Metal Complexes with Macrocyclic Ligands. Part XXXII. Reactivity studies of the pendant carboxylic group in a macrocyclic Cu2+complex towards amide formation and its use as a protein-labelling agent

1990 ◽  
Vol 73 (1) ◽  
pp. 149-153 ◽  
Author(s):  
Martin Studer ◽  
Thomas A. Kaden ◽  
Helmut R. Mäcke
Keyword(s):  
Metal Complexes ◽  
Macrocyclic Ligands ◽  
Carboxylic Group ◽  
Protein Labelling ◽  
Amide Formation

Binuclear and polynuclear transition metal complexes with macrocyclic ligands 7. Directed step-by-step synthesis of novel unsymmetric macrocyclic ligands

2005 ◽  
Vol 54 (9) ◽  
pp. 2219-2223 ◽  
Author(s):  
V. V. Roznyatovsky ◽  
N. E. Borisova ◽  
M. D. Reshetova ◽  
A. G. Buyanovskaya ◽  
Yu. A. Ustynyuk
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Macrocyclic Ligands

SYNTHESIS, SPECTRAL STUDIES, STRUCTURAL EVALUATION AND ANTIMICROBIAL ACTIVITY OF SOME NOVEL C R(III) COMPLEXES CONTAINING TETRADENTATE MACROCYCLIC LIGANDS

INDIAN DRUGS ◽  
2017 ◽  
Vol 54 (06) ◽  
pp. 20-29
Author(s):  
S Shukla ◽  
◽  
S. Gautam ◽  
S Chandra ◽  
A. Kumar
Keyword(s):  
Metal Complexes ◽  
Metal Ion ◽  
Metal Salt ◽  
Condensation Reaction ◽  
Macrocyclic Ligand ◽  
Agar Plate ◽  
Macrocyclic Ligands ◽  
Diffusion Method ◽  
Spectral Studies ◽  
Spectral Techniques

A string of novel coordination compounds of Cr(III) complexes have been derived and characterized from the macrocyclic ligands (L 1 -L 2 ) carried out by condensation reaction between ligands and the subsequent metal salt. The chemical composition of ligand was determined by analytical and spectral techniques i.e. elemental analysis, IR and Mass spectrocopy. Spectral techniques revealed tetradentate [N 4 ] the nature of ligand and its coordination mode to metal ion through nitrogen donor atoms. Metal complexes were characterized by elemental analyses, molar conductance, magnetic susceptibility measurements, IR, electronic spectra, ePR studies. The geometry of these complexes was ascertained by molecular modelling study by using Gaussian 09 program. All metal complexes were found to exhibit octahedral geometry around the metal ion. The newly synthesized macrocyclic ligands and metal complexes were subjected for antimicrobial screening to determine the inhibition and control against tested microorganisms, bacteria ( S.lutea , S.aureus, S.albus and E.coli ) and fungi ( A.fulviceps, U . hordei, A. niger and P.catinus ) by using disc diffusion method and agar plate technique, respectively. The experimental results suggest that metal complexes exhibit enhanced inhibition zone than free macrocyclic ligand.

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