Phase change microcapsules with lead tungstate shell for gamma radiation shielding and thermal energy storage

2019 ◽  
Author(s):  
Lan Lou ◽  
Zhuoni Jiang ◽  
Quanping Zhang ◽  
Dongliang Liu ◽  
Yuanlin Zhou ◽  
...  
Keyword(s):  
Energy Storage ◽  
Gamma Radiation ◽  
Phase Change ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Radiation Shielding ◽  
Lead Tungstate

Thermal Energy Storage Through Melting of a Commercial Phase Change Material in an Annulus with Radially Divergent Longitudinal Fins

2020 ◽  
Vol 7 (1) ◽  
Author(s):  
Tonny Tabassum Mainul Hasan ◽  
Latifa Begum
Keyword(s):  
Energy Storage ◽  
Phase Change ◽  
Phase Change Material ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Storage System ◽  
Operating Conditions ◽  
Melting Time ◽  
Bottom Part ◽  
Change Material

This study reports on the unsteady two-dimensional numerical investigations of melting of a paraffin wax (phase change material, PCM) which melts over a temperature range of 8.7oC. The PCM is placed inside a circular concentric horizontal-finned annulus for the storage of thermal energy. The inner tube is fitted with three radially diverging longitudinal fins strategically placed near the bottom part of the annulus to accelerate the melting process there. The developed CFD code used in Tabassum et al., 2018 is extended to incorporate the presence of fins. The numerical results show that the average Nusselt number over the inner tube surface, the total melt fraction, the total stored energy all increased at every time instant in the finned annulus compared to the annulus without fins. This is due to the fact that in the finned annulus, the fins at the lower part of the annulus promotes buoyancy-driven convection as opposed to the slow conduction melting that prevails at the bottom part of the plain annulus. Fins with two different heights have been considered. It is found that by extending the height of the fin to 50% of the annular gap about 33.05% more energy could be stored compared to the bare annulus at the melting time of 82.37 min for the identical operating conditions. The effects of fins with different heights on the temperature and streamfunction distributions are found to be different. The present study can provide some useful guidelines for achieving a better thermal energy storage system.

scholarly journals Latent Heat Phase Change Heat Transfer of a Nanoliquid with Nano–Encapsulated Phase Change Materials in a Wavy-Wall Enclosure with an Active Rotating Cylinder

2021 ◽  
Vol 13 (5) ◽  
pp. 2590
Author(s):  
S. A. M. Mehryan ◽  
Kaamran Raahemifar ◽  
Leila Sasani Gargari ◽  
Ahmad Hajjar ◽  
Mohamad El Kadri ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Energy Storage ◽  
Phase Change ◽  
Latent Heat ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Wavy Wall ◽  
Governing Equations ◽  
Stefan Number ◽  
Change Material

A Nano-Encapsulated Phase-Change Material (NEPCM) suspension is made of nanoparticles containing a Phase Change Material in their core and dispersed in a fluid. These particles can contribute to thermal energy storage and heat transfer by their latent heat of phase change as moving with the host fluid. Thus, such novel nanoliquids are promising for applications in waste heat recovery and thermal energy storage systems. In the present research, the mixed convection of NEPCM suspensions was addressed in a wavy wall cavity containing a rotating solid cylinder. As the nanoparticles move with the liquid, they undergo a phase change and transfer the latent heat. The phase change of nanoparticles was considered as temperature-dependent heat capacity. The governing equations of mass, momentum, and energy conservation were presented as partial differential equations. Then, the governing equations were converted to a non-dimensional form to generalize the solution, and solved by the finite element method. The influence of control parameters such as volume concentration of nanoparticles, fusion temperature of nanoparticles, Stefan number, wall undulations number, and as well as the cylinder size, angular rotation, and thermal conductivities was addressed on the heat transfer in the enclosure. The wall undulation number induces a remarkable change in the Nusselt number. There are optimum fusion temperatures for nanoparticles, which could maximize the heat transfer rate. The increase of the latent heat of nanoparticles (a decline of Stefan number) boosts the heat transfer advantage of employing the phase change particles.

scholarly journals Demonstration of Phase Change Thermal Energy Storage in Zinc Oxide Microencapsulated Sodium Nitrate

