Cation Effect on the Binary and Ternary Phase Behaviors of Double‐Tailed Methanesulfonate Amphiphiles

2021 ◽  
Author(s):  
Jesús F. Ontiveros ◽  
Bing Hong ◽  
Kenji Aramaki ◽  
Christel Pierlot ◽  
Jean‐Marie Aubry ◽  
...  
Keyword(s):  
Ternary Phase ◽  
Cation Effect ◽  
Phase Behaviors

Molecular Origins of Polymorphism in Cocoa Butter

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Saeed M. Ghazani ◽  
Alejandro G. Marangoni
Keyword(s):  
Cocoa Butter ◽  
Ternary Phase ◽  
Annual Review ◽  
Food Science ◽  
Publication Date ◽  
Polymorphic Transformations ◽  
Crystal Forms ◽  
Polymorphic Forms ◽  
Phase Behaviors ◽  
Metastable Forms

Cocoa butter displays complex crystallization behavior and six crystal polymorphic forms. Although the crystal structure of cocoa butter has been studied extensively, the molecular interactions between cocoa butter triacylglycerols in relation to polymorphic transformations from metastable forms (forms III and IV) to stable crystal forms (forms V and VI) remain largely unknown. In this review, the triclinic polymorphism and melting profiles of the major triacylglycerols in cocoa butter—POP, POS, and SOS—are reviewed, and their binary and ternary phase behaviors in metastable (pseudoβ′) and stable (β2) crystal forms are discussed. We also attempt to clarify how the transformation of cocoa butter from form IV to V, as a critical step in the tempering of chocolate, is controlled by POS interactions with both POP and SOS. Moreover, we show how the crystal forms V and VI of cocoa butter are templated by crystal forms β3 and β1 of POS, respectively. Expected final online publication date for the Annual Review of Food Science and Technology, Volume 12 is March 2021. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.

Binary and Ternary Phase Behaviors of Short Double-Chain Quaternary Ammonium Amphiphiles: Surface Tension, Polarized Optical Microscopy, and SAXS Investigations

2013 ◽  
Vol 117 (47) ◽  
pp. 14732-14742 ◽  
Author(s):  
Bing Hong ◽  
Jonathan Lai ◽  
Loïc Leclercq ◽  
Marion Collinet-Fressancourt ◽  
Jean-Marie Aubry ◽  
...  
Keyword(s):  
Surface Tension ◽  
Optical Microscopy ◽  
Quaternary Ammonium ◽  
Ternary Phase ◽  
Double Chain ◽  
Polarized Optical Microscopy ◽  
Phase Behaviors

Moire Fringes on Precipitates in Quenched and Aged Beryllium

1968 ◽  
Vol 26 ◽  
pp. 426-427
Author(s):  
F. J. Fraikor ◽  
A. W. Brewer
Keyword(s):  
Ternary Phase ◽  
Volume Fraction ◽  
Age Hardening ◽  
Orientation Relationships ◽  
Solute Content ◽  
Moiré Fringes ◽  
Moire Patterns ◽  
Total Volume Fraction ◽  
Diffraction Patterns ◽  
Moiré Patterns

A number of investigators have examined moire patterns on precipitate particles in various age-hardening alloys. For example, Phillips has analyzed moire fringes at cobalt precipitates in copper and Von Heimendahl has reported on moire fringes in the system Al-Au. Recently, we have observed moire patterns on impurity precipitates in beryllium quenched in brine from 1000°C and aged at various temperatures in the range of 500-800°C. This heat treatment of beryllium rolled from vacuum cast ingots produces the precipitation of both an fee ternary phase, AlFeBe4, and an hcp binary phase, FeBe11. However, unlike a typical age-hardening alloy, the solute content of this material is low (less than 1000 ppm of Fe and 600 ppm of Al) and hence the total volume fraction of precipitates is small. Therefore there is some difficulty in distinguishing the precipitates and their orientation relationships with the beryllium matrix since the weak precipitate spots generally do not appear on the diffraction patterns.

Chemoselectivity in Cyclosiloxanolate Cluster Formation: An Alkali Cation Effect?

2000 ◽  
Vol 2000 (6) ◽  
pp. 1327-1331 ◽  
Author(s):  
Claudia Zucchi ◽  
Manuela Mattioli ◽  
Giovanna Gavioli ◽  
Massimo Moret ◽  
Angelo Sironi ◽  
...  
Keyword(s):  
Cluster Formation ◽  
Alkali Cation ◽  
Cation Effect

Using phase boundary mapping to resolve discrepancies in the Mg2Si–Mg2Sn miscibility gap

2021 ◽  
Author(s):  
Rachel Orenstein ◽  
James P. Male ◽  
Michael Toriyama ◽  
Shashwat Anand ◽  
G. Jeffrey Snyder
Keyword(s):  
Phase Diagram ◽  
Phase Boundary ◽  
Ternary Phase ◽  
Ternary Phase Diagram ◽  
Miscibility Gap ◽  
Boundary Mapping

A new understanding of the MgSi–MgSn miscibility gap is reached through phase boundary mapping the Mg–Si–Sn ternary phase diagram.

Influences of alkanes on the phase behaviors of system of cationic–anionic surfactants

2021 ◽  
pp. 1-7
Author(s):  
Hongni Teng ◽  
Na Wang ◽  
Yao Zhang ◽  
Jingjing Wang ◽  
Yong Chen
Keyword(s):  
Anionic Surfactants ◽  
Phase Behaviors

Combining CaO–SiO2–TiO2 and CaO–SiO2–Al2O3 ternary phase systems for design of bimetallic welds

2021 ◽  
Vol 235 (8) ◽  
pp. 1271-1283
Author(s):  
Deepak Bhandari ◽  
Rahul Chhibber ◽  
Lochan Sharma ◽  
Navneet Arora ◽  
Rajeev Mehta
Keyword(s):  
Weld Metal ◽  
Power Plants ◽  
Ternary Phase ◽  
Desirability Function ◽  
Manganese Content ◽  
Research Work ◽  
Welding Process ◽  
Delta Ferrite ◽  
Electrode Coating ◽  
Phase Systems

The bimetallic welds are frequently utilized for pipeline transport system of the nuclear power plants. The occurrences of welding defects generally depend on the filler electrode as well as the electrode coatings during shielded metal arc welding process. This study involves the design of austenitic stainless steel welding electrodes for SS304L–SA516 bimetallic welds. The objective of research work includes the novel design of Al2O3–TiO2–CaO–SiO2 coatings by combining two ternary phase systems using extreme vertices mixture design methodology to analyze the effect of key coating constituents on the weld metal chemistry and mechanical properties of the welds. The significant effect of electrode coating constituent CaO on weld metal manganese content is observed which further improves the toughness of bimetallic weld joints. Various regression models have been developed for the weld responses and multi objective optimisation approach using composite desirability function has been adopted for identifying the optimized set of electrode coating compositions. The role of delta ferrite content in promoting the favourable solidification mode has been studied through microstructural examination.

Calculation of phase diagrams and thermodynamic properties of 14 additive and reciprocal ternary systems containing Li2CO3, Na2CO3, K2CO3, Li2SO4, Na2SO4, K2SO4, LiOH, NaOH, and KOH

1984 ◽  
Vol 62 (3) ◽  
pp. 457-474 ◽  
Author(s):  
A. D. Pelton ◽  
C. W. Bale ◽  
P. L. Lin
Keyword(s):  
Phase Diagram ◽  
Thermodynamic Properties ◽  
Molten Salt ◽  
Phase Diagrams ◽  
Binary Systems ◽  
Ternary Phase ◽  
Ternary Phase Diagram ◽  
Ternary Systems ◽  
Maximum Error ◽  
Critical Assessment

Phase diagrams and thermodynamic properties of five additive molten salt ternary systems and nine reciprocal molten salt ternary systems containing the ions Li+, Na+, [Formula: see text], OH− are calculated from the thermodynamic properties of their binary subsystems which were obtained previously by a critical assessment of the thermodynamic data and the phase diagrams in these binary systems. Thermodynamic properties of ternary liquid phases are estimated from the binary properties by means of the Conformal Ionic Solution Theory. The ternary phase diagrams are then calculated from these thermodynamic properties by means of computer programs designed for the purpose. It is found that a ternary phase diagram can generally be calculated in this way with a maximum error about twice that of the maximum error in the binary phase diagrams upon which the calculations are based. If, in addition, some reliable ternary phase diagram measurements are available, these can be used to obtain small ternary correction terms. In this way, ternary phase diagram measurements can be smoothed and the isotherms drawn in a thermodynamically correct way. The thermodynamic approach permits experimental data to be critically assessed in the light of thermodynamic principles and accepted solution models. A critical assessment of error limits on all the calculated ternary diagrams is made, and suggestions as to which composition regions merit further experimental study are given.

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