scholarly journals Legacy impacts of all-time anthropogenic emissions on the global mercury cycle

2013 ◽  
Vol 27 (2) ◽  
pp. 410-421 ◽  
Author(s):  
Helen M. Amos ◽  
Daniel J. Jacob ◽  
David G. Streets ◽  
Elsie M. Sunderland
Keyword(s):  
Anthropogenic Emissions ◽  
Legacy Impacts ◽  
Mercury Cycle

scholarly journals Determining the Role of Acidity, Fate and Formation of IEPOX-Derived SOA in CMAQ

Atmosphere ◽  
2021 ◽  
Vol 12 (6) ◽  
pp. 707
Author(s):  
Petros Vasilakos ◽  
Yongtao Hu ◽  
Armistead Russell ◽  
Athanasios Nenes
Keyword(s):  
Significant Influence ◽  
Organic Aerosol ◽  
Liquid Water Content ◽  
Anthropogenic Emissions ◽  
So2 Emissions ◽  
Aerosol Acidity ◽  
A Value ◽  
Future Emission ◽  
The Impact

Formation of aerosol from biogenic hydrocarbons relies heavily on anthropogenic emissions since they control the availability of species such as sulfate and nitrate, and through them, aerosol acidity (pH). To elucidate the role that acidity and emissions play in regulating Secondary Organic Aerosol (SOA), we utilize the 2013 Southern Oxidant and Aerosol Study (SOAS) dataset to enhance the extensive mechanism of isoprene epoxydiol (IEPOX)-mediated SOA formation implemented in the Community Multiscale Air Quality (CMAQ) model (Pye et al., 2013), which was then used to investigate the impact of potential future emission controls on IEPOX OA. We found that the Henry’s law coefficient for IEPOX was the most impactful parameter that controls aqueous isoprene OA products, and a value of 1.9 × 107 M atm−1 provides the best agreement with measurements. Non-volatile cations (NVCs) were found in higher-than-expected quantities in CMAQ and exerted a significant influence on IEPOX OA by reducing its production by as much as 30% when present. Consistent with previous literature, a strong correlation of isoprene OA with sulfate, and little correlation with acidity or liquid water content, was found. Future reductions in SO2 emissions are found to not affect this correlation and generally act to increase the sensitivity of IEPOX OA to sulfate, even in extreme cases.

scholarly journals Solar Brightening/Dimming over China’s Mainland: Effects of Atmospheric Aerosols, Anthropogenic Emissions, and Meteorological Conditions

2020 ◽  
Vol 13 (1) ◽  
pp. 88
Author(s):  
Hejin Fang ◽  
Wenmin Qin ◽  
Lunche Wang ◽  
Ming Zhang ◽  
Xuefang Yang
Keyword(s):  
Atmospheric Aerosols ◽  
Southern China ◽  
Influencing Factor ◽  
Precipitable Water ◽  
Northwest China ◽  
Meteorological Conditions ◽  
Anthropogenic Emissions ◽  
Main Role ◽  
Surface Solar Radiation ◽  
Climate Change Research

Surface solar radiation (SSR) is the main factor affecting the earth’s climate and environment and its variations and the reason for these variations are an important part of climate change research. In this research, we investigated the long-term variations of SSR during 1984–2016 and the quantitative influences of atmospheric aerosols, anthropogenic emissions, and meteorological conditions on SSR over China’s mainland. The results show the following: (1) The annual average SSR values had a decline trend at a rate of −0.371 Wm−2 yr−1 from 1984 to 2016 over China. (2) The aerosol optical depth (AOD) plays the main role in inducing variations in SSR over China, with r values of −0.75. Moreover, there are marked regional differences in the influence of anthropogenic emissions and meteorological conditions on SSR trends. (3) From a regional perspective, AOD is the main influencing factor on SSR in northeast China (NEC), Yunnan Plateau and surrounding regions (YPS), North China (NC), and Loess Plateau (LP), with r values of −0.65, −0.60, −0.89, and −0.50, respectively. However, the main driving factors for SSR in northwest China (NWC) are “in cloud optical thickness of all clouds” (TAUTOT) (−0.26) and black carbon (BC) anthropogenic emissions (−0.21). TAUTOT (−0.39) and total precipitable water vapor (TQV) (−0.29) are the main influencing factors of SSR in the middle-lower Yangtze Plain (MYP). The main factors that influence SSR in southern China (SC) are surface pressure (PS) (−0.66) and AOD (−0.43). This research provides insights in understanding the variations of SSR and its relationships with anthropogenic conditions and meteorological factors.

