Treatment performance evaluation of chemical oxygen demand from landfill leachate by electro-coagulation and electro-fenton technique

2010 ◽  
Vol 31 (1) ◽  
pp. 59-67 ◽  
Author(s):  
Merve Oya Orkun ◽  
Ayşe Kuleyin
Keyword(s):  
Performance Evaluation ◽  
Chemical Oxygen Demand ◽  
Landfill Leachate ◽  
Oxygen Demand ◽  
Treatment Performance ◽  
Electro Coagulation

Treatment of a complex landfill leachate with peat

1978 ◽  
Vol 5 (1) ◽  
pp. 83-97 ◽  
Author(s):  
Robert D. Cameron
Keyword(s):  
Chemical Oxygen Demand ◽  
Ferric Chloride ◽  
Landfill Leachate ◽  
Metal Removal ◽  
Oxygen Demand ◽  
Treatment Method ◽  
Manganese Concentration ◽  
Chemical Pretreatment ◽  
Iron Manganese

The use of cheap, locally available peat as a treatment method for landfill leachate was investigated by passing leachate through plexiglass columns filled with an amorphous-granular peat. Preliminary adjustment of pH showed that reducing pH to 4.8 dramatically reduced adsorption. Increasing the pH to 8.4, metal removal was increased owing to filtration of precipitated metals. The best adsorption of metals occurred at the 'natural' pH of 7.1. Manganese was found to be the limiting pollutant. At the 0.05 mg/ℓ maximum acceptable manganese concentration 94% of the total metals were removed, requiring 159 kg of peat per 1000 ℓ of leachate.Resting the peat for 1 month did significantly increase removal capacity.Desorption of some contaminants occurred when water was percolated through the peat. The desorption test effluent was not toxic to fish although iron, lead and COD (chemical oxygen demand) exceeded acceptable values.Chemical pretreatment using lime and ferric chloride achieved significant iron, manganese and calcium removals. Chemical pretreatment followed by peat adsorption offered no advantage other than reducing toxicity to fish.Peat treatment alone was effective in reducing concentrations to a level that was non-toxic to fish.

Ozonation With Catalyst in Landfill Leachate Treatment

2019 ◽  
pp. 324-354
Author(s):  
Siti Nor Farhana Zakaria
Keyword(s):  
Molecular Structure ◽  
Hydrogen Peroxide ◽  
Hydroxyl Radical ◽  
Chemical Oxygen Demand ◽  
Human Health ◽  
Chemical Reaction ◽  
Landfill Leachate ◽  
Treatment Cost ◽  
Oxygen Demand ◽  
Leachate Treatment

Landfill leachate is a hazardous pollutant generated from a landfill site. Discharge of landfill leachate has caused a major contamination to the environment and detrimental to human health. This chapter introduces an alternative method to treat recalcitrant pollutant in leachate by using ozonation with catalyst. The production of hydroxyl radical in ozonation was not enough to oxidize complex molecular structure in the leachate. Theoretically, the addition of catalyst enhances the capacity of radical and accelerates the chemical reaction. The effectiveness of ozonation with Fenton (O3/Fenton), hydrogen peroxide (O3/H2O2), and zirconium tetrachloride (O3/ZrCl4) in removing pollutant such as chemical oxygen demand (COD), color, and improvement of biodegradability by using this process were also discussed in this chapter. Comparison in term of treatment cost and benefits of the application of chemical as catalyst are briefly elaborated at the end of this chapter.

Raw landfill leachate treatment using an electrocoagulation process with a novel rotating electrode reactor

2019 ◽  
Vol 80 (3) ◽  
pp. 458-465 ◽  
Author(s):  
Ahmed Samir Naje ◽  
Mohammed A. Ajeel ◽  
Isam Mohamad Ali ◽  
Hussein A. M. Al-Zubaidi ◽  
Peter Adeniyi Alaba
Keyword(s):  
Landfill Leachate ◽  
Suspended Solids ◽  
Treatment Process ◽  
Oxygen Demand ◽  
Neutral Medium ◽  
Leachate Treatment ◽  
Rotating Speed ◽  
Electrode Distance ◽  
Treatment Performance ◽  
Electrocoagulation Process

Abstract In this work, landfill leachate treatment by electrocoagulation process with a novel rotating anode reactor was studied. The influence of rotating anode speed on the removal efficiency of chemical oxygen demand (COD), total dissolved solids (TDS), and total suspended solids (TSS) of raw landfill leachate was investigated. The influence of operating parameters like leachate pH, leachate temperature, current, and inter-distance between the cathode rings and anode impellers on the electrocoagulation performance were also investigated. The results revealed the optimum rotating speed is 150 rpm and increasing the rotating speed above this value led to reducing process performance. The leachate electrocoagulation treatment process favors the neutral medium and the treatment performance increases with increasing current intensity. Furthermore, the electrocoagulation treatment performance improves with increasing leachate temperature. However, the performance reduces with increasing inter-electrode distance.

Optimisation of chemical oxygen demand removal from landfill leachate by sonocatalytic degradation in the presence of cupric oxide nanoparticles

2017 ◽  
Vol 35 (6) ◽  
pp. 636-646 ◽  
Author(s):  
Paria Amirian ◽  
Edris Bazrafshan ◽  
Abolfazl Payandeh
Keyword(s):  
Response Surface Methodology ◽  
Chemical Oxygen Demand ◽  
Response Surface ◽  
Landfill Leachate ◽  
Cupric Oxide ◽  
Oxygen Demand ◽  
Oxide Nanoparticles ◽  
Ultrasonic Frequency ◽  
Optimum Conditions ◽  
Cupric Oxide Nanoparticles

Leachate is the liquid formed when waste breaks down in the landfill and water filters through that waste. This liquid is very toxic and can pollute the land, ground water, and water resources. In most countries, it is mandatory for landfills to be protected against leachate. In addition to all other harms to the environment, disposal of raw landfill leachate can be a major source of hazard to closed water bodies. Hence, treatment of landfill leachate is considered an essential step prior to its discharge from source. This article describes the sonocatalytic degradation of chemical oxygen demand in landfill leachate using cupric oxide nanoparticles as sonocatalyst (cupric oxide/ultrasonic) and aims to establish this method as an effective alternative to currently used approaches. An ideal experimental design was carried out based on a central composite design with response surface methodology. The response surface methodology was used to evaluate the effect of process variables including pH values (3, 7, 11), cupric oxide nanoparticles dose (0.02, 0.035, 0.05 g), reaction time (10, 35, 60 minutes), ultrasonic frequency (35, 37, 130 KHz), and their interaction towards the attainment of their optimum conditions. The derived second-order model, including both significant linear and quadratic terms, seemed to be adequate in predicting responses (R2 = 0.9684 and prediction R2 = 0.9581). The optimum conditions for the maximum chemical oxygen demand sonocatalytic degradation of 85.82% were found to be pH 6.9, cupric oxide nanoparticles dosage of 0.05 gr L−1, and the ultrasonic frequency of 130 kHz at a contact time of 10 min.

Physico-chemical treatment of Merida landfill leachate for chemical oxygen demand reduction by coagulation

2005 ◽  
Vol 23 (6) ◽  
pp. 560-564 ◽  
Author(s):  
Roger I. Méndez-Novelo ◽  
Elba R. Castillo-Borges ◽  
María R. Sauri-Riancho ◽  
Carlos A. Quintal-Franco ◽  
Germán Giacomán-Vallejos ◽  
...  
Keyword(s):  
Chemical Oxygen Demand ◽  
Landfill Leachate ◽  
Chemical Treatment ◽  
Oxygen Demand ◽  
Physico Chemical ◽  
Demand Reduction ◽  
Chemical Oxygen Demand Reduction

scholarly journals An investigation on treatment of tannery wastewater by electrocoagulation

2013 ◽  
Vol 11 (4) ◽  
pp. 546-555 ◽  
Keyword(s):  
Chemical Oxygen Demand ◽  
Suspended Solids ◽  
Oxygen Demand ◽  
Electrical Current ◽  
The Other ◽  
Tannery Wastewater ◽  
Contact Duration ◽  
A Value ◽  
Removal Efficiencies ◽  
Electro Coagulation

Treatability by the electro-coagulation (EC) and electro-Fenton (EF) methods have been applied to the tannery wastewater from an organized industrial region consisting mostly of tannery plants and compared with each other in this study. Iron plates were used as the anode and cathode. Electrical current was applied at a value of 33.3 mA m-2 for all processes in order to determine the electricity consumptions for chemical oxygen demand (COD) and sulfide removal. The optimal contact duration for each process was discovered at the end of the first five minutes. During the EC process, the removal efficiencies of COD and sulfide were 46% and 90%, respectively. Electricity consumptions were also obtained as 1.8 kWh kg- 1 COD removed and 27.7 kWh kg-1 sulfide removed. During the EF process, on the other hand, the removal efficiencies of COD and sulfide parameters were 54% and 85%, respectively, and electricity consumptions were also obtained as 1.5 kWh kg-1 COD removed and 8.3 kWh kg-1 sulfide removed. Furthermore, the removal efficiencies of total Chrome and suspended solids were determined to be 97% and 70%, respectively.

Performance of Ozone/ZrCl4 Oxidation in Stabilized Landfill Leachate Treatment

2015 ◽  
Vol 802 ◽  
pp. 501-506 ◽  
Author(s):  
Siti Nor Farhana Zakaria ◽  
Hamidi Abdul Aziz ◽  
Salem S. Abu Amr
Keyword(s):  
Chemical Oxygen Demand ◽  
Landfill Leachate ◽  
Oxygen Demand ◽  
Landfill Site ◽  
Sanitary Landfill ◽  
Ammoniacal Nitrogen ◽  
Combined Method ◽  
Zirconium Tetrachloride ◽  
Leachate Treatment ◽  
Treatment Facilities

Landfill leachate generation is one of the main problems from sanitary landfill. Chemical oxygen demand (COD), ammoniacal nitrogen (NH3-N), and color are among the most problematic parameters in stabilized leachate. In this regard, dedicated treatment facilities are required before leachate can be discharged into the environment. The performance of the combined ozonation (O3) and zirconium tetrachloride (ZrCl4) to treat two types of stabilized leachate was investigated during this study. Leachate samples were collected from an anaerobic stabilized leachate (Alor Pongsu Landfill Site, APLS) and semi-aerobic stabilized leachate (Pulau Burung Landfill Site, PBLS). Zirconium tetrachloride dosage was determined as 1 g/1 g (COD/ZrCl4 ratio) and then added to the leachate samples with 60 min ozonation at natural leachate pH (8). COD, color, and NH3-N were removed from the APLS sample at 33%, 70%, and 53% rates, respectively, whereas 48%, 75%, and 69%, respectively, from the PBLS samples. Ozone consumption was also calculated with the highest value (3.81 Kg O3/ Kg COD) reported in PBLS, whereas the lowest value (2.32 Kg O3/ Kg COD) was reported in APLS. Biodegradability of (BOD5/COD) was investigated and improved from 0.07 to 0.08 for the APLS samples and 0.05 to 0.11 for the PBLS samples after leachate oxidation. Results showed that the performance of O3/ZrCl4 oxidation is more efficient in treating semi-aerobic stabilized leachate than anaerobic stabilized leachate Moreover, the combined method proved to be more efficient in remediating leachate compared with ozone and zirconium treatment alone.

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