The use of nickel oxide as a hole transport material in perovskite solar cell configuration: Achieving a high performance and stable device

2020 ◽  
Vol 44 (13) ◽  
pp. 9839-9863
Author(s):  
Agnes C. Nkele ◽  
Assumpta C. Nwanya ◽  
Nanasaheb M. Shinde ◽  
Sabastine Ezugwu ◽  
Malik Maaza ◽  
...  
2021 ◽  
Author(s):  
Monika Srivastava ◽  
◽  
Karan Surana ◽  
Pramod Kumar Singh ◽  
Ram Chandra Singh ◽  
...  

Author(s):  
Xinmiao Chen ◽  
Lei Lu ◽  
Dawei Gu ◽  
Xiaoyan Zhang ◽  
Yu He ◽  
...  

The printable HTM-free (HTM=hole transport materials) mesoporous carbon-based perovskite solar cell (C-PSC) is one of the most promising technologies, because of its simple production process, lost-cost and excellent stability. In...


2021 ◽  
Vol 412 ◽  
pp. 128746
Author(s):  
Pei-Huan Lee ◽  
Ting-Tzu Wu ◽  
Chia-Feng Li ◽  
Damian Głowienka ◽  
Yi-Hsuan Sun ◽  
...  

2020 ◽  
Vol 208 ◽  
pp. 110352 ◽  
Author(s):  
Pei-Huan Lee ◽  
Bo-Ting Li ◽  
Chia-Feng Lee ◽  
Zhi-Hao Huang ◽  
Yu-Ching Huang ◽  
...  

2020 ◽  
Vol 15 (6) ◽  
pp. 725-733
Author(s):  
Safdar Mehmood ◽  
Mohammad Kaleem ◽  
Sajid Nazir ◽  
Adeel Israr ◽  
Hamid Turab Mirza

The perovskite-based solar cells (PSCs) are gaining much attention for application in solar cell device frameworks due to high absorption property, easy and low-cost fabrication, and tunable bandgap. The PSCs exhibiting conversion efficiency up to ∼22% are reported utilizing expensive and unstable electrons and hole transportation layers (ETL and HTL). However the stability of these devices drastically suffers under humid conditions and in an environment that is rich with ultraviolet radiation. The deterioration under such conditions produces Pb ions which are harmful to the biotic environment limiting its usefulness for practical device implantation. In this work, we propose the designing of methyl ammonium lead halide (CH3NH3PBI3) based planar perovskite solar cell. The general-purpose solar cell simulation tool (GPVDM) is used to simulate and study the proposed design in detail. The format of the cell consists of indium tin oxide (ITO)/zinc oxide (ZnO)/CH3NH3PBI3/Cu doped (2%) nickel oxide (Cu: NiOx)/Aluminum (AL). The HTL layer utilized in our study demonstrated a high stability (48%) in ultraviolet radiation. We also investigated the effect of active layer thickness, ETL and HTL layer, parasitic resistance, light intensity and operating temperature on proposed PSCs. The optimum layer thickness of active, ETL and HTL was found to be 400 nm and 150 nm respectively, while keeping the electrode thickness to 100 nm. At the optimum thickness, the device demonstrates fill factor (FF) and efficiency as 15.33% and 0.8516, respectively. The optimum device operating temperature was 285 k. The observed maximum FF and maximum efficiency reached up to 15.85% and 0.8574 respectively with thicker active, ETL/HTL layers. We observed that our HTL layer (Cu doped nickel oxide) shows stability of 66% against ultraviolet A and 48% against both ultraviolet A and B. This study provides a comprehensive numerical analysis for designing an efficient perovskite based solar cell which can be adopted for practical device fabrication.


2019 ◽  
Vol 87 (1) ◽  
pp. 10101 ◽  
Author(s):  
Davoud Jalalian ◽  
Abbas Ghadimi ◽  
Azadeh Kiani

In this study, a lead-free nontoxic and hole transport material (HTM)-free perovskite solar cell (PSC) with a novel configuration of glass/FTO/ZnO/CH3NH3SnI3−xBrx/back contact has been modeled and optimized by a solar cell capacitance simulator (SCAPS). The bandgap of CH3NH3SnI3−xBrx absorber is tuned in the range of 1.3 eV to 2.15 eV by variation of the Br doping content. To make a comparison, an optimized Pb-based PSC is also modeled. By optimizing the parameters, power conversion efficiency (PCE) of 16.30%, open circuit voltage (Voc) of 1.02 V, short circuit current density (Jsc) of 22.23 mA/cm2, and fill factor (FF) of 0.72 were obtained. As compare to the reports available in the literature, these results show much improvement and can provide guidelines for production of economic and environmentally friendly PSCs with further efficiency enhancement.


RSC Advances ◽  
2017 ◽  
Vol 7 (42) ◽  
pp. 26202-26210 ◽  
Author(s):  
Zhiyong Liu ◽  
Tingwei He ◽  
Kaikai Liu ◽  
Qinqin Zhi ◽  
Mingjian Yuan

Solution processed double-decked V2Ox/PEDOT:PSS HTL film can effectively improve optoelectronic properties of PSC devices.


Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1751
Author(s):  
Inga Ermanova ◽  
Narges Yaghoobi Nia ◽  
Enrico Lamanna ◽  
Elisabetta Di Bartolomeo ◽  
Evgeny Kolesnikov ◽  
...  

In this paper, we demonstrate the high potentialities of pristine single-cation and mixed cation/anion perovskite solar cells (PSC) fabricated by sequential method deposition in p-i-n planar architecture (ITO/NiOX/Perovskite/PCBM/BCP/Ag) in ambient conditions. We applied the crystal engineering approach for perovskite deposition to control the quality and crystallinity of the light-harvesting film. The formation of a full converted and uniform perovskite absorber layer from poriferous pre-film on a planar hole transporting layer (HTL) is one of the crucial factors for the fabrication of high-performance PSCs. We show that the in-air sequential deposited MAPbI3-based PSCs on planar nickel oxide (NiOX) permitted to obtain a Power Conversion Efficiency (PCE) exceeding 14% while the (FA,MA,Cs)Pb(I,Br)3-based PSC achieved 15.6%. In this paper we also compared the influence of transporting layers on the cell performance by testing material depositions quantity and thickness (for hole transporting layer), and conditions of deposition processes (for electron transporting layer). Moreover, we optimized second step of perovskite deposition by varying the dipping time of substrates into the MA(I,Br) solution. We have shown that the layer by layer deposition of the NiOx is the key point to improve the efficiency for inverted perovskite solar cell out of glove-box using sequential deposition method, increasing the relative efficiency of +26% with respect to reference cells.


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