scholarly journals Source attributions of pollution to the Western Arctic during the NASA ARCTAS field campaign

2013 ◽  
Vol 13 (9) ◽  
pp. 4707-4721 ◽  
Author(s):  
H. Bian ◽  
P. R. Colarco ◽  
M. Chin ◽  
G. Chen ◽  
J. M. Rodriguez ◽  
...  
Keyword(s):  
Biomass Burning ◽  
Field Experiments ◽  
Transport Model ◽  
Background Level ◽  
Anthropogenic Emissions ◽  
Airborne Measurements ◽  
Ch4 Production ◽  
Regional Sources ◽  
Western Arctic ◽  
Co Concentrations

Abstract. We use the NASA GEOS-5 transport model with tagged tracers to investigate the contributions of different regional sources of CO and black carbon (BC) to their concentrations in the Western Arctic (i.e., 50–90° N and 190–320° E) in spring and summer 2008. The model is evaluated by comparing the results with airborne measurements of CO and BC from the NASA Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) field campaigns to demonstrate the strengths and limitations of our simulations. We also examine the reliability of tagged CO tracers in characterizing air mass origins using the measured fossil fuel tracer of dichloromethane and the biomass burning tracer of acetonitrile. Our tagged CO simulations suggest that most of the enhanced CO concentrations (above background level from CH4 production) observed during April originate from Asian anthropogenic emissions. Boreal biomass burning emissions and Asian anthropogenic emissions are of similar importance in July domain wise, although the biomass burning CO fraction is much larger in the area of the ARCTAS field experiments. The fraction of CO from Asian anthropogenic emissions is larger in spring than in summer. European sources make up no more than 10% of CO levels in the campaign domain during either period. Comparisons of CO concentrations along the flight tracks with regional averages from GEOS-5 show that the along-track measurements are representative of the concentrations within the large domain of the Western Arctic in April but not in July.

scholarly journals Enhanced SOA formation from mixed anthropogenic and biogenic emissions during the CARES campaign

2013 ◽  
Vol 13 (4) ◽  
pp. 2091-2113 ◽  
Author(s):  
J. E. Shilling ◽  
R. A. Zaveri ◽  
J. D. Fast ◽  
L. Kleinman ◽  
M. L. Alexander ◽  
...  
Keyword(s):  
Mass Spectrometer ◽  
Organic Aerosol ◽  
Proton Transfer Reaction ◽  
Chemical Mechanism ◽  
Biogenic Emissions ◽  
Anthropogenic Emissions ◽  
Radiation Balance ◽  
Particle Phase ◽  
Aerosol Formation ◽  
Research Aircraft

