TFAA/H3PO4-Mediated C-2 Acylation of Thiophene: A Direct Synthesis of Known and Novel Thiophene Derivatives of Pharmacological Interest

2013 ◽  
Vol 51 (3) ◽  
pp. 586-593 ◽  
Author(s):  
P. Bindu ◽  
Shravan Reddy Naini ◽  
K. Shanmukha Rao ◽  
P. K. Dubey ◽  
Sarbani Pal
Keyword(s):  
Direct Synthesis ◽  
Pharmacological Interest ◽  
Thiophene Derivatives ◽  
Derivatives Of

ChemInform Abstract: TFAA/H3PO4-Mediated C-2 Acylation of Thiophene: A Direct Synthesis of Known and Novel Thiophene Derivatives of Pharmacological Interest.

ChemInform ◽  
2014 ◽  
Vol 45 (47) ◽  
pp. no-no
Author(s):  
P. Bindu ◽  
Shravan Reddy Naini ◽  
K. Shanmukha Rao ◽  
P. K. Dubey ◽  
Sarbani Pal
Keyword(s):  
Direct Synthesis ◽  
Pharmacological Interest ◽  
Thiophene Derivatives ◽  
Derivatives Of

570. Compounds of potential pharmacological interest. Part IV. Aryl and alkyl derivatives of 1-aminoindane

1956 ◽  
pp. 2928 ◽  
Author(s):  
J. A. Barltrop ◽  
R. M. Acheson ◽  
P. G. Philpott ◽  
K. E. MacPhee ◽  
J. S. Hunt
Keyword(s):  
Alkyl Derivatives ◽  
Pharmacological Interest ◽  
Derivatives Of

Direct synthesis of organic derivatives of silicon using nonhalogenated organic compounds

1970 ◽  
Vol 9 (5) ◽  
pp. 1071-1075 ◽  
Author(s):  
William E. Newton ◽  
Eugene G. Rochow
Keyword(s):  
Organic Compounds ◽  
Direct Synthesis ◽  
Derivatives Of

Bis(ether) derivatives of tetrakis(2-hydroxyphenyl)ethene — Direct synthesis of (E)- and (Z)-bis(2-hydroxyphenyl)-bis(2-methoxyphenyl)ethene via the McMurry olefination reaction

2006 ◽  
Vol 84 (10) ◽  
pp. 1250-1253 ◽  
Author(s):  
Mee-Kyung Chung ◽  
Paul Fancy ◽  
Jeffrey M Stryker
Keyword(s):  
Supramolecular Chemistry ◽  
Direct Synthesis ◽  
Protecting Groups ◽  
Tert Butyl ◽  
Orthogonal Protection ◽  
Protection Strategies ◽  
Titanium Trichloride ◽  
Sterically Hindered ◽  
Derivatives Of

The direct synthesis of sterically hindered, partially etherified derivatives of tetrakis(2-hydroxyphenyl)ethene is reported by using the McMurry reductive olefination reaction on a range of differentially substituted 2,2′-dialkoxy benzophenone substrates. Three orthogonal protection strategies are demonstrated, incorporating β-silylethyl, 3-butenyl, and tert-butyl protecting groups, respectively, into the starting benzophenones. The latter proved most efficient, with both the McMurry coupling and deprotection steps occurring concomitantly under the McMurry conditions to directly yield the desired bis(2-hydroxyphenyl)-bis(2-methoxyphenyl)ethene as a 1:1 mixture of E- and Z-diastereoisomers.Key words: preorganized polyaryloxide ligands, McMurry olefination, titanium trichloride, supramolecular chemistry, tetrakis(2-hydroxyphenyl)ethene, 2,2′-disubstituted benzophenone.

Optical and electro-optical properties of silicon-contaning thiophene derivatives of star-shaped and dendritic structure

2013 ◽  
Vol 86 (5) ◽  
pp. 747-755 ◽  
Author(s):  
N. P. Yevlampieva ◽  
A. P. Khurchak ◽  
Yu. N. Luponosov ◽  
E. A. Kleimyuk ◽  
S. A. Ponomarenko ◽  
...  
Keyword(s):  
Optical Properties ◽  
Dendritic Structure ◽  
Thiophene Derivatives ◽  
Derivatives Of

Direct Synthesis of Z, Boc, Fmoc, Alloc[ddot] Derivatives of 5-Aminooxazoles Starting from Acylamino Acids and Chlorosulfonylcarbamates

2000 ◽  
Vol 30 (14) ◽  
pp. 2541-2548 ◽  
Author(s):  
Georges Dewynter ◽  
A. Houssem Hajri ◽  
Loic Toupet ◽  
Jean-Louis Montero
Keyword(s):  
Direct Synthesis ◽  
Derivatives Of
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