High adsorption of methylene blue from water onto graphenic materials: Effect of degree of graphitization and analysis of kinetic models

2021 ◽  
Author(s):  
Eduardo E. Pérez‐Ramírez ◽  
Miguel Luz‐Asunción ◽  
Ana L. Martínez‐Hernández ◽  
Juan G. Luna‐Bárcenas ◽  
Perla E. García‐Casillas ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Kinetic Models ◽  
High Adsorption ◽  
Degree Of Graphitization

scholarly journals Synthesis and characterization of Cu(OH)2-NWs-PVA-AC Nano-composite and its use as an efficient adsorbent for removal of methylene blue

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Sivarama Krishna Lakkaboyana ◽  
Khantong Soontarapa ◽  
Nabel Kalel Asmel ◽  
Vinay Kumar ◽  
Ravi Kumar Marella ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Kinetic Models ◽  
Batch Reactor ◽  
Maximum Adsorption Capacity ◽  
Nano Composite ◽  
Adsorption Processes ◽  
Intra Particle Diffusion ◽  
Short Time ◽  
Efficient Adsorbent

AbstractThe present study focused on the synthesis of copper hydroxide nanowires decorated on activated carbon (Cu(OH)2-NWs-PVA-AC). The obtained Cu(OH)2-NWs-PVA-AC Nano-composite was distinguished by XRD, SEM, EDX, BET, FTIR and XPS respectively. Besides, different variables such as solution pH, and initial dye concentration, contact time, and temperature were performed on the adsorption efficiency of MB in a small batch reactor. Further, the experimental results are analyzed by various kinetic models via PFO, PSO, intra-particle diffusion and Elovich models, and the results revealed that among the kinetic models, PSO shows more suitability. In addition, different adsorption isotherms were applied to the obtained experimental data and found that Langmuir–Freundlich and Langmuir isotherm were best fits with the maximum adsorption capacity of 139.9 and 107.6 mg/g, respectively. The Nano-composite has outstanding MB removal efficiency of 94–98.5% with a span of 10 min. and decent adsorption of about 98.5% at a pH of 10. Thermodynamic constants like Gibbs free energy, entropy, and enthalpy were analyzed from the temperature reliance. The results reveal the adsorption processes are spontaneous and exothermic in nature. The high negative value of ΔG° (− 44.11 to − 48.86 kJ/mol) and a low negative value of ΔH° (− 28.96 kJ/mol) show the feasibility and exothermic nature of the adsorption process. The synthesized dye was found to be an efficient adsorbent for the potential removal of cationic dye (methylene blue) from wastewater within a short time.

Kinetic and Thermodynamic Study Adsorbing Methylene Blue on Nanozirconia

2013 ◽  
Vol 475-476 ◽  
pp. 1311-1319
Author(s):  
Ping Hua Chen ◽  
Xue Zhen Zhou ◽  
Yong Xiu Li ◽  
Dong Ping Li ◽  
Jing Li ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Thermodynamic Properties ◽  
Adsorption Process ◽  
Sorption Process ◽  
Kinetic Properties ◽  
High Adsorption ◽  
Adsorption Ability ◽  
Methylene Blue Adsorption ◽  
Influence Of Temperature ◽  
Kinetic And Thermodynamic Study

In present study, uniformed nanozirconia is obtained via precipitation, ball milling and spray drying. The characteristics of methylene blue adsorption by nanozirconia are studied in details. The morphology of nanozirconia is examined by SEM. The influence of temperature is studied to obtain the optimal adsorption conditions. The equilibrium adsorption isotherms and the kinetic properties of the adsorption process are investigated to study the mechanism. The thermodynamic properties of methylene blue adsorption is investigated, and the thermodynamic parameters of Gθ, Hθ and Sθ are calculated. The results show nanozirconia has high adsorption ability of 43.99 mg/g to methylene blue, and the adsorption reaction is a spontaneous and physic-sorption process.

Two-fold 2D + 2D → 2D interweaved rhombus (4,4) grid: synthesis, structure, and dye removal properties in darkness and in daylight

2019 ◽  
Vol 48 (3) ◽  
pp. 1095-1107 ◽  
Author(s):  
Meng-Jung Tsai ◽  
Jheng-Hua Luo ◽  
Jing-Yun Wu
Keyword(s):  
Methylene Blue ◽  
Methyl Orange ◽  
Malachite Green ◽  
Dye Removal ◽  
Acid Orange 7 ◽  
High Adsorption ◽  
Acid Orange ◽  
Adsorption Capacities

A rhombus (4,4) grid showing two-fold 2D + 2D → 2D interweaved nets appeared to be a good adsorbent to selectively adsorb and separate anionic methyl orange (MO) and acid orange 7 (AO7) dyes over cationic methylene blue (MB) and malachite green (MG) from water with high adsorption capacities in both darkness and daylight.

High adsorption of methylene blue from aqueous solutions using leaf-shaped ZIF-8

2019 ◽  
pp. 1-14
Author(s):  
Abdolazim Alinejad ◽  
Shahram Sadeghi ◽  
Mansour Ghaderpoori ◽  
Soleyman Sahebi ◽  
Afshin Ghaderpoury ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Aqueous Solutions ◽  
High Adsorption

scholarly journals Magnetic graphene oxide-nano zero valent iron (GO–nZVI) nanohybrids synthesized using biocompatible cross-linkers for methylene blue removal

RSC Advances ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 963-973 ◽  
Author(s):  
Novin Mehrabi ◽  
Arvid Masud ◽  
Moyosore Afolabi ◽  
Jinwoo Hwang ◽  
Gabriel A. Calderon Ortiz ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Graphene Oxide ◽  
Green Synthesis ◽  
Synthesis Method ◽  
Zero Valent Iron ◽  
Adsorption Efficiency ◽  
High Adsorption ◽  
Magnetic Graphene Oxide ◽  
Methylene Blue Removal ◽  
Nano Zero Valent Iron

A green synthesis method was used to prepare GO–nZVI nanohybrids to provide an adsorbent with high adsorption efficiency that can be removed from aqueous solutions easily by magnetic separation.

scholarly journals Ginger Straw Waste-Derived Porous Carbons as Effective Adsorbents toward Methylene Blue

Molecules ◽  
2019 ◽  
Vol 24 (3) ◽  
pp. 469 ◽  
Author(s):  
Wenlin Zhang ◽  
Huihe Li ◽  
Jianmin Tang ◽  
Hongjia Lu ◽  
Yiqing Liu
Keyword(s):  
Methylene Blue ◽  
Porous Materials ◽  
Adsorption Capacity ◽  
Adsorption Rate ◽  
Dye Wastewater ◽  
Porous Carbons ◽  
High Adsorption ◽  
New Approach ◽  
High Adsorption Capacity

In this work, ginger straw waste-derived porous carbons, with high adsorption capacity, high adsorption rate, and good reusability for removing the toxic dye of methylene blue from wastewater, were prepared by a facile method under oxygen-limiting conditions. This study opens a new approach for the utilization of ginger straw waste, and the porous materials can be employed as great potential adsorbents for treating dye wastewater.

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