Synergistically Suppressing Lithium Dendrite Growth by Coating Poly‐ l ‐Lactic Acid on Sustainable Gel Polymer Electrolyte

2019 ◽  
Vol 7 (5) ◽  
pp. 1800768 ◽  
Author(s):  
Lei Li ◽  
Miao Yu ◽  
Feijun Wang ◽  
Xinfang Zhang ◽  
Ziqiang Shao
2019 ◽  
Vol 7 (22