Two‐dimensional and deuterium‐induced, differential‐isotope‐shift nuclear magnetic resonance characterization of potassium sucrose octasulfate and sucralfate

1992 ◽  
Vol 81 (5) ◽  
pp. 471-474 ◽  
Author(s):  
Gary L. Silvey
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Isotope Shift ◽  
Two Dimensional ◽  
Sucrose Octasulfate ◽  
Nuclear Magnetic

Unambiguous structural and nuclear magnetic resonance spectral characterization of two triterpenoids of Maprouneaguianensis by two-dimensional nuclear magnetic resonance spectroscopy

1987 ◽  
Vol 65 (11) ◽  
pp. 2519-2525 ◽  
Author(s):  
Stewart McLean ◽  
Marion Perpick-Dumont ◽  
William F. Reynolds ◽  
Helen Jacobs ◽  
Sagar Singh Lachmansing
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Resonance Spectroscopy ◽  
Two Dimensional ◽  
Mass Spectral Fragmentation ◽  
Mass Spectral ◽  
Alternative Approaches ◽  
Fragmentation Patterns ◽  
Nuclear Magnetic

It is shown that 1H–13C shift-correlated two-dimensional spectra obtained for polarization transfer via two-bond and three-bond 13C–1H coupling can, in conjunction with related experiments, be used to assign unambiguously the molecular skeletons of two of the less common triterpenes, moretenone and 3-acetylaleuritolic acid. It is concluded that this is a technique of considerable generality for assigning structures of triterpenes and is more reliable than alternative approaches such as mass spectral fragmentation patterns. It has the additional benefit of simultaneously providing reliable 13C and 1H spectral assignments for these compounds.

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