Polyimide Electrolyte Membranes Having Fluorenyl and Sulfopropoxy Groups for High Temperature PEFCs

Fuel Cells ◽  
2005 ◽  
Vol 5 (2) ◽  
pp. 296-301 ◽  
Author(s):  
H. Zhou ◽  
K. Miyatake ◽  
M. Watanabe
2018 ◽  
Vol 19 (12) ◽  
pp. 2449-2457 ◽  
Author(s):  
Xiaorui Ren ◽  
Huanhuan Li ◽  
Ke Liu ◽  
Hongyi Lu ◽  
Jingshuai Yang ◽  
...  

2020 ◽  
Vol MA2020-02 (35) ◽  
pp. 2247-2247
Author(s):  
Maria Perez-Page ◽  
Jianuo Chen ◽  
Andres Parra-Puerto ◽  
Javier Rubio-Garcia ◽  
Anthony R. J. Kucernak ◽  
...  

Author(s):  
Nobuyuki Tanaka ◽  
Tetsuya Yamaki ◽  
Masaharu Asano ◽  
Yasunari Maekawas ◽  
Kaoru Onuki ◽  
...  

Japan Atomic Energy Agency has been conducting research and development on a thermochemical water-splitting cycle featuring iodine- and sulfur-compounds (called an IS process) as one of promising heat utilization systems of High Temperature Gas-Cooled Reactors. We have prepared polymer electrolyte membranes by the radiation-induced graft polymerization and cross-linking methods and then have investigated their applicability to electro-electrodialysis (EED) for concentrating HI in an HI-I2-H2O mixture. For practical applications, EED membranes are required to be stable in the severe environment of high-temperature strongly acidic solutions. We thus examined thermal, chemical and electrochemical stabilities of the radiation-grafted membranes under the conditions of the actual EED operation over 100 hours, while measuring the time evolution of a cell voltage and a change in the ion exchange capacity between the EED experiment. The results showed that chemical cross-linking in the graft chains could largely improve the membrane stability.


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