Kinetic Determination of GA by the BZ Oscillating Chemical System

2004 ◽  
Vol 51 (1) ◽  
pp. 7-11 ◽  
Author(s):  
Yanjie Dong ◽  
Ke Gai ◽  
Xinxing Gong
Keyword(s):  
Chemical System ◽  
Kinetic Determination ◽  
Oscillating Chemical System

scholarly journals Kinetic Determination of Paracetamol using a Novel Belousov-Zhabotinskii Oscillating System Catalyzed by a Tetraazamacrocyclic Complex

2012 ◽  
Vol 9 (3) ◽  
pp. 1412-1421 ◽  
Author(s):  
Gang Hu ◽  
Qin Wang ◽  
Min Meng ◽  
Ming Ying Lu ◽  
Fu Sheng Zhao ◽  
...  
Keyword(s):  
Linear Relationship ◽  
Malic Acid ◽  
Analytical Method ◽  
Oscillation Amplitude ◽  
Probable Mechanism ◽  
Chemical System ◽  
Kinetic Determination ◽  
Tetraazamacrocyclic Complex ◽  
Oscillating Chemical System

A new analytical method for determination of paracetamol is proposed. This method is based on a novel B-Z oscillating system, which involves a Tetraazamacrocyclic Complex [CuL](ClO4)2as catalyst and malic acid as the substrate. The ligand L in the complex is 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene. By perturbation mount of paracetamol on the B-Z system, there is a linear relationship between the changes in the oscillation amplitude and the logarithm of paracetamol concentration in the range 5×10-7to 2×10-4M, with a correlation coefficient of 0.99743. The effects of influential variables, such as the concentration of reaction components, temperature and on the determinations were studied. The probable mechanism involving the perturbation of paracetamol on the oscillating chemical system was also discussed.

Kinetic determination of tryptophan by using the B-Z oscillating chemical system

Amino Acids ◽  
2008 ◽  
Vol 36 (3) ◽  
pp. 391-397 ◽  
Author(s):  
Jinzhang Gao ◽  
Jie Qu ◽  
Wu Yang ◽  
Xiaoxia Wei ◽  
Hongxia Dai ◽  
...  
Keyword(s):  
Chemical System ◽  
Kinetic Determination ◽  
Oscillating Chemical System

Trace determination of cobalt ion by using malic acid–malonic acid double substrate oscillating chemical system

2008 ◽  
Vol 19 (9) ◽  
pp. 1103-1107 ◽  
Author(s):  
Jie Wang ◽  
Wu Yang ◽  
Jie Ren ◽  
Miao Guo ◽  
Xiao Dong Chen ◽  
...  
Keyword(s):  
Malonic Acid ◽  
Malic Acid ◽  
Chemical System ◽  
Trace Determination ◽  
Cobalt Ion ◽  
Double Substrate ◽  
Oscillating Chemical System

Determination of Complex Reaction Mechanisms

2006 ◽  
Author(s):  
John Ross ◽  
Igor Schreiber ◽  
Marcel O. Vlad
Keyword(s):  
Reaction Mechanism ◽  
Reaction Mechanisms ◽  
Reaction Pathway ◽  
Chemical Species ◽  
Rate Coefficients ◽  
Chemical System ◽  
Evolutionary Development ◽  
Complex Reaction ◽  
Oscillatory Reactions

In a chemical system with many chemical species several questions can be asked: what species react with other species: in what temporal order: and with what results? These questions have been asked for over one hundred years about simple and complex chemical systems, and the answers constitute the macroscopic reaction mechanism. In Determination of Complex Reaction Mechanisms authors John Ross, Igor Schreiber, and Marcel Vlad present several systematic approaches for obtaining information on the causal connectivity of chemical species, on correlations of chemical species, on the reaction pathway, and on the reaction mechanism. Basic pulse theory is demonstrated and tested in an experiment on glycolysis. In a second approach, measurements on time series of concentrations are used to construct correlation functions and a theory is developed which shows that from these functions information may be inferred on the reaction pathway, the reaction mechanism, and the centers of control in that mechanism. A third approach is based on application of genetic algorithm methods to the study of the evolutionary development of a reaction mechanism, to the attainment given goals in a mechanism, and to the determination of a reaction mechanism and rate coefficients by comparison with experiment. Responses of non-linear systems to pulses or other perturbations are analyzed, and mechanisms of oscillatory reactions are presented in detail. The concluding chapters give an introduction to bioinformatics and statistical methods for determining reaction mechanisms.

Sign in / Sign up

Export Citation Format

Share Document