Lipase-catalyzed synthesis of long-chain cellulose esters using ionic liquid mixtures as reaction media

2016 ◽  
Vol 92 (6) ◽  
pp. 1203-1210 ◽  
Author(s):  
Fengli Wang ◽  
Guanglei Zhao ◽  
Xiongfei Lang ◽  
Junrong Li ◽  
Xiaofeng Li
Keyword(s):  
Ionic Liquid ◽  
Liquid Mixtures ◽  
Cellulose Esters ◽  
Reaction Media ◽  
Long Chain

Enhanced solubilization and extraction of hydrophobic bioactive compounds using water/ionic liquid mixtures

2016 ◽  
Vol 18 (12) ◽  
pp. 3549-3557 ◽  
Author(s):  
Wenbin Jin ◽  
Qiwei Yang ◽  
Binbin Huang ◽  
Zongbi Bao ◽  
Baogen Su ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Bioactive Compounds ◽  
Extraction Efficiency ◽  
Liquid Mixtures ◽  
Long Chain

The developed water/LCC-IL (long-chain carboxylate ionic liquid) mixtures exhibited extremely high solubilities for various hydrophobic bioactive compounds (HBCs) and excellent extraction efficiency for tocopherols.

General Trend of Negative Transference Number in Li Salt/Ionic Liquid Mixtures

2019 ◽  
Author(s):  
Nicola Molinari ◽  
Jonathan P. Mailoa ◽  
Boris Kozinsky
Keyword(s):  
Ionic Liquid ◽  
Transference Number ◽  
Liquid Mixtures ◽  
Single Linkage ◽  
Self Diffusion ◽  
Wide Range ◽  
Single Linkage Cluster ◽  
Concentrated Solution ◽  
The One ◽  
Dynamics Simulations

We show that strong cation-anion interactions in a wide range of lithium-salt/ionic liquid mixtures result in a negative lithium transference number, using molecular dynamics simulations and rigorous concentrated solution theory. This behavior fundamentally deviates from the one obtained using self-diffusion coefficient analysis and agrees well with experimental electrophoretic NMR measurements, which accounts for ion correlations. We extend these findings to several ionic liquid compositions. We investigate the degree of spatial ionic coordination employing single-linkage cluster analysis, unveiling asymmetrical anion-cation clusters. Additionally, we formulate a way to compute the effective lithium charge that corresponds to and agrees well with electrophoretic measurements and show that lithium effectively carries a negative charge in a remarkably wide range of chemistries and concentrations. The generality of our observation has significant implications for the energy storage community, emphasizing the need to reconsider the potential of these systems as next generation battery electrolytes.<br>

Rapid relaxation NMR measurements to predict rate coefficients in ionic liquid mixtures. An examination of reaction outcome changes in a homologous series of ionic liquids

2021 ◽  
Author(s):  
Daniel C Morris ◽  
Stuart W Prescott ◽  
Jason B Harper
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Homologous Series ◽  
Rate Coefficient ◽  
Liquid Mixtures ◽  
Solvent Mixture ◽  
Rate Coefficients ◽  
Substitution Process

A series of ionic liquids based on the 1-alkyl-3-methylimidazolium cations were examined as components of the solvent mixture for a bimolecular substitution process. The effects on both the rate coefficient...

Eutectic ionic liquid mixtures and their effect on CO2 solubility and conductivity

RSC Advances ◽  
2015 ◽  
Vol 5 (63) ◽  
pp. 51407-51412 ◽  
Author(s):  
Anna S. Ivanova ◽  
Thomas Brinzer ◽  
Elliot A. Roth ◽  
Victor A. Kusuma ◽  
John D. Watkins ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Binary System ◽  
Liquid Mixtures ◽  
Short Chain ◽  
Co2 Solubility

A simple binary system of compounds resembling short-chain versions of popular ionic liquids has been shown to have alloying properties.

Synthesis of Nickel Hydroxide with Different Morphologies Using an Ionic Liquid

2010 ◽  
Vol 663-665 ◽  
pp. 1163-1166
Author(s):  
Cun Ying Xu ◽  
Yi Xin Hua
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Ionic Liquid ◽  
Volume Ratio ◽  
X Ray Diffraction ◽  
X Ray ◽  
Reaction Media ◽  
Solvothermal Conditions ◽  
Facile Route ◽  
Scanning Electron

A new and facile route has been developed to synthesize β-Ni(OH)2 nanostructures using ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4) as reaction media under solvothermal conditions. The β-Ni(OH)2 with different morphologies, such as nanoflakes, nanoplatelet and nanorods, can be obtained by controlling the volume ratio of the ionic liquid to water and reaction temperature. The as-prepared products were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM).

scholarly journals Two-Stage Prediction of the Effects of Imidazolium and Pyridinium Ionic Liquid Mixtures on Luciferase

Molecules ◽  
2014 ◽  
Vol 19 (5) ◽  
pp. 6877-6890 ◽  
Author(s):  
Hui-Lin Ge ◽  
Shu-Shen Liu ◽  
Bing-Xia Su ◽  
Xiang-Wei Zhu
Keyword(s):  
Ionic Liquid ◽  
Liquid Mixtures ◽  
Two Stage

Using Ionic Liquid Mixtures To Improve the SO2 Absorption Performance in Flue Gas

2017 ◽  
Vol 31 (2) ◽  
pp. 1771-1777 ◽  
Author(s):  
Wen Li ◽  
Ying Liu ◽  
Lihong Wang ◽  
Guanjun Gao
Keyword(s):  
Ionic Liquid ◽  
Flue Gas ◽  
Liquid Mixtures ◽  
Absorption Performance ◽  
So2 Absorption
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