An efficient construction of CN bond under catalyst‐free and room temperature conditions

2021 ◽  
Vol 58 (5) ◽  
pp. 1179-1191
Author(s):  
Jinpeng Zhang ◽  
Jing Liu ◽  
Lei Dai ◽  
Yuqian Ge ◽  
Linlin Xu ◽  
...  
2016 ◽  
Vol 7 (11) ◽  
pp. 2105-2111 ◽  
Author(s):  
Alexander Yuen ◽  
Amaury Bossion ◽  
Enrique Gómez-Bengoa ◽  
Fernando Ruipérez ◽  
Mehmet Isik ◽  
...  

Non-isocyanate polyurethanes (NIPUs) were prepared via polyaddition of highly reactive 8-membered ‘bis-cyclic’ carbonates and various diamines under catalyst-free and room temperature conditions.


2018 ◽  
Vol 20 (3) ◽  
pp. 604-608 ◽  
Author(s):  
Ying-chun Wang ◽  
Li-qiu Liu ◽  
Guang-mang Wang ◽  
Hui Ouyang ◽  
You-ji Li

The combination of N-fluorobenzenesulfonimide (NFSI) with diselenides allowed the rapid decarboxylative tri- or tetrafunctionalization of alkynyl carboxylic acids under catalyst-free room-temperature conditions. This reaction offers an novel and facile route to polyseleno-substituted enamines.


2021 ◽  
Author(s):  
Wenjing Li ◽  
Shun Li ◽  
Lihua Luo ◽  
Yichen Ge ◽  
Jiaqi Xu ◽  
...  

The catalyst-free oxidative cleavage of (Z)-triaryl-substituted alkenes bearing pyridyl motif with ambient air under irradiation of blue LED at room temperature has been developed. The reaction was facile and scalable,...


1948 ◽  
Vol 35 (1) ◽  
pp. 39-48 ◽  
Author(s):  
E. D. Smith ◽  
B. H. Ershoff ◽  
R. J. Winzler ◽  
H. J. Deuel

ChemInform ◽  
2008 ◽  
Vol 39 (47) ◽  
Author(s):  
Janhavi J. Shrikhande ◽  
Manoj B. Gawande ◽  
Radha V. Jayaram

Synlett ◽  
2017 ◽  
Vol 28 (19) ◽  
pp. 2619-2623 ◽  
Author(s):  
Yunxia Wang ◽  
Na Cui ◽  
Yu Zhao

A catalyst-free oxidative [3+2] cycloaddition of phenols and styrenes was developed with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone as the oxidant and 1,1,1,3,3,3-hexafluoropropan-2-ol as the solvent at room temperature. With this method, a broad range of dihydrobenzofurans were efficiently and quickly obtained from readily available phenols and styrenes.


Author(s):  
Rashmi Singh ◽  
Vishal Prasad Sharma ◽  
Priyanka Yadav ◽  
Priyanka Sonker ◽  
Radhey Mohan Singh ◽  
...  

A novel, simple and eco-friendly strategy for the synthesis of thiopyrano[4,3-b]quinolin-1-ones and pyrrolo[3,4-b]quinolin-1-ones from 2-alkynylquinoline-3-carbonitriles and sodium sulphide (Na2S·9H2O) under catalyst-free conditions at RT.


2021 ◽  
Vol 878 ◽  
pp. 15-22
Author(s):  
Brianna A. Richmond ◽  
Carisa D. Kunkle ◽  
Daniela M. Topasna

This study presents the long time effects of varying temperature conditions on pH-responsive films deposited on glass slides. The films were fabricated from Brilliant Yellow and poly (allylamine hydrochloride) through ionically self-assembled monolayer technique using an automated slide strainer. The absorbance of the films was monitored and the effect of varying temperature on the optical properties of the films was studied. We found that as the films are maintained at increasing temperatures their absorbance slightly decreased. As the temperature increased the percent change decreased reaching a plateau. Films kept at low temperatures of 3.24 °C and below freezing (-9.02 °C) had a small increase in absorbance. Finally, we monitored the absorbance of films kept at room temperature over a long time (128 days) and found that the films showed decreased absorbance by 19%.


Sign in / Sign up

Export Citation Format

Share Document