Total Synthesis of Mesembrine - The Construction of Quaternary Stereocenters by Gold-Catalyzed Diyne Desymmetrization

Constantin Czekelius

doi:10.1002/ijch.201700060

Total Synthesis of Mesembrine - The Construction of Quaternary Stereocenters by Gold-Catalyzed Diyne Desymmetrization

Israel Journal of Chemistry ◽

10.1002/ijch.201700060 ◽

2018 ◽

Vol 58 (5) ◽

pp. 568-577 ◽

Cited By ~ 4

Author(s):

Constantin Czekelius

Keyword(s):

Total Synthesis ◽

Quaternary Stereocenters

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ChemInform Abstract: Domino Double Michael-Claisen Cyclizations: A Powerful General Tool for Introducing Quaternary Stereocenters at C(4) of Cyclohexane-1,3-diones and Total Synthesis of Diverse Families of Sterically Congested Alkaloids.

ChemInform ◽

10.1002/chin.200907061 ◽

2009 ◽

Vol 40 (7) ◽

Author(s):

Teruhiko Ishikawa ◽

Kazuhiro Kudo ◽

Ken Kuroyabu ◽

Satoshi Uchida ◽

Takayuki Kudoh ◽

...

Keyword(s):

Total Synthesis ◽

Diverse Families ◽

Quaternary Stereocenters ◽

General Tool

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Retraction of “An Expeditious Route to Both Enantiomers of All Carbon Quaternary Stereocenters at C-3 Carbon of Lactams via [3,3]-Sigmatropic Rearrangement: Total Synthesis of (−)-Physostigmine”

Organic Letters ◽

10.1021/acs.orglett.7b03188 ◽

2017 ◽

Vol 19 (22) ◽

pp. 6264-6264 ◽

Cited By ~ 1

Author(s):

Ganesh Pandey ◽

Jagadish Khamrai ◽

Akash Mishra

Keyword(s):

Total Synthesis ◽

Sigmatropic Rearrangement ◽

Quaternary Stereocenters

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Synthesis of Cyclopentenones with C4-Quaternary Stereocenters via Stereospecific [3,3]-Sigmatropic Rearrangement and Applications in Total Synthesis of Sesquiterpenoids

Journal of the American Chemical Society ◽

10.1021/jacs.1c07966 ◽

2021 ◽

Author(s):

Weiping Zhou ◽

Arnaud Voituriez

Keyword(s):

Total Synthesis ◽

Sigmatropic Rearrangement ◽

Quaternary Stereocenters

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Generation of All-Carbon Quaternary Stereocenters at the C-3 Carbon of Lactams via [3,3]-Sigmatropic Rearrangement and Revision of Absolute Configuration: Total Synthesis of (−)-Physostigmine

Organic Letters ◽

10.1021/acs.orglett.7b03537 ◽

2017 ◽

Vol 20 (1) ◽

pp. 166-169 ◽

Cited By ~ 9

Author(s):

Ganesh Pandey ◽

Jagadish Khamrai ◽

Akash Mishra

Keyword(s):

Total Synthesis ◽

Absolute Configuration ◽

Sigmatropic Rearrangement ◽

Quaternary Stereocenters

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Toward the Total Synthesis of Palhinine A: Expedient Assembly of Multifunctionalized Isotwistane Ring System with Contiguous Quaternary Stereocenters

Organic Letters ◽

10.1021/ol301534r ◽

2012 ◽

Vol 14 (14) ◽

pp. 3696-3699 ◽

Cited By ~ 20

Author(s):

Guo-Biao Zhang ◽

Fang-Xin Wang ◽

Ji-Yuan Du ◽

Hu Qu ◽

Xiao-Yan Ma ◽

...

Keyword(s):

Total Synthesis ◽

Ring System ◽

Quaternary Stereocenters

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Toward the Total Synthesis of Maoecrystal V: Establishment of Contiguous Quaternary Stereocenters

Organic Letters ◽

10.1021/ol102446u ◽

2010 ◽

Vol 12 (24) ◽

pp. 5656-5659 ◽

Cited By ~ 38

Author(s):

Irina Baitinger ◽

Peter Mayer ◽

Dirk Trauner

Keyword(s):

Total Synthesis ◽

Maoecrystal V ◽

Quaternary Stereocenters

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ChemInform Abstract: An Expeditious Route to Both Enantiomers of All Carbon Quaternary Stereocenters at C-3 Carbon of Lactams via [3,3]-Sigmatropic Rearrangement: Total Synthesis of (-)-Physostigmine.

ChemInform ◽

10.1002/chin.201528258 ◽

2015 ◽

Vol 46 (28) ◽

pp. no-no

Author(s):

Ganesh Pandey ◽

Jagadish Khamrai ◽

Akash Mishra

Keyword(s):

Total Synthesis ◽

Sigmatropic Rearrangement ◽

Quaternary Stereocenters

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Generation of all carbon quaternary stereocenters at the C-3 carbon of piperidinones and pyrrolidinones and its application in natural product total synthesis

Tetrahedron ◽

10.1016/j.tet.2018.05.004 ◽

2018 ◽

Vol 74 (38) ◽

pp. 4903-4915 ◽

Cited By ~ 9

Author(s):

Ganesh Pandey ◽

Akash Mishra ◽

Jagadish Khamrai

Keyword(s):

Total Synthesis ◽

Natural Product ◽

Quaternary Stereocenters

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Asymmetric Construction of All-Carbon Quaternary Stereocenters by Chiral-Auxiliary-Mediated Claisen Rearrangement and Total Synthesis of (+)-Bakuchiol

Molecules ◽

10.3390/molecules171113330 ◽

2012 ◽

Vol 17 (11) ◽

pp. 13330-13344 ◽

Cited By ~ 15

Author(s):

Ken-ichi Takao ◽

Shu Sakamoto ◽

Marianne Touati ◽

Yusuke Kusakawa ◽

Kin-ichi Tadano

Keyword(s):

Total Synthesis ◽

Claisen Rearrangement ◽

Chiral Auxiliary ◽

Quaternary Stereocenters

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Domino Double Michael−Claisen Cyclizations: A Powerful General Tool for Introducing Quaternary Stereocenters at C(4) of Cyclohexane-1,3-diones and Total Synthesis of Diverse Families of Sterically Congested Alkaloids

The Journal of Organic Chemistry ◽

10.1021/jo801316s ◽

2008 ◽

Vol 73 (19) ◽

pp. 7498-7508 ◽

Cited By ~ 57

Author(s):

Teruhiko Ishikawa ◽

Kazuhiro Kudo ◽

Ken Kuroyabu ◽

Satoshi Uchida ◽

Takayuki Kudoh ◽

...

Keyword(s):

Total Synthesis ◽

Diverse Families ◽

Quaternary Stereocenters ◽

General Tool

Download Full-text