Synthesis of Two-Dimensional Terbenzodithiophene-based Derivative by Palladium-catalyzed C─H Benzannulation and Its Donor-Acceptor Copolymers for Organic Photovoltaics

2017 ◽  
Vol 65 (1) ◽  
pp. 133-140
Author(s):  
Fong-Yi Cao ◽  
Yung-Lung Chen ◽  
Yu-Ying Lai ◽  
Yen-Ju Cheng
2016 ◽  
Vol 7 (7) ◽  
pp. 1486-1493 ◽  
Author(s):  
Zhongsheng Xu ◽  
Guoping Luo ◽  
Jiangsheng Yu ◽  
Xinxing Yin ◽  
Enwei Zhu ◽  
...  

Two donor–acceptor alternating polymers of bis(octylthio)thienyl BDT and fluorinated BT or 5-dodecylthienyl-6-fluorobenzo[c][1,2,5]thiadiazole were designed for organic photovoltaics.


2020 ◽  
Vol 22 (46) ◽  
pp. 27413-27424
Author(s):  
Michele Turelli ◽  
Domenico Alberga ◽  
Gianluca Lattanzi ◽  
Ilaria Ciofini ◽  
Carlo Adamo

Transport mechanisms in a set of crystal polymorphs of a donor–acceptor dyad used in a SMOSC, are revealed through the comparison of polymorphs’ transport efficiencies. The findings offer hints on how to improve the design of better performing dyads.


2020 ◽  
Author(s):  
Ain Uddin ◽  
Kyle Plunkett

A series of donor-acceptor copolymers with dicyclopenta[cd,jk]pyrene and dicyclopenta[cd,lm]perylene acceptor units was prepared via palladium catalyzed cyclopenta-annulation reactions. The acceptor units were paired with diethynyl containing donor groups based on benzo[1,2-b:4,5-b']dithiophene, thieno[3,2-b]thiophene, and 4-octyl-4H-dithieno[3,2-b:2',3'-d]pyrrole to create six polymer variants. The cyclopentannulation polymerization resulted in copolymers with molecular weights (Mn) of 6-14 kDa and broad light absorption in the visible region with band gaps of 1.38-1.85 eV. The synthetic methodology, as well as optoelectronic properties, including thin-film absorption and cyclic voltammetry, of the donor-acceptor copolymers are presented.<br> <br><br>


2017 ◽  
Vol 8 (13) ◽  
pp. 2764-2773 ◽  
Author(s):  
Monroe P. Griffin ◽  
Raluca Gearba ◽  
Keith J. Stevenson ◽  
David A. Vanden Bout ◽  
Andrei Dolocan

2021 ◽  
Author(s):  
Thomas Chaney ◽  
Andrew Levin ◽  
Sebastian Schneider ◽  
Michael F. Toney

Precise control of the complex morphology of organic photovoltaic bulk heterojunction (BHJ) active layers remains an important yet challenging approach for improving power conversion efficiency. Of particular interest are the...


2020 ◽  
Vol 53 (18) ◽  
pp. 7740-7748
Author(s):  
Huai-Hsuan Liu ◽  
Shao-Ling Chang ◽  
Kuo-Hsiu Huang ◽  
Fong-Yi Cao ◽  
Kuang-Yi Cheng ◽  
...  

2020 ◽  
Vol 4 (4) ◽  
pp. 2026-2034
Author(s):  
Samuel S. Lawton ◽  
Daniel Warr ◽  
Luís M. A. Perdigão ◽  
Yujing Chang ◽  
Agnieszka Pron ◽  
...  

Organic photovoltaics (OPVs) are attracting significant attention due to the growing demand for economically viable and renewable energy sources.


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