Effects of sediment organic carbon content on the elimination rates of neutral lipophilic compounds in the midge(Chironomus Riparius)

1992 ◽  
Vol 11 (3) ◽  
pp. 347-356 ◽  
Author(s):  
Michael J. Lydy ◽  
Paul C. Baumann ◽  
James T. Oris ◽  
Susan W. Fisher
2016 ◽  
Vol 13 (12) ◽  
pp. 3677-3686 ◽  
Author(s):  
Perran L. M. Cook ◽  
Miles Jennings ◽  
Daryl P. Holland ◽  
John Beardall ◽  
Christy Briles ◽  
...  

Abstract. Blooms of noxious N2 fixing cyanobacteria such as Nodularia spumigena are a recurring problem in some estuaries; however, the historic occurrence of such blooms in unclear in many cases. Here we report the results of a palaeoecological study on a temperate Australian lagoon system (the Gippsland Lakes) where we used stable isotopes and pigment biomarkers in dated cores as proxies for eutrophication and blooms of cyanobacteria. Pigment proxies show a clear signal, with an increase in cyanobacterial pigments (echinenone, canthaxanthin and zeaxanthin) in the period coinciding with recent blooms. Another excursion in these proxies was observed prior to the opening of an artificial entrance to the lakes in 1889, which markedly increased the salinity of the Gippsland Lakes. A coincident increase in the sediment organic-carbon content in the period prior to the opening of the artificial entrance suggests that the bottom waters of the lakes were more stratified and hypoxic, which would have led to an increase in the recycling of phosphorus. After the opening of the artificial entrance, there was a  ∼  60-year period with low values for the cyanobacterial proxies as well as a low sediment organic-carbon content suggesting a period of low bloom activity associated with the increased salinity of the lakes. During the 1940s, the current period of re-eutrophication commenced, as indicated by a steadily increasing sediment organic-carbon content and cyanobacterial pigments. We suggest that increasing nitrogen inputs from the catchment led to the return of hypoxia and increased phosphorus release from the sediment, which drove the re-emergence of cyanobacterial blooms.


2017 ◽  
Vol 14 (6) ◽  
pp. 350 ◽  
Author(s):  
Wen-Qing Cao ◽  
Jun Song ◽  
Gui-Peng Yang

Environmental contextOfloxacin, a widely used fluorinated antibiotic, is resistant to biodegradation and hence can accumulate in the environment. A systematic investigation of ofloxacin on marine sediments showed that sediment organic carbon and heterogeneous sites on sediments play important roles in adsorption processes. The results help our understanding of the environmental behaviour and fate of ofloxacin in marine systems. AbstractThe adsorption behaviour of ofloxacin (OFL) on marine sediments treated by different methods was investigated using batch experiments. Three factors (sediment organic carbon content, salinity and temperature) that may affect the adsorption behaviour of OFL were analysed. The equilibrium time for OFL adsorption on marine sediment in natural seawater was ~4–5h. The adsorption of OFL on all sediments with different treatments fitted the Freundlich model well. The adsorption parameter Kf value was in the order of Kf (H2O2 treatment)<Kf (H2O treatment)<Kf (HCl treatment) over the studied concentration range. The adsorption of OFL was influenced not only by the sediment organic carbon content but also by external factors such as salinity of media and temperature. The adsorption was favourably influenced by decreased salinity and temperature of seawater. The adsorption capacity of OFL on marine sediments decreased with an increase of temperature and salinity. The Kf values decreased from 33.73±1.66 to 22.54±1.12(Lkg−1)1/n when the temperature increased from 283 to 313K. The changes in standard Gibbs free energy (ΔG0) and enthalpy (ΔH0) were −6.62±0.34kJmol−1 and −7.58±0.38kJmol−1 respectively, indicating that the adsorption process of OFL was spontaneous and exothermic. The positive value of the entropy change ΔS0 (i.e. 3.38±0.17JK−1mol−1) suggests that the degree of freedom increased during the adsorption process.


2015 ◽  
Vol 12 (22) ◽  
pp. 18829-18853
Author(s):  
P. L. M. Cook ◽  
M. Jennings ◽  
D. P. Holland ◽  
J. Beardall ◽  
C. Briles ◽  
...  

Abstract. Blooms of noxious N2 fixing cyanobacteria such as Nodularia spumigena are a recurring problem in some estuaries. Here we report the results of a palaeoecological study on a temperate Australian lagoon system (The Gippsland Lakes) where we used stable isotopes and pigment biomarkers in dated cores as proxies for eutrophication and blooms of cyanobacteria. Pigment proxies show a clear signal, with an increase in cyanobacterial pigments (echinenone, canthaxanthin and zeaxanthin) in the period coinciding with recent blooms. Another excursion in these proxies was observed prior to the opening of an artificial entrance to the lakes in 1889, which markedly increased the salinity of the Gippsland Lakes. A coincident increase in the sediment organic carbon content in the period prior to the opening of the artificial entrance suggests the bottom waters of the lakes were increasingly stratified and hypoxic, which would have led to an increase in the recycling of phosphorus. After the opening of the artificial entrance there was a ~ 60 year period with low values for the cyanobacterial proxies as well as a low sediment organic carbon content suggesting a period of low bloom activity associated with the increased salinity of the lakes. During the 1940s, the current period of re-eutrophication commenced as indicated by a steadily increasing sediment organic carbon content and cyanobacterial pigments. We suggest increasing nitrogen inputs from the catchment led to the return of hypoxia and increased phosphorus release from the sediment, which drove the re-emergence of cyanobacterial blooms.


Limnology ◽  
2005 ◽  
Vol 6 (2) ◽  
pp. 139-139 ◽  
Author(s):  
Boo-Keun Khim ◽  
Hee Mdn Jung ◽  
Daekyo Cheong

Limnology ◽  
2005 ◽  
Vol 6 (1) ◽  
pp. 61-66
Author(s):  
Boo-Keun Khim ◽  
Hee Mdn Jung ◽  
Daekyo Cheong

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