Kinetics of sulfer dioxide uptake on supported cerium oxide sorbents

1992 ◽  
Vol 11 (2) ◽  
pp. 98-103 ◽  
Author(s):  
Sheila W. Hedges ◽  
James T. Yeh
Keyword(s):  
Cerium Oxide ◽  
Sulfer Dioxide ◽  
Kinetics Of

Crotonaldehyde hydrogenation on platinum–titanium oxide and platinum–cerium oxide catalysts: selective CO bond hydrogen requires platinum sites beyond the oxide–metal interface

2016 ◽  
Vol 6 (18) ◽  
pp. 6824-6835 ◽  
Author(s):  
Xin Yang ◽  
Yutichai Mueanngern ◽  
Quinn A. Baker ◽  
L. Robert Baker
Keyword(s):  
Titanium Oxide ◽  
Cerium Oxide ◽  
Oxide Catalysts ◽  
Metal Interface ◽  
Crotonaldehyde Hydrogenation ◽  
Kinetics Of ◽  
Bond Hydrogenation

We have investigated a series of Pt–TiO2 and Pt–CeO2 catalysts for crotonaldehyde hydrogenation with the goal of better understanding the kinetics of CO bond hydrogenation.

The Effects of Morphology on the Oxidation of Ceria by Water and Carbon Dioxide

2011 ◽  
Vol 134 (1) ◽  
Author(s):  
Luke J. Venstrom ◽  
Nicholas Petkovich ◽  
Stephen Rudisill ◽  
Andreas Stein ◽  
Jane H. Davidson
Keyword(s):  
Carbon Dioxide ◽  
Specific Surface ◽  
Surface Area ◽  
Cerium Oxide ◽  
Pore System ◽  
Production Rates ◽  
Ordered Macroporous ◽  
Kinetics Of ◽  
Interconnected Pore ◽  
Low Porosity

The oxidation of three-dimensionally ordered macroporous (3DOM) CeO2 (ceria) by H2O and CO2 at 1100 K is presented in comparison to the oxidation of nonordered mesoporous and sintered, low porosity ceria. 3DOM ceria, which features interconnected and ordered pores, increases the maximum H2 and CO production rates over the low porosity ceria by 125% and 260%, respectively, and increases the maximum H2 and CO production rates over the nonordered mesoporous cerium oxide by 75% and 175%, respectively. The increase in the kinetics of H2O and CO2 splitting with 3DOM ceria is attributed to its enhanced specific surface area and to its interconnected pore system that facilitates the transport of reacting species to and from oxidation sites.

Reduction and Sulfidation Kinetics of Cerium Oxide and Cu-Modified Cerium Oxide

2002 ◽  
Vol 41 (13) ◽  
pp. 3115-3123 ◽  
Author(s):  
Makoto Kobayashi ◽  
Maria Flytzani-Stephanopoulos
Keyword(s):  
Cerium Oxide ◽  
Sulfidation Kinetics ◽  
Kinetics Of

Direct observations of radiation-enhanced transformations in glass

1983 ◽  
Vol 41 ◽  
pp. 354-355
Author(s):  
J. F. DeNatale ◽  
D. G. Howitt
Keyword(s):  
Glass Matrix ◽  
Diffusion Mechanism ◽  
Bubble Formation ◽  
Silicate Glasses ◽  
Phase Decomposition ◽  
Direct Observations ◽  
Thin Foils ◽  
Oxygen Bubble ◽  
Electron Energy Loss ◽  
Kinetics Of

The electron irradiation of silicate glasses containing metal cations produces various types of phase separation and decomposition which includes oxygen bubble formation at intermediate temperatures figure I. The kinetics of bubble formation are too rapid to be accounted for by oxygen diffusion but the behavior is consistent with a cation diffusion mechanism if the amount of oxygen in the bubble is not significantly different from that in the same volume of silicate glass. The formation of oxygen bubbles is often accompanied by precipitation of crystalline phases and/or amorphous phase decomposition in the regions between the bubbles and the detection of differences in oxygen concentration between the bubble and matrix by electron energy loss spectroscopy cannot be discerned (figure 2) even when the bubble occupies the majority of the foil depth.The oxygen bubbles are stable, even in the thin foils, months after irradiation and if van der Waals behavior of the interior gas is assumed an oxygen pressure of about 4000 atmospheres must be sustained for a 100 bubble if the surface tension with the glass matrix is to balance against it at intermediate temperatures.

Irradiation behavior of pyrolytic silicon carbide

1983 ◽  
Vol 41 ◽  
pp. 72-73
Author(s):  
R. J. Lauf
Keyword(s):  
Silicon Carbide ◽  
Fission Products ◽  
Thermodynamics And Kinetics ◽  
Neutron Fluences ◽  
Fuel Particles ◽  
Sic Coatings ◽  
Irradiation Behavior ◽  
Kinetics Of ◽  
Htgr Fuel

Fuel particles for the High-Temperature Gas-Cooled Reactor (HTGR) contain a layer of pyrolytic silicon carbide to act as a miniature pressure vessel and primary fission product barrier. Optimization of the SiC with respect to fuel performance involves four areas of study: (a) characterization of as-deposited SiC coatings; (b) thermodynamics and kinetics of chemical reactions between SiC and fission products; (c) irradiation behavior of SiC in the absence of fission products; and (d) combined effects of irradiation and fission products. This paper reports the behavior of SiC deposited on inert microspheres and irradiated to fast neutron fluences typical of HTGR fuel at end-of-life.

The Ordered Phase Formation in Ti-Al-Ga Alloys

1970 ◽  
Vol 28 ◽  
pp. 440-441
Author(s):  
Shiro Fujishiro ◽  
Harold L. Gegel
Keyword(s):  
Thermal Stability ◽  
High Temperature ◽  
Titanium Alloys ◽  
Growth Kinetics ◽  
Stoichiometric Composition ◽  
Good Potential ◽  
Alpha Titanium ◽  
Cold Rolled ◽  
Kinetics Of ◽  
Thermal Stability Of

Ordered-alpha titanium alloys having a DO19 type structure have good potential for high temperature (600°C) applications, due to the thermal stability of the ordered phase and the inherent resistance to recrystallization of these alloys. Five different Ti-Al-Ga alloys consisting of equal atomic percents of aluminum and gallium solute additions up to the stoichiometric composition, Ti3(Al, Ga), were used to study the growth kinetics of the ordered phase and the nature of its interface.The alloys were homogenized in the beta region in a vacuum of about 5×10-7 torr, furnace cooled; reheated in air to 50°C below the alpha transus for hot working. The alloys were subsequently acid cleaned, annealed in vacuo, and cold rolled to about. 050 inch prior to additional homogenization

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