Self‐purging microwave pyrolysis: an innovative approach to convert oil palm shell into carbon‐rich biochar for methylene blue adsorption

2019 ◽  
Vol 94 (5) ◽  
pp. 1397-1405 ◽  
Author(s):  
Sieng‐Huat Kong ◽  
Su Shiung Lam ◽  
Peter Nai Yuh Yek ◽  
Rock Keey Liew ◽  
Nyuk Ling Ma ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Oil Palm ◽  
Innovative Approach ◽  
Methylene Blue Adsorption ◽  
Microwave Pyrolysis ◽  
Palm Shell ◽  
Oil Palm Shell

scholarly journals Adsorption of Phenol and Methylene Blue in Solution by Oil Palm Shell Activated Carbon Prepared by Chemical Activation

2018 ◽  
Vol 34 (4) ◽  
pp. 2043-2050 ◽  
Author(s):  
Buhani Buhani ◽  
Megafhit Puspitarini ◽  
Rahmawaty Rahmawaty ◽  
Suharso Suharso ◽  
Mita Rilyanti ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Oil Palm ◽  
Binary Systems ◽  
Chemical Activation ◽  
Palm Shell ◽  
Oil Palm Shell ◽  
Before And After ◽  
Single And Binary Systems ◽  
Paired Condition ◽  
Mb Adsorption

In this research, it has been performed carbon activation of oil palm shells (CAC) prepared by chemical treatment as adsorbents of phenol and methylene blue (MB) in solution either in the form of single or in pair solution. The activation of carbon from the oil palm shells was done physically at a temperature of 700°C for 1 hour continued with chemical activation using 10% H3PO4 for 24 hours. Identification of functional groups on the carbon from oil palm shell before and after chemically activated was performed using infrared spectrophotometer (IR) and analysis of its surface morphology was carried out using scanning electron microscope (SEM). The phenol and MB adsorption process was performed in single and binary systems using the batch method. The adsorption of phenol on CAC is optimum at pH 8 while MB at pH 11 with optimum contact time of 90 min for phenol and 120 min for MB respectively. The phenol and MB adsorption data on the CAC in the single system follow the pseudo-second-order kinetics model with the adsorption rate constant of 0.399 and 0.769 g mmol-1 min-1 respectively. The adsorption isotherms of phenol and MB in CAC tend to follow Freundlich adsorption isotherm pattern with the adsorption intensity factor (n) for phenol, MB, phenol/MB, and MB/phenol: 1.739, 1.341, 1.334, and 1.293 respectively. The adsorbent of CAC is effective to remove phenol and MB in solution, either in single or paired condition.

scholarly journals Activated carbon and palm oil fuel ash as microwave absorbers for microwave-assisted pyrolysis of oil palm shell waste

RSC Advances ◽  
2020 ◽  
Vol 10 (53) ◽  
pp. 32058-32068
Author(s):  
Sunisa Chuayjumnong ◽  
Seppo Karrila ◽  
Saysunee Jumrat ◽  
Yutthapong Pianroj
Keyword(s):  
Activated Carbon ◽  
Palm Oil ◽  
Oil Palm ◽  
Palm Oil Fuel Ash ◽  
Microwave Pyrolysis ◽  
Microwave Absorbers ◽  
Palm Shell ◽  
Oil Palm Shell ◽  
Fuel Ash ◽  
Oil Fuel

In this study, the effects of two microwave absorbers (MWAb) or catalysts, namely activated carbon (AC) and palm oil fuel ash (POFA), were investigated in microwave pyrolysis of oil palm shell (OPS).

Simple microwave pyrolysis kinetics of lignocellulosic biomass (oil palm shell) with activated carbon and palm oil fuel ash catalysts

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Saysunee Jumrat ◽  
Teerasak Punvichai ◽  
Wichuta Sae-jie ◽  
Seppo Karrila ◽  
Yutthapong Pianroj
Keyword(s):  
Activated Carbon ◽  
Palm Oil ◽  
Oil Palm ◽  
Pyrolysis Kinetics ◽  
Palm Oil Fuel Ash ◽  
Microwave Pyrolysis ◽  
Palm Shell ◽  
Oil Palm Shell ◽  
Fuel Ash ◽  
Oil Fuel

Abstract The important parameters characterizing microwave pyrolysis kinetics, namely the activation energy (E a) and the rate constant pre-exponential factor (A), were investigated for oil palm shell mixed with activated carbon and palm oil fuel ash as microwave absorbers, using simple lab-scale equipment. These parameters were estimated for the Kissinger model. The estimates for E a ranged within 31.55–58.04 kJ mol−1 and for A within 6.40E0–6.84E+1 s−1, in good agreement with prior studies that employed standard techniques: Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). The E a and A were used with the Arrhenius reaction rate equation, solved by the 4th order Runge-Kutta method. The statistical parameters coefficient of determination (R 2) and root mean square error (RMSE) were used to verify the good fit of simulation to the experimental results. The best fit had R 2 = 0.900 and RMSE = 4.438, respectively, for MW pyrolysis at power 440 W for OPS with AC as MW absorber.

scholarly journals Pengaruh Variasi Suhu Hidrotermal dan Aktivator Kalium Hidroksida (KOH) terhadap Kemampuan Hydrochar sebagai Adsorben pada Proses Adsorpsi Limbah Cair Metilen Biru

