Removal of heavy metals from fly ash and the impact on its quality

2002 ◽  
Vol 77 (3) ◽  
pp. 389-395 ◽  
Author(s):  
Henk W Nugteren ◽  
Maria Janssen-Jurkovícová ◽  
Brian Scarlett
2000 ◽  
Vol 42 (1-2) ◽  
pp. 347-352
Author(s):  
E.H. Smith ◽  
S. Chatterjee

Waste shot-blast fines from surface finishing processes have been demonstrated to be effective for removing heavy metals from solution by adsorption.The technology offers the potential for inexpensive recovery and reuse of a material normally discarded as a solid waste. While metal removals compare favorably with those achieved by commercial sorbents, applications issues such as the impact of background metal-complexing agents require investigation. The presence of oxalic acid, a complexing organic compound, impacted cadmium and lead adsorption in accordance with predictions from metal speciation equilibria; i.e., a small but measurable reduction in lead removal was observed, but cadmium adsorption was relatively unaffected. The effects were repeated in dynamic column experiments, with lead removals reduced by 15 to 20% in the presence of the ligand. Efforts to model adsorption equilibria in the presence of oxalic acid did not fully capture the reduced lead removal, presumably because the model does not consider the complete formation of metal-oxalic acid complexes prior to contact with the sorbent.


2014 ◽  
Vol 264 ◽  
pp. 1-7 ◽  
Author(s):  
Hu-Chun Tao ◽  
Tao Lei ◽  
Gang Shi ◽  
Xiao-Nan Sun ◽  
Xue-Yan Wei ◽  
...  

RSC Advances ◽  
2019 ◽  
Vol 9 (28) ◽  
pp. 16018-16027 ◽  
Author(s):  
Lihui Gao ◽  
Jillian L. Goldfarb

Heterogeneous biochar via pyrolysis of wheat straw and fly ash with chemical adsorption mechanism; cobalt shows higher capacity and rate.


2001 ◽  
Vol 4 (3) ◽  
pp. 77-83 ◽  
Author(s):  
Hee-chan Cho ◽  
Dal-young Oh ◽  
Hyo-Taek Chon

2011 ◽  
Vol 84-85 ◽  
pp. 626-630 ◽  
Author(s):  
Xi Peng ◽  
Bin Quan Jiao ◽  
Lin Yu ◽  
Dong Wei Li ◽  
Ke Yang

Since MSWI fly ash enriches heavy metals and many toxic components and these components would potentially leach when the ashes are land filled, it is regulated as hazardous waste in many countries. Electrokinetic removal, an electrochemically assisted extraction method, has recently been adopted as a new method for removal of heavy metals from MSWI fly ashes. But the generation of metal hydroxide precipitation near the cathode decreased conductivity of electrokinetic removal system and limited metal extraction from the sample area. In this study, cation exchange membrane was used in electrokinetic removal experiment to improve this method. After 192 hours of electrokinetic removal, about 15%Cd,20%Pb, 30% Zn, and 10% As was removed from 2.850kg MSWI fly ash. It showed positive effect compared to the trial test. But there still exists some problems, such as low removal efficiency. Further work should be done to solve it.Moreover, the high conductivity in fly ash limits the current , which in turn causes low electroosmotic flow. While electroosmotic flow is the main factor leting the heavy meatals release from fly ash, it would become the focus in further experiment to look for ways increasing the electroosmotic flow in sample cell.


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