Stereoselectivity and Chiral Recognition in the Electron-Transfer Reaction between Spinach Ferredoxin and Optically Active Cobalt(III) Complexes

1990 ◽  
Vol 73 (2) ◽  
pp. 346-352 ◽  
Author(s):  
Klaus Bernauer ◽  
Michel Monzione ◽  
Peter Schürmann ◽  
Véronique Viette
Keyword(s):  
Electron Transfer ◽  
Chiral Recognition ◽  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Optically Active

Basic Approach toward Sensor Searching for a Molecular Recognition Site of Electron Transfer Proteins

2006 ◽  
Vol 11-12 ◽  
pp. 343-346 ◽  
Author(s):  
Takashi Kato ◽  
Isao Takahashi ◽  
Yasuhiro Funahashi ◽  
Tomohiro Ozawa ◽  
Hideki Masuda
Keyword(s):  
Electron Transfer ◽  
Molecular Recognition ◽  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Optically Active ◽  
Recognition Site ◽  
Basic Study ◽  
Electron Transfer Proteins ◽  
Cytochrome C553 ◽  
Selective Behavior

As a basic study to search a molecular recognition site in electron transfer proteins, optically-active ruthenium complexes, [RuII/III(bcmaa)(bpy)] (BCMAA: N,Nbis( carboxymethyl)amino acid, BPY: 2,2’-bipyridine), were designed and prepared. The electron transfer reaction with cytochrome c553 (Alcaligenes xylosoxidans GIFU1051) was kinetically investigated, and its enantio-selectivity was detected. Based on the results of enantio-selective behavior for cytochrome c553, the local structure of molecular recognition site of cytochrome c553 was discussed.

scholarly journals Electron transfer studies of a conventional redox probe in human sweat and saliva bio-mimicking conditions

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
P. Krishnaveni ◽  
V. Ganesh
Keyword(s):  
Electron Transfer ◽  
Crystalline Phase ◽  
Liquid Crystalline ◽  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Redox Couple ◽  
Liquid Crystalline Phase ◽  
Transfer Reactions ◽  
Redox Probe ◽  
Human Sweat

AbstractModern day hospital treatments aim at developing electrochemical biosensors for early diagnosis of diseases using unconventional human bio-fluids like sweat and saliva by monitoring the electron transfer reactions of target analytes. Such kinds of health care diagnostics primarily avoid the usage of human blood and urine samples. In this context, here we have investigated the electron transfer reaction of a well-known and commonly used redox probe namely, potassium ferro/ferri cyanide by employing artificially simulated bio-mimics of human sweat and saliva as unconventional electrolytes. Typically, electron transfer characteristics of the redox couple, [Fe(CN)6]3−/4− are investigated using electrochemical techniques like cyclic voltammetry and electrochemical impedance spectroscopy. Many different kinetic parameters are determined and compared with the conventional system. In addition, such electron transfer reactions have also been studied using a lyotropic liquid crystalline phase comprising of Triton X-100 and water in which the aqueous phase is replaced with either human sweat or saliva bio-mimics. From these studies, we find out the electron transfer reaction of [Fe(CN)6]3−/4− redox couple is completely diffusion controlled on both Au and Pt disc shaped electrodes in presence of sweat and saliva bio-mimic solutions. Moreover, the reaction is partially blocked by the presence of lyotropic liquid crystalline phase consisting of sweat and saliva bio-mimics indicating the predominant charge transfer controlled process for the redox probe. However, the rate constant values associated with the electron transfer reaction are drastically reduced in presence of liquid crystalline phase. These studies are essentially carried out to assess the effect of sweat and saliva on the electrochemistry of Fe2+/3+ redox couple.

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