scholarly journals Liquid-liquid extraction of cadmium(II) by Cyanex 923 and its application to a solid-supported liquid membrane system

2005 ◽  
Vol 80 (9) ◽  
pp. 967-972 ◽  
Author(s):  
Ana María Rodríguez ◽  
Dulce Gómez-Límón ◽  
Francisco José Alguacil
Molecules ◽  
2020 ◽  
Vol 25 (22) ◽  
pp. 5238
Author(s):  
Francisco José Alguacil

Ionic liquid A327H+Cl− was generated by reaction of tertiary amine A327 and HCl, and the liquid-liquid extraction of indium(III) from the HCl medium by this ionic liquid dissolved in Solvesso 100 was investigated. The extraction reaction is exothermic. The numerical analysis of indium distribution data suggests the formation of A327H+InCl4− in the organic phase. The results derived from indium(III) extraction have been implemented in a supported liquid membrane system. The influence of the stirring speed (600–1200 min−1), carrier concentration (2.5–20% v/v) in the membrane phase, and indium concentration (0.01–0.2 g/L) in the feed phase on metal transport have been investigated.


2015 ◽  
Vol 1 (01) ◽  
pp. 54-60
Author(s):  
G Muthuraman

The liquid-liquid extraction (LLE) and supported liquid membrane (SLM) studies of reactive dyes namely Gold Yellow (GYHE-R) and Reactive Green HE 4BD (RGHE-4BD) from aqueous solution using Aliquot 336 as the carrier has been investigated. Polytetrafluoroethylene (PTFE) membrane with 0.5 μm pore size has been used after impregnated with Aliquot 336 in dichloromethane. In liquid liquid extraction the following parameters had been optimized; pH of feed, diluent, carrier , strip and dye concentration and the same parameters have been applied to supported liquid membrane (SLM) study to transport dye from aqueous solution.The main advantages SLM study is; the extraction and stripping as single stage process and low consumption of carrier in the membrane phase compared to the solvent extraction process. The other parameters such as transport time, stirring speed and mechanism of dye transport has also studied by SLM. The percentage of transport of dye and flux rate increases with increasing time. The stability of membrane is satisfactory over 5 days.


2012 ◽  
Vol 75 (9-10) ◽  
pp. 513-520 ◽  
Author(s):  
Kessy F. Kilulya ◽  
Titus A. M. Msagati ◽  
Bhekie B. Mamba ◽  
J. Catherine Ngila ◽  
Tamara Bush

Author(s):  
Hossein Kamran Haghighi ◽  
Mehdi Irannajad ◽  
Maria Teresa Coll ◽  
Ana Maria Sastre

The transport of germanium from an aqueous solution containing oxalic acid was studied using a flat sheet supported liquid membrane (FSSLM) system. Cyanex 923 immobilized in a polytetrafluoroethylene membrane was employed as a carrier. The solution chemistry and related diagrams were applied to study the transport of germanium. The effectual parameters such as oxalic acid, the carrier, and strip reagent concentrations were evaluated in this study. Based on the results, the oxalic acid concentration of 0.075 mol/L and the carrier concentration of 20 %v/v were the condition in which the efficient germanium transport occurred. Among strip reagents tested, NaOH had the best efficiency to transport germanium through the supported liquid membrane system. Furthermore, the permeation model was obtained to calculate the mass transfer resistances. According to the results, the values of 1 and 1345 s/cm were evaluated for Δm and Δf, respectively. The model curve showed that the P value reached a steady state at higher concentrations of the carrier because the viscosity governed the transport phenomenon.


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