Modeling of the radicalary state in the H2O2/UV oxidation system to predict the degradation kinetics of phenolic mixture solutions

2010 ◽  
Vol 30 (2) ◽  
pp. 196-207 ◽  
Author(s):  
Ana De Luis ◽  
José Ignacio Lombraña ◽  
Amaia Menéndez
Keyword(s):  
Degradation Kinetics ◽  
Kinetics Of ◽  
Oxidation System ◽  
Uv Oxidation

Decolorization and aromatic ring degradation kinetics of Direct Red 80 by UV oxidation in the presence of hydrogen peroxide utilizing TiO2 as a photocatalyst

2005 ◽  
Vol 112 (1-3) ◽  
pp. 191-196 ◽  
Author(s):  
Niyaz Mohammad Mahmoodi ◽  
Mokhtar Arami ◽  
Nargess Yousefi Limaee ◽  
Nooshin Salman Tabrizi
Keyword(s):  
Hydrogen Peroxide ◽  
Aromatic Ring ◽  
Degradation Kinetics ◽  
Kinetics Of ◽  
Uv Oxidation

scholarly journals Degradation Kinetics of Humic acid in Aqueous Solution by Ozonation Treatment under Different Parameter Conditions

2020 ◽  
Vol 596 ◽  
pp. 012010
Author(s):  
Zafirah Mahyun ◽  
Noor Fazliani Shoparwe ◽  
Ahmad Zuhairi Abdullah ◽  
Abdul Latif Ahmad ◽  
Mardawani Mohamad ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Humic Acid ◽  
Degradation Kinetics ◽  
Kinetics Of

scholarly journals Thermal Degradation Kinetics and Modeling Study of Ultra High Molecular Weight Polyethylene (UHMWP)/Graphene Nanocomposite

Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1597
Author(s):  
Iman Jafari ◽  
Mohamadreza Shakiba ◽  
Fatemeh Khosravi ◽  
Seeram Ramakrishna ◽  
Ehsan Abasi ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Molecular Weight ◽  
Thermal Degradation ◽  
High Molecular Weight ◽  
Degradation Kinetics ◽  
Graphene Nanosheets ◽  
Thermal Degradation Kinetics ◽  
Graphene Nanocomposites ◽  
Kinetics Of ◽  
Ultra High Molecular Weight

The incorporation of nanofillers such as graphene into polymers has shown significant improvements in mechanical characteristics, thermal stability, and conductivity of resulting polymeric nanocomposites. To this aim, the influence of incorporation of graphene nanosheets into ultra-high molecular weight polyethylene (UHMWPE) on the thermal behavior and degradation kinetics of UHMWPE/graphene nanocomposites was investigated. Scanning electron microscopy (SEM) analysis revealed that graphene nanosheets were uniformly spread throughout the UHMWPE’s molecular chains. X-Ray Diffraction (XRD) data posited that the morphology of dispersed graphene sheets in UHMWPE was exfoliated. Non-isothermal differential scanning calorimetry (DSC) studies identified a more pronounced increase in melting temperatures and latent heat of fusions in nanocomposites compared to UHMWPE at lower concentrations of graphene. Thermogravimetric analysis (TGA) and derivative thermogravimetric (DTG) revealed that UHMWPE’s thermal stability has been improved via incorporating graphene nanosheets. Further, degradation kinetics of neat polymer and nanocomposites have been modeled using equations such as Friedman, Ozawa–Flynn–Wall (OFW), Kissinger, and Augis and Bennett’s. The "Model-Fitting Method” showed that the auto-catalytic nth-order mechanism provided a highly consistent and appropriate fit to describe the degradation mechanism of UHMWPE and its graphene nanocomposites. In addition, the calculated activation energy (Ea) of thermal degradation was enhanced by an increase in graphene concentration up to 2.1 wt.%, followed by a decrease in higher graphene content.

Drying characteristics and lycopene degradation kinetics of tomato soup

2021 ◽  
pp. 100757
Author(s):  
Akshay Sonawane ◽  
O.P. Chauhan ◽  
Shubhankar D. Semwal ◽  
A.D. Semwal
Keyword(s):  
Degradation Kinetics ◽  
Drying Characteristics ◽  
Kinetics Of ◽  
Tomato Soup

scholarly journals Isothermal Vulcanization and Non-Isothermal Degradation Kinetics of XNBR/Epoxy/XNBR-g-Halloysite Nanotubes (HNT) Nanocomposites

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2872
Author(s):  
Seyed Mohamad Reza Paran ◽  
Ghasem Naderi ◽  
Elnaz Movahedifar ◽  
Maryam Jouyandeh ◽  
Krzysztof Formela ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Degradation Kinetics ◽  
Halloysite Nanotubes ◽  
Butadiene Rubber ◽  
Order Model ◽  
Scanning Calorimetry ◽  
Theoretical Methods ◽  
Vulcanization Kinetics ◽  
Kinetics Of ◽  
Thermal Stability Of

The effect of several concentrations of carboxylated nitrile butadiene rubber (XNBR) functionalized halloysite nanotubes (XHNTs) on the vulcanization and degradation kinetics of XNBR/epoxy compounds were evaluated using experimental and theoretical methods. The isothermal vulcanization kinetics were studied at various temperatures by rheometry and differential scanning calorimetry (DSC). The results obtained indicated that the nth order model could not accurately predict the curing performance. However, the autocatalytic approach can be used to estimate the vulcanization reaction mechanism of XNBR/epoxy/XHNTs nanocomposites. The kinetic parameters related to the degradation of XNBR/epoxy/XHNTs nanocomposites were also assessed using thermogravimetric analysis (TGA). TGA measurements suggested that the grafted nanotubes strongly enhanced the thermal stability of the nanocomposite.

scholarly journals Thermal Degradation Kinetics of Sugarcane Bagasse and Soft Wood Cellulose

Materials ◽  
2017 ◽  
Vol 10 (11) ◽  
pp. 1246 ◽  
Author(s):  
Samson M. Mohomane ◽  
Tshwafo E. Motaung ◽  
Neerish Revaprasadu
Keyword(s):  
Thermal Degradation ◽  
Sugarcane Bagasse ◽  
Degradation Kinetics ◽  
Thermal Degradation Kinetics ◽  
Wood Cellulose ◽  
Kinetics Of

Degradation kinetics of anthocyanins in freeze-dried microencapsulates from lowbush blueberries (Vaccinium angustifoliumAiton) and prediction of shelf-life

2016 ◽  
Vol 34 (10) ◽  
pp. 1175-1184 ◽  
Author(s):  
Giovana Bonat Celli ◽  
Rojin Dibazar ◽  
Amyl Ghanem ◽  
Marianne Su-Ling Brooks
Keyword(s):  
Shelf Life ◽  
Degradation Kinetics ◽  
Freeze Dried ◽  
Kinetics Of

Degradation kinetics of 4-amino naphthalene-1-sulfonic acid by a biofilm-forming bacterial consortium under carbon and nitrogen limitations

2012 ◽  
Vol 39 (8) ◽  
pp. 1169-1177 ◽  
Author(s):  
C. Juárez-Ramírez ◽  
R. Velázquez-García ◽  
N. Ruiz-Ordaz ◽  
J. Galíndez-Mayer ◽  
O. Ramos Monroy
Keyword(s):  
Sulfonic Acid ◽  
Degradation Kinetics ◽  
Bacterial Consortium ◽  
Carbon And Nitrogen ◽  
Kinetics Of
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