Detection of the reduced forms of radical adducts on the ESR trace using HPLC-electrochemical detector-ultraviolet absorption detector-electron spin resonance-MS

2010 ◽  
pp. NA-NA ◽  
Author(s):  
Hideyuki Ikeda ◽  
Hideo Iwahashi
1966 ◽  
Vol 44 (14) ◽  
pp. 1677-1683 ◽  
Author(s):  
D. A. Stiles ◽  
W. J. R. Tyerman ◽  
O. P. Strausz ◽  
H. E. Gunning

Samples of COSe and CSe2 were photolyzed at 77 °K, either pure or in matrices of Xe or trans-2-butene. Observed electron spin resonance spectra are assigned to Se(43P), to Se2, and to chains of selenium atoms, •Se(Se)nSe•. The selenium chains exhibit metallic behavior intermediate between that of sulfur and tellurium. It is suggested that polymeric chains of CSe are formed on warming photolyzed samples containing CSe2. The ultraviolet absorption spectrum of COSe vapor is reported.


1968 ◽  
Vol 107 (4) ◽  
pp. 601-602 ◽  
Author(s):  
R C Bray ◽  
P F Knowles ◽  
F M Pick ◽  
T Vänngård

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