Catalytic Activity and Performance of Copper-Based Complexes Mediating Atom Transfer Radical Polymerization

2012 ◽  
Vol 52 (3-4) ◽  
pp. 276-287 ◽  
Author(s):  
Nicolay V. Tsarevsky
Keyword(s):  
Catalytic Activity ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
And Performance

scholarly journals Reusable Surface-Modified Bacterial Cellulose Based on Atom Transfer Radical Polymerization Technology with Excellent Catalytic Properties

Nanomaterials ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 1443 ◽  
Author(s):  
Xin Li ◽  
Quan Feng ◽  
Dawei Li ◽  
Narh Christopher ◽  
Huizhen Ke ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Atom Transfer Radical Polymerization ◽  
Bacterial Cellulose ◽  
Radical Polymerization ◽  
Membrane Surface ◽  
Catalytic Performance ◽  
Reusable Catalyst ◽  
High Catalytic Activity ◽  
Atom Transfer ◽  
Surface Modified

The high catalytic activity of membrane-binding gold nanoparticles (AuNPs) makes its application in oxidation or reduction an attractive challenge. Herein, surface-functionalized bacterial cellulose (BC-poly(HEMA)) was successfully prepared with 2-hydroxyethyl methacrylate (HEMA) as monomers via the atom transfer radical polymerization (ATRP) method. BC-poly(HEMA) was further utilized as not only reducing agent but also carrier for uniform distribution of the AuNPs in the diameter of about 8 nm on the membrane surface during the synthesis stage. The synthesized AuNPs/BC-poly(HEMA) exhibited excellent catalytic activity and reusability for reducing 4-nitrophenol (4-NP) from NaBH4. The results proved that the catalytic performance of AuNPs/BC-poly(HEMA) was affected by the surrounding temperature and pH, and AuNPs/BC-poly(HEMA) maintained the extremely high catalytic activity of AuNPs/BC-poly(HEMA) even after 10 reuses. In addition, no 4-NP was detected in the degradation solution after being stored for 45 days. The reusable catalyst prepared by this work shows a potential industrial application prospect.

Thermo-regulated phase separable catalysis (TPSC)-based atom transfer radical polymerization in a thermo-regulated ionic liquid

2014 ◽  
Vol 50 (66) ◽  
pp. 9266-9269 ◽  
Author(s):  
Xiangyang Du ◽  
Jinlong Pan ◽  
Mengting Chen ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Transition Metal ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Atom Transfer ◽  
Aget Atrp ◽  
First Time

A thermo-regulated phase separable catalysis (TPSC) system for AGET ATRP based on a thermo-regulated ionic liquid was developed for the first time. The corresponding transition metal catalysts could be easily recovered and reused several times with negligible loss of catalytic activity.

scholarly journals Organocatalyzed Atom Transfer Radical Polymerization: Perspectives on Catalyst Design and Performance

2017 ◽  
Vol 38 (13) ◽  
pp. 1700040 ◽  
Author(s):  
Jordan C. Theriot ◽  
Blaine G. McCarthy ◽  
Chern-Hooi Lim ◽  
Garret M. Miyake
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Catalyst Design ◽  
Atom Transfer ◽  
And Performance
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