Abstract. The CARES campaign was conducted during June, 2010 in the vicinity of Sacramento, California to study aerosol formation and aging in a region where anthropogenic and biogenic emissions regularly mix. Here, we describe measurements from an Aerodyne High Resolution Aerosol Mass Spectrometer (AMS), an Ionicon Proton Transfer Reaction Mass Spectrometer (PTR-MS), and trace gas detectors (CO, NO, NOx) deployed on the G-1 research aircraft to investigate ambient gas- and particle-phase chemical composition. AMS measurements showed that the particle phase is dominated by organic aerosol (OA) (85% on average) with smaller concentrations of sulfate (5%), nitrate (6%) and ammonium (3%) observed. PTR-MS data showed that isoprene dominated the biogenic volatile organic compound concentrations (BVOCs), with monoterpene concentrations generally below the detection limit. Using two different metrics, median OA concentrations and the slope of plots of OA vs. CO concentrations (i.e., ΔOA/ΔCO), we contrast organic aerosol evolution on flight days with different prevailing meteorological conditions to elucidate the role of anthropogenic and biogenic emissions on OA formation. Airmasses influenced predominantly by biogenic emissions had median OA concentrations of 2.2 μg m−3 and near zero ΔOA/ΔCO. Those influenced predominantly by anthropogenic emissions had median OA concentrations of 4.7 μg m−3 and ΔOA/ΔCO ratios of 35–44 μg m−3 ppmv. But, when biogenic and anthropogenic emissions mixed, OA levels were enhanced, with median OA concentrations of 11.4 μg m−3 and ΔOA/ΔCO ratios of 77–157 μg m−3 ppmv. Taken together, our observations show that production of OA was enhanced when anthropogenic emissions from Sacramento mixed with isoprene-rich air from the foothills. After considering several anthropogenic/biogenic interaction mechanisms, we conclude that NOx concentrations play a strong role in enhancing SOA formation from isoprene, though the chemical mechanism for the enhancement remains unclear. If these observations are found to be robust in other seasons and in areas outside of Sacramento, regional and global aerosol modules will need to incorporate more complex representations of NOx-dependent SOA mechanisms and yields into their algorithms. Ultimately, accurately predicting OA mass concentrations and their effect on radiation balance will require a mechanistically-based treatment of the interactions of biogenic and anthropogenic emissions.

Are there pre-Quaternary geological analogues for a future greenhouse warming?

2011 ◽  
Vol 369 (1938) ◽  
pp. 933-956 ◽  
Author(s):  
Alan M. Haywood ◽  
Andy Ridgwell ◽  
Daniel J. Lunt ◽  
Daniel J. Hill ◽  
Matthew J. Pound ◽  
...  
Keyword(s):  
Climate Change ◽  
Greenhouse Gases ◽  
Future Climate ◽  
Future Climate Change ◽  
Anthropogenic Emissions ◽  
Earth System ◽  
System Sensitivity ◽  
Earth History ◽  
Scientific Papers

Given the inherent uncertainties in predicting how climate and environments will respond to anthropogenic emissions of greenhouse gases, it would be beneficial to society if science could identify geological analogues to the human race’s current grand climate experiment . This has been a focus of the geological and palaeoclimate communities over the last 30 years, with many scientific papers claiming that intervals in Earth history can be used as an analogue for future climate change. Using a coupled ocean–atmosphere modelling approach, we test this assertion for the most probable pre-Quaternary candidates of the last 100 million years: the Mid- and Late Cretaceous, the Palaeocene–Eocene Thermal Maximum (PETM), the Early Eocene, as well as warm intervals within the Miocene and Pliocene epochs. These intervals fail as true direct analogues since they either represent equilibrium climate states to a long-term CO 2 forcing—whereas anthropogenic emissions of greenhouse gases provide a progressive (transient) forcing on climate—or the sensitivity of the climate system itself to CO 2 was different. While no close geological analogue exists, past warm intervals in Earth history provide a unique opportunity to investigate processes that operated during warm (high CO 2 ) climate states. Palaeoclimate and environmental reconstruction/modelling are facilitating the assessment and calculation of the response of global temperatures to increasing CO 2 concentrations in the longer term (multiple centuries); this is now referred to as the Earth System Sensitivity, which is critical in identifying CO 2 thresholds in the atmosphere that must not be crossed to avoid dangerous levels of climate change in the long term. Palaeoclimatology also provides a unique and independent way to evaluate the qualities of climate and Earth system models used to predict future climate.

Sign in / Sign up

Export Citation Format

Share Document