Raman spectroscopy of optical phonon confinement in nanostructured materials

2007 ◽  
Vol 38 (6) ◽  
pp. 604-617 ◽  
Author(s):  
Akhilesh K. Arora ◽  
M. Rajalakshmi ◽  
T. R. Ravindran ◽  
V. Sivasubramanian
Keyword(s):  
Raman Spectroscopy ◽  
Nanostructured Materials ◽  
Optical Phonon ◽  
Phonon Confinement

Modified phonon confinement model for Raman spectroscopy of nanostructured materials

2010 ◽  
Vol 82 (11) ◽  
Author(s):  
K. Roodenko ◽  
I. A. Goldthorpe ◽  
P. C. McIntyre ◽  
Y. J. Chabal
Keyword(s):  
Raman Spectroscopy ◽  
Nanostructured Materials ◽  
Phonon Confinement ◽  
Confinement Model

scholarly journals Raman spectroscopy of optical phonon and charge density wave modes in 1T-TiSe2 exfoliated flakes

2017 ◽  
Vol 266 ◽  
pp. 21-25 ◽  
Author(s):  
Lin Cui ◽  
Rui He ◽  
Gaomin Li ◽  
Yujun Zhang ◽  
Yumeng You ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Charge Density ◽  
Optical Phonon ◽  
Charge Density Wave ◽  
Density Wave ◽  
Wave Modes

Phonon confinement effect on nanocrystalline LiCoO2 studied with Raman spectroscopy

2008 ◽  
Vol 69 (11) ◽  
pp. 2911-2915 ◽  
Author(s):  
M. Okubo ◽  
E. Hosono ◽  
T. Kudo ◽  
H.S. Zhou ◽  
I. Honma
Keyword(s):  
Raman Spectroscopy ◽  
Confinement Effect ◽  
Phonon Confinement ◽  
Phonon Confinement Effect

Nondestructive Characterizations of Au-Catalyzed GaAs Nanowires on GaAs(111)B Substrates via Identifications of 1st Order Optical Phonon Modes Using μ-Raman Spectroscopy

2020 ◽  
Vol 20 (7) ◽  
pp. 4358-4363
Author(s):  
Jeung Hun Park ◽  
Richard S. Kim ◽  
Se-Jeong Park ◽  
Gye-Choon Park ◽  
Choong-Heui Chung
Keyword(s):  
Raman Spectroscopy ◽  
Dose Rate ◽  
Raman Spectra ◽  
Optical Phonon ◽  
Longitudinal Optical ◽  
Transverse Optical ◽  
Longitudinal Optical Phonon ◽  
Phonon Modes ◽  
Gaas Nanowires ◽  
Beam Dose

We report the relation between the catalyst patterning conditions and the intensity of the 1st order Raman active modes in Au-catalyzed GaAs nanowire bundles. We fabricated e-beam lithographically Au-patterned GaAs(111)B substrates by varying the patterning conditions (e-beam dose rate, dot-size and interdot-spacings), and grew GaAs nanowires via vapor–liquid–solid process using a solid-source molecular beam epitaxy. To understand the effects of the substrate preparation conditions and resulting morphologies on the optical characteristics of 1st order transverse optical and longitudinal optical phonon modes of GaAs, we characterized the nanowire bundles using complementary μ-Raman spectroscopy and scanning electron microscopy as a function of the e-beam dose rate (145–595 μC/cm2), inter-dot spacing (100 and 150 nm) and pattern size (100 and 150 nm). Ensembles of single crystalline GaAs nanowires covered with different Au-thickness exhibit a downshift and asymmetric broadening of the 1st order transverse optical and longitudinal optical phonon peaks relative to GaAs bulk modes. We also showed that the sensitivity of a downshift and broadening of Raman spectra are directly related to morphological and surface coverage variations in as-grown nanowires. We observed clear increases of the transverse optical and longitudinal optical intensity as well as the relatively higher peak shift and broadening of Raman spectra from the 100 nm patterning in response to the dose rate change. Strong dependence of Raman spectra of the nanowire bundles on the e-beam dose rate changes are attributed to the variations in spatial density, size, shape and random growth orientation of the wires. We have shown that the identification of the changes in GaAs longitudinal optical and Arsenic anti-site peaks is good indicators to characterize the quality of as-grown GaAs nanowires. Our finding confirms the utilization of Raman spectroscopy as a powerful tool for characterizing chemical, structural, and morphological information of as-grown nanowires within the supporting substrate.

Evaluation of phonon confinement in ultrathin-film silicon-on-insulator by Raman spectroscopy

2014 ◽  
Vol 53 (3) ◽  
pp. 032401 ◽  
Author(s):  
Kohki Nagata ◽  
Munehisa Takei ◽  
Atsushi Ogura ◽  
Ken Uchida
Keyword(s):  
Raman Spectroscopy ◽  
Ultrathin Film ◽  
Silicon On Insulator ◽  
Phonon Confinement
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