Nitrite accumulation characteristics of high strength ammonia wastewater in an autotrophic nitrifying biofilm reactor

2003 ◽  
Vol 78 (4) ◽  
pp. 377-383 ◽  
Author(s):  
Ho-Joon Yun ◽  
Dong-Jin Kim
2007 ◽  
Vol 55 (8-9) ◽  
pp. 43-49 ◽  
Author(s):  
E. Germain ◽  
L. Bancroft ◽  
A. Dawson ◽  
C. Hinrichs ◽  
L. Fricker ◽  
...  

An integrated fixed-film activated sludge (IFAS) pilot plant and a moving bed biofilm reactor coupled with an activated sludge process (MBBR/AS) were operated under different temperatures, carbon loadings and solids retention times (SRTs). These two types of hybrid systems were compared, focusing on the nitrification capacity and the nitrifiers population of the media and suspended biomass alongside other process performances such as carbonaceous and total nitrogen (TN) removal rates. At high temperatures and loadings rates, both processes were fully nitrifying and achieved similarly high carbonaceous removal rates. However, under these conditions, the IFAS configuration performed better in terms of TN removal. Lower temperatures and carbon loadings led to lower carbonaceous removal rates for the MBBR/AS configuration, whereas the IFAS configuration was not affected. However, the nitrification capacity of the IFAS process decreased significantly under these conditions and the MBBR/AS process was more robust in terms of nitrification. Ammonia oxidising bacteria (AOB) and nitrite oxidising bacteria (NOB) population counts accurately reflected the changes in nitrification capacity. However, significantly less NOBs than AOBs were observed, without noticeable nitrite accumulation, suggesting that the characterisation method used was not as sensitive for NOBs and/or that the NOBs had a higher activity than the AOBs.


1991 ◽  
Vol 23 (7-9) ◽  
pp. 1417-1425 ◽  
Author(s):  
Sheng-Kun Chen ◽  
Chin-Kun Juaw ◽  
Sheng-Shung Cheng

Two sets of fixed-film biological processes were operated separately for nitritification of amnonium and for denitritification of nitrite associated with organic compounds. High strength amnonium wastewater (50-1000 mg NH4+-N/l) could be effectively nitritified by a draft-tube fluidized bed which was operated at an extremely high loading of 1.0 kg NH4−1-N/m3.day with 95% amnonium conversion and 60 to 95% nitrite formation. Additionally, a biofilm fixed-bed was employed to denitritify the high strength nitrite (200 to 1000 mg NO2−-N/l) associated with organic compounds of glucose, acetate and benzoic acid. Complete nitrite removal could be achieved with sufficient HRT and COD/NO2−-N ratio. The conversion ratios were estimated experimentally at 2.5 for glucose and acetate, and 2.0 g ∆COD/g ∆NO2−-N for benzoic acid. A proposed process of an aerobic nitritifying biofilm reactor combined with an anoxic denitritifying biofilm reactor in series could be employed for complete nitrogen removal.


2005 ◽  
Vol 24 (2) ◽  
pp. 173-183 ◽  
Author(s):  
N. Bernet ◽  
O. Sanchez ◽  
D. Cesbron ◽  
J.-P. Steyer ◽  
J.-P. Delgenès

2013 ◽  
Vol 69 (6) ◽  
pp. 1227-1233 ◽  
Author(s):  
Vojtech Kouba ◽  
Michael Catrysse ◽  
Hana Stryjova ◽  
Ivana Jonatova ◽  
Eveline I. P. Volcke ◽  
...  

The application of nitrification–denitrification over nitrite (nitritation–denitritation) with municipal (i.e. diluted and cold (or low-temperature)) wastewater can substantially improve the energy balance of municipal wastewater treatment plants. For the accumulation of nitrite, it is crucial to inhibit nitrite-oxidizing bacteria (NOB) with simultaneous proliferation of ammonium-oxidizing bacteria (AOB). The present study describes the effect of the influent total ammonium nitrogen (TAN) concentration on AOB and NOB activity in two moving bed biofilm reactors operated as sequencing batch reactors (SBR) at 15 °C (SBR I) and 21 °C (SBR II). The reactors were fed with diluted reject water containing 600, 300, 150 and 75 mg TAN L−1. The only factor limiting NOB activity in these reactors was the high concentrations of free ammonia and/or free nitrous acid (FNA) during the SBR cycles. Nitrite accumulation was observed with influents containing 600, 300 and 150 mg TAN L−1 in SBR I and 600 and 300 in SBR II. Once nitrate production established in the reactors, the increase of influent TAN concentration up to the original 600 mg TAN L−1 did not limit NOB activity. This was due to the massive development of NOB clusters throughout the biofilm that were able to cope with faster formation of FNA. The results of the fluorescence in situ hybridization analysis preliminarily showed the stratification of bacteria in the biofilm.


2012 ◽  
Vol 209-211 ◽  
pp. 2039-2044
Author(s):  
Jian Lei Gao ◽  
Bing Nan Lv ◽  
Yi Xin Yan ◽  
Jian Ping Wu

A full-scale nitrogen removal system composed of an anoxic tank, an anaerobic tank, a micro-aerobic tank and an aerobic tank (A2O2) was established to treat 15,000 t/d high strength ammonia wastewater of a nitrogenous fertilizer factory. After the first stage of commissioning test, the stable operation of short-cut nitrification and denitrification has been realized at the normal temperature. The results showed that under the conditions of COD/TN ratio of only 1~2, the average removal efficiency of COD、NH3-N and TN achieved 80%, 96% and 54%, respectively without extra addition of alkalinity or carbon source, and the effluent quality was better than the requirement of the《Synthetic ammonia industrial water contamination emission standard》(draft for comment). The variation of nitrogen compounds concentration and operational parameters of pH, DO were investigated in each tank of A2O2 system. The results showed that the short-cut nitrification was stabilized in the micro-aerobic tank through the control of DO concentration (about 0.6 mg/L). Although the pH of micro-aerobic tank was only 6.6 which inhibited the growth of nitrite bacteria, the nitrite accumulation ratio reached about 48 %, closing to the criteria for judgment of short-cut nitrification of 50%. During operation, the process parameters of the A2O2 system such as reflux ratio of the mixed liquids, sludge load, sludge concentration, sludge age and SVI were all maintained in normal range, and small fluctuation of process parameters didn’t show obvious influence on short-cut nitrification.


Water ◽  
2021 ◽  
Vol 13 (18) ◽  
pp. 2484
Author(s):  
César Huiliñir ◽  
Vivian Fuentes ◽  
Carolina Estuardo ◽  
Christian Antileo ◽  
Ernesto Pino-Cortés

This work aimed to achieve partial nitrification (PN) in a Sequencing Moving Bed Biofilm Reactor SMBBR with zeolite as a biomass carrier by using sulfide pulses in the presence of organic matter as an inhibitor. Two conditions were evaluated: sulfide (HS−) = 5 mg S/L and vvm (air volume per liquid volume per minute, L of air L−1 of liquid min−1) = 0.1 (condition 1); and a HS− = 10 mg S/L and a vvm = 0.5 (condition 2). The simultaneous effect of organic matter and sulfide was evaluated at a Chemical Oxygen Demand (COD) = 350 mg/L and HS− = 5 mg S/L, with a vvm = 0.5. As a result, using the sulfide pulse improved the nitrite accumulation in both systems. However, Total Ammonia Nitrogen (TAN) oxidation in both processes decreased by up to 60%. The simultaneous presence of COD and sulfide significantly reduced the TAN and nitrite oxidation, with a COD removal yield of 80% and sulfide oxidation close to 20%. Thus, the use of a sulfide pulse enabled PN in a SMBBR with zeolite. Organic matter, together with the sulfide pulse, almost completely inhibited the nitrification process despite using zeolite.


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