2020 ◽  
Vol 14 (2) ◽  
pp. 160
Author(s):  
Aziz Askaputra ◽  
Ahmad Tawfiequrahman Yuliansyah
Keyword(s):  
Methylene Blue ◽  
Removal Efficiency ◽  
Oil Palm ◽  
Hydrothermal Carbonization ◽  
Activation Process ◽  
Carbonization Process ◽  
Palm Shell ◽  
Oil Palm Shell ◽  
Water Effects ◽  
Higher Temperature

Oil palm shell is one of biomass-wastes which is abundantly found in palm oil industries. Its economical value can be enhanced by converting it into hydrochar using a hydrothermal carbonization process (HTC). In this study, preparation of oil palm shell hydrochar was performed and the material was used as adsorbent to remove methylene blue from waste water. Effects of HTC temperature, KOH activator concentration, and adsorption time were studied. Functional groups of hydrochar were evaluated by Fourier transform infrared (FTIR) spectroscopy. Meanwhile, the uptake capacity of hydrochar to adsorp methylene blue was measured by using UV-Vis spectrophotometer. The results showed that dehydration and decarboxylation reactions took place more progressively at the higher temperature of HTC. It was also found that activation process resulted higher removal efficiency of methylene blue. The highest adsorption capacity (16.58 mg/g, with removal efficiency 99.51%) was obtained by hydrochar prepared by HTC 270°C, KOH 1.5 N, and carried out for 80 minutes.Keywords: activator; adsorption; hydrothermal carbonization; methylene blue; oil palm shellA B S T R A KTempurung kelapa sawit merupakan salah satu limbah biomassa yang jumlahnya cukup melimpah di industri minyak kelapa sawit. Nilai ekonomi tempurung kelapa sawit dapat ditingkatkan, salah satunya melalui hydrothermal carbonization process (HTC). Dalam penelitian ini, hydrochar dari tempurung kelapa sawit dibuat dan digunakan sebagai adsorben untuk menjerap metilen biru dari limbah cair. Dalam hal ini, akan dipelajari pengaruh suhu HTC, konsentrasi aktivator KOH, dan durasi adsorpsi. Gugus fungsional hydrochar dianalisis dengan FT-IR spectroscopy, sementara itu kapasitas adsorpsi terhadap metilen biru diukur dengan spektrofotometer UV-Vis. Hasil percobaan menunjukkan bahwa reaksi dehidrasi dan dekarboksilasi pada kondisi hidrotermal terjadi lebih cepat pada suhu HTC yang lebih tinggi. Selain itu, proses aktivasi dengan KOH terbukti dapat meningkatkan efisiensi penyisihan metilen biru. Kapasitas adsorpsi maksimum sebesar 16,58 mg/g (dengan efisiensi penyisihan 99,51%) dihasilkan dari adsorpsi dengan menggunakan hydrochar yang diperoleh dari HTC suhu 270 °C, diaktivasi dengan KOH 1,5 N dan durasi adsorpsi selama 80 menit.Kata kunci: adsorpsi; aktivator; karbonisasi hidrotermal; metilen biru; tempurung kelapa sawit 

Pengaruh Tekanan dan Penggunaan Conplast terhadap Sifat Mekanik Eternit dari Abu Cangkang Sawit

2016 ◽  
Vol 8 (15) ◽  
pp. 47-54
Author(s):  
Haspiadi Haspiadi
Keyword(s):  
Mechanical Properties ◽  
Oil Palm ◽  
Modulus Of Elasticity ◽  
Modulus Of Rupture ◽  
Palm Shell ◽  
Oil Palm Shell ◽  
Density Values ◽  
Test Result

The purpose of this research is to know the influence of pressure and use of conplast against mechanical properties which are a Modulus of Elasticity (MOE) and Modulus of Rupture (MOR) of plasterboard. The study is done because still low quality of plasterboard made from a mixture of ashes of oil-palm shell especially of the mechanical properties compared to the controls. The method of this reserach used variation of printed pressure and the addition of conplast. Test result is obtained that the highest value of Modulus of Elasticity (MOE) 90875.94 Kg/cm2, Modulus of Rupture (MOR) 61.16 Kg/cm2 and density values in generally good printed at the pressure 60 g/cm3 and the addition of conplast 25% as well as the composition of the ash of palm shell oil 40%: limestone 40%: cement 15%: fiber 5% and 300 mL of water. ABSTRAK Tujuan dari penelitian ini adalah untuk mengetahui pengaruh tekanan dan penggunaan conplast terhadap sifat mekanik yaitu kuat lentur dan keteguhan patah eternit berbahan dasar abu cangkang sawit. Penelitian ini dilakukan karena masi rendahnya mutu eternit berbahan campuran abu cangkang sawit dari bolier khususnya sifat mekanik dibandingkan dengan kontrol. Metode penelitian yang digunakan adalah dengan variasi tekanan cetak dan penambahan conplast. Hasil uji diperoleh bahwa kuat lentur tertinggi sebesar 90875,94 Kg/cm2 dan keteguhan patah sebesar 61,16 Kg/cm2, yang dicetak pada tekanan 60 g/cm3 dan penambahan conplast 25% dengan komposisi  abu cangkang sawit 40 %: kapur 40 % : semen 15 %: serat 5 % dan air 300 mL.Kata Kunci :  Abu cangkang sawit, conplast, kuat lentur, keteguhan patah.

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