2021 ◽  
Vol 11 (13) ◽  
pp. 6234
Author(s):  
Ciprian Neagoe ◽  
Ioan Albert Tudor ◽  
Cristina Florentina Ciobota ◽  
Cristian Bogdanescu ◽  
Paul Stanciu ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Thermal Properties ◽  
High Temperature ◽  
Energy Storage ◽  
Phase Change ◽  
Thermal Energy ◽  
Sodium Nitrate ◽  
Thermal Energy Storage ◽  
Metal Corrosion ◽  
Scanning Calorimetry

Microencapsulation of sodium nitrate (NaNO3) as phase change material for high temperature thermal energy storage aims to reduce costs related to metal corrosion in storage tanks. The goal of this work was to test in a prototype thermal energy storage tank (16.7 L internal volume) the thermal properties of NaNO3 microencapsulated in zinc oxide shells, and estimate the potential of NaNO3–ZnO microcapsules for thermal storage applications. A fast and scalable microencapsulation procedure was developed, a flow calorimetry method was adapted, and a template document created to perform tank thermal transfer simulation by the finite element method (FEM) was set in Microsoft Excel. Differential scanning calorimetry (DSC) and transient plane source (TPS) methods were used to measure, in small samples, the temperature dependency of melting/solidification heat, specific heat, and thermal conductivity of the NaNO3–ZnO microcapsules. Scanning electron microscopy (SEM) and chemical analysis demonstrated the stability of microcapsules over multiple tank charge–discharge cycles. The energy stored as latent heat is available for a temperature interval from 303 to 285 °C, corresponding to onset–offset for NaNO3 solidification. Charge–self-discharge experiments on the pilot tank showed that the amount of thermal energy stored in this interval largely corresponds to the NaNO3 content of the microcapsules; the high temperature energy density of microcapsules is estimated in the range from 145 to 179 MJ/m3. Comparison between real tank experiments and FEM simulations demonstrated that DSC and TPS laboratory measurements on microcapsule thermal properties may reliably be used to design applications for thermal energy storage.

scholarly journals Thermophysical Properties of Multifunctional Syntactic Foams Containing Phase Change Microcapsules for Thermal Energy Storage

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1790
Author(s):  
Francesco Galvagnini ◽  
Andrea Dorigato ◽  
Luca Fambri ◽  
Giulia Fredi ◽  
Alessandro Pegoretti
Keyword(s):  
Thermal Conductivity ◽  
Energy Storage ◽  
Phase Change ◽  
Epoxy Resin ◽  
Storage Modulus ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Neat Epoxy ◽  
Low Density ◽  
Syntactic Foams

Syntactic foams (SFs) combining an epoxy resin and hollow glass microspheres (HGM) feature a unique combination of low density, high mechanical properties, and low thermal conductivity which can be tuned according to specific applications. In this work, the versatility of epoxy/HGM SFs was further expanded by adding a microencapsulated phase change material (PCM) providing thermal energy storage (TES) ability at a phase change temperature of 43 °C. At this aim, fifteen epoxy (HGM/PCM) compositions with a total filler content (HGM + PCM) of up to 40 vol% were prepared and characterized. The experimental results were fitted with statistical models, which resulted in ternary diagrams that visually represented the properties of the ternary systems and simplified trend identification. Dynamic rheological tests showed that the PCM increased the viscosity of the epoxy resin more than HGM due to the smaller average size (20 µm vs. 60 µm) and that the systems containing both HGM and PCM showed lower viscosity than those containing only one filler type, due to the higher packing efficiency of bimodal filler distributions. HGM strongly reduced the gravimetric density and the thermal insulation properties. In fact, the sample with 40 vol% of HGM showed a density of 0.735 g/cm3 (−35% than neat epoxy) and a thermal conductivity of 0.12 W/(m∙K) (−40% than neat epoxy). Moreover, the increase in the PCM content increased the specific phase change enthalpy, which was up to 68 J/g for the sample with 40 vol% of PCM, with a consequent improvement in the thermal management ability that was also evidenced by temperature profiling tests in transient heating and cooling regimes. Finally, dynamical mechanical thermal analysis (DMTA) showed that both fillers decreased the storage modulus but generally increased the storage modulus normalized by density (E′/ρ) up to 2440 MPa/(g/cm3) at 25 °C with 40 vol% of HGM (+48% than neat epoxy). These results confirmed that the main asset of these ternary multifunctional syntactic foams is their versatility, as the composition can be tuned to reach the property set that best matches the application requirements in terms of TES ability, thermal insulation, and low density.

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