A Review of Modification Methods of Solid Electrolytes for All‐Solid‐State Sodium‐Ion Batteries

2020 ◽  
Vol 9 (1) ◽  
pp. 2000682
Author(s):  
Hanqing Dai ◽  
Yuanyuan Chen ◽  
Wenqian Xu ◽  
Zhe Hu ◽  
Jing Gu ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Sodium Ion ◽  
Sodium Ion Batteries

scholarly journals Effective Approaches of Improving the Performance of Chalcogenide Solid Electrolytes for All-Solid-State Sodium-Ion Batteries

2020 ◽  
Vol 8 ◽  
Author(s):  
Hanqing Dai ◽  
Wenqian Xu ◽  
Zhe Hu ◽  
Yuanyuan Chen ◽  
Xian Wei ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Sodium Ion ◽  
Sodium Ion Batteries

Theoretical formulation of Na3AO4X (A = S/Se, X = F/Cl) as high-performance solid electrolytes for all-solid-state sodium batteries

2019 ◽  
Vol 7 (38) ◽  
pp. 21985-21996 ◽  
Author(s):  
Yuran Yu ◽  
Zhuo Wang ◽  
Guosheng Shao
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
High Performance ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Theoretical Formulation ◽  
Sodium Batteries ◽  
Solid State Electrolytes

It is very important and yet extremely challenging to develop solid state electrolytes to make sodium ion batteries (SIBs) safer, since the much larger size of Na+ than that of Li+ makes transport of Na+ rather difficult.

Materials Design of Sodium Chloride Solid Electrolytes Na3MCl6 for All-Solid-State Sodium-Ion Batteries

2021 ◽  
Author(s):  
Dongsu Park ◽  
Kwangnam Kim ◽  
Gin Hyung Chun ◽  
Brandon C. Wood ◽  
Joon Hyung Shim ◽  
...  
Keyword(s):  
Sodium Chloride ◽  
Solid State ◽  
Solid Electrolytes ◽  
Low Cost ◽  
Materials Design ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Li Ion Batteries ◽  
Li Ion

All-solid-state sodium-ion batteries have attracted increasing attention owing to the low cost of sodium and the enhanced safety compared to conventional Li-ion batteries. Recently, halides have been considered as promising...

scholarly journals A stable cathode-solid electrolyte composite for high-voltage, long-cycle-life solid-state sodium-ion batteries

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Erik A. Wu ◽  
Swastika Banerjee ◽  
Hanmei Tang ◽  
Peter M. Richardson ◽  
Jean-Marie Doux ◽  
...  
Keyword(s):  
Solid State ◽  
High Voltage ◽  
Coulombic Efficiency ◽  
Composite Cathode ◽  
Cycling Performance ◽  
Sodium Ion ◽  
Great Promise ◽  
Sodium Ion Batteries ◽  
Ion Conductor ◽  
Oxide Cathodes

AbstractRechargeable solid-state sodium-ion batteries (SSSBs) hold great promise for safer and more energy-dense energy storage. However, the poor electrochemical stability between current sulfide-based solid electrolytes and high-voltage oxide cathodes has limited their long-term cycling performance and practicality. Here, we report the discovery of the ion conductor Na3-xY1-xZrxCl6 (NYZC) that is both electrochemically stable (up to 3.8 V vs. Na/Na+) and chemically compatible with oxide cathodes. Its high ionic conductivity of 6.6 × 10−5 S cm−1 at ambient temperature, several orders of magnitude higher than oxide coatings, is attributed to abundant Na vacancies and cooperative MCl6 rotation, resulting in an extremely low interfacial impedance. A SSSB comprising a NaCrO2 + NYZC composite cathode, Na3PS4 electrolyte, and Na-Sn anode exhibits an exceptional first-cycle Coulombic efficiency of 97.1% at room temperature and can cycle over 1000 cycles with 89.3% capacity retention at 40 °C. These findings highlight the immense potential of halides for SSSB applications.

Na3.12Fe2.44(P2O7)2/multi-walled carbon nanotube composite as a cathode material for sodium-ion batteries

2015 ◽  
Vol 3 (33) ◽  
pp. 17224-17229 ◽  
Author(s):  
Yubin Niu ◽  
Maowen Xu ◽  
Chuanjun Cheng ◽  
ShuJuan Bao ◽  
Junke Hou ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Solid State ◽  
Cathode Material ◽  
Solid State Reaction ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Multi Walled Carbon Nanotube ◽  
Carbon Nanotube Composite

Na3.12Fe2.44(P2O7)2/multi-walled carbon nanotube (MWCNT) composite was fabricated by a solid state reaction and was further used to fabricate a cathode for sodium-ion batteries.

scholarly journals Probing Solid–Solid Interfacial Reactions in All-Solid-State Sodium-Ion Batteries with First-Principles Calculations

2017 ◽  
Vol 30 (1) ◽  
pp. 163-173 ◽  
Author(s):  
Hanmei Tang ◽  
Zhi Deng ◽  
Zhuonan Lin ◽  
Zhenbin Wang ◽  
Iek-Heng Chu ◽  
...  
Keyword(s):  
Solid State ◽  
First Principles ◽  
Interfacial Reactions ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
First Principles Calculations

A novel PMA/PEG-based composite polymer electrolyte for all-solid-state sodium ion batteries

Nano Research ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 6244-6251 ◽  
Author(s):  
Xuejing Zhang ◽  
Xingchao Wang ◽  
Shuang Liu ◽  
Zhanliang Tao ◽  
Jun Chen
Keyword(s):  
Solid State ◽  
Polymer Electrolyte ◽  
Sodium Ion ◽  
Composite Polymer Electrolyte ◽  
Sodium Ion Batteries ◽  
Composite Polymer

Flexible Quasi-Solid-State Sodium-Ion Batteries Built by Stacking Two-Dimensional Titania Sheets with Carbon Nanotube Spacers

2019 ◽  
Vol 2 (8) ◽  
pp. 5707-5715 ◽  
Author(s):  
Hongbin Chu ◽  
Kun Jiang ◽  
Guohui Li ◽  
Zhigang Zhao ◽  
Qingwen Li ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Solid State ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Two Dimensional

scholarly journals Synthesis and electrochemical performances of Na3V2(PO4)2F3/C composites as cathode materials for sodium ion batteries

RSC Advances ◽  
2019 ◽  
Vol 9 (53) ◽  
pp. 30628-30636 ◽  
Author(s):  
Mingxue Wang ◽  
Xiaobing Huang ◽  
Haiyan Wang ◽  
Tao Zhou ◽  
Huasheng Xie ◽  
...  
Keyword(s):  
Solid State ◽  
Carbon Source ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Sodium Ion ◽  
Electrochemical Performances ◽  
Sodium Ion Batteries ◽  
Rate Performance ◽  
Cycle Stability ◽  
Reaction Method

Na3V2(PO4)2F3/C composites were synthesized by a solid-state reaction method using pitch as the carbon source, the as-prepared sample with the carbon content of 12.14% possesses an excellent rate performance and cycle stability.

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