensitivity ◽  
Molecularly Imprinted ◽  
Imprinted Polymers ◽  
Residue Detection ◽  
Molecular Imprinting Technology

Molecularly imprinted polymers (MIPs) are produced using molecular imprinting technology (MIT) and have specific analyte-binding abilities and unique properties, including chemical and thermal stability, reusability, high selectivity, and high sensitivity.

Sythesis of Molecularly Imprinted Polymers for the Binding and Recognition of Nonylphenol

2013 ◽  
Vol 641-642 ◽  
pp. 55-59 ◽  
Author(s):  
Yan Jie Bi ◽  
Wen Yan Li ◽  
Chen Yuan ◽  
Bin Song Wang
Keyword(s):  
Molecularly Imprinted Polymers ◽  
High Selectivity ◽  
Sol Gel ◽  
Template Molecule ◽  
Binding Properties ◽  
Adsorption Selectivity ◽  
Molecularly Imprinted ◽  
Imprinted Polymers ◽  
Selective Enrichment ◽  
Sol Gel Process

In this paper, molecularly imprinted polymers with high selectivity for nonylphenol (NP) were synthesized by sol-gel process using 4-vinylpyridine (4-Vpy) as functional monomer, ethyleneglycol dimethacrylate as crosslinker (EGDMA), azobisisobutyronitrile (AIBN) as initiator, NP as template molecules. The performance of imprinted material was evaluated by adsorption kinetic, adsorption isotherm and adsorption selectivity. The results indicated that this material had not only binding properties but also high selectivity to the template molecule, which had good application prospects in the selective enrichment and separation of NP for pretreatment and analysis of complex environmental samples.

Designer Ligands. Part 10.1 Novel Nickel(Ii)-Selective Ligands for Use in the Construction of Molecularly Imprinted Polymers

2003 ◽  
Vol 2003 (4) ◽  
pp. 179-181 ◽  
Author(s):  
Perry T. Kaye ◽  
T. Robert Tshikhudo
Keyword(s):  
Molecularly Imprinted Polymers ◽  
High Selectivity ◽  
Preliminary Evaluation ◽  
Molecularly Imprinted ◽  
Imprinted Polymers ◽  
Selective Ligands

Novel, bidentate nickel(II)-selective ligands have been developed for use in the construction of molecularly imprinted polymers (MIPs), preliminary evaluation of which indicates high selectivity for nickel(II) over iron(III).

scholarly journals Development of molecularly imprinted polymers (MIPs) as a solid phase extraction (SPE) sorbent for the determination of ibuprofen in water

RSC Advances ◽  
2017 ◽  
Vol 7 (50) ◽  
pp. 31441-31447 ◽  
Author(s):  
Y. A. Olcer ◽  
M. Demirkurt ◽  
M. M. Demir ◽  
A. E. Eroglu
Keyword(s):  
Solid Phase Extraction ◽  
Molecularly Imprinted Polymers ◽  
High Selectivity ◽  
Solid Phase ◽  
Phase Extraction ◽  
Molecularly Imprinted ◽  
Imprinted Polymers ◽  
Related Compounds

Ibuprofen-templated molecularly imprinted polymers (MIPs) demonstrated high selectivity to ibuprofen in the presence of closely related compounds, naproxen and ketoprofen.

Synthesis of a new substituted zinc phthalocyanine as functional monomer in the preparation of MIPs

2006 ◽  
Vol 10 (08) ◽  
pp. 1061-1065 ◽  
Author(s):  
Luigia Longo ◽  
Giuseppe Vasapollo ◽  
Anna Scardino ◽  
Rosaria Anna Picca ◽  
Cosimino Malitesta
Keyword(s):  
Free Energy ◽  
Binding Affinity ◽  
Gibbs Free Energy ◽  
Molecularly Imprinted Polymers ◽  
Binding Constant ◽  
High Selectivity ◽  
Zinc Phthalocyanine ◽  
Functional Monomer ◽  
Molecularly Imprinted ◽  
Imprinted Polymers

A new zinc phthalocyanine peripherally substituted with methacrylic groups was synthesized to be employed as a functional monomer in the formation of molecularly imprinted polymers as nucleoside receptors. The binding affinity and selectivity of the synthesized phthalocyanine towards nucleosides were evaluated by UV-vis titration experiments in CH 2 Cl 2 at 298 K. The binding constant ( K a) and Gibbs free energy changes (-Δ G 0) were calculated according to the modified Benesi-Hildebrand equation. Binding experiments showed that K a of phthalocyanine with tri-O-acetyladenosine ( TOAA ) is 1.35 × 104, 500 times that of phthalocyanine with tri-O-acetyluridine ( TOAU ), indicating a high selectivity of the synthesized phthalocyanine derivative.

High selectivity and sensitivity fluorescence sensing of melamine based on the combination of a fluorescent chemosensor and molecularly imprinted polymers

RSC Advances ◽  
2015 ◽  
Vol 5 (114) ◽  
pp. 94084-94090 ◽  
Author(s):  
Kejin Sun ◽  
Qiliang Deng ◽  
Ting Guo ◽  
Rina Su ◽  
Yuchen Gu ◽  
...  
Keyword(s):  
Molecularly Imprinted Polymers ◽  
High Selectivity ◽  
Fluorescent Chemosensor ◽  
Fluorescence Sensing ◽  
Molecularly Imprinted ◽  
Imprinted Polymers ◽  
Efficient Approach

In this study, a sensitive and efficient approach was developed for the determination of melamine (MEL) based on the combination of molecularly imprinted polymers (MIPs) with a synthesized fluorescent chemosensor.

scholarly journals Selective recognition of methotrexate by molecularly imprinted polymers

e-Polymers ◽  
2009 ◽  
Vol 9 (1) ◽  
Author(s):  
Manuela Curcio ◽  
Ortensia Ilaria Parisi ◽  
Giuseppe Cirillo ◽  
Umile Gianfranco Spizzirri ◽  
Francesco Puoci ◽  
...  
Keyword(s):  
Clinical Trials ◽  
Functional Groups ◽  
Methacrylic Acid ◽  
Molecularly Imprinted Polymers ◽  
High Selectivity ◽  
Selective Recognition ◽  
Template Molecule ◽  
Molecularly Imprinted ◽  
Functional Monomers ◽  
Imprinted Polymers

AbstractThe aim of this study is the preparation of molecularly imprinted polymers with high selectivity for metotrexate (MTX), a useful antineoplastic drug widely employed in clinical trials. Methacrylic acid, 2-(dimethylamino)ethyl methacrylate and a mixture of them were tested as functional monomers in order to optimize the performance of imprinted materials. The specificity and the selectivity of imprinted polymers was tested by performing rebinding experiments in water at pH 7.4. The best results were obtained by employing both functional monomers in the polymeric feed. In this way, each monomer interacts with complementary functionalities on template molecule, stabilizing the prepolymerization complex and minimizing the repulsive effects (due to the ionization of functional groups) in the rebinding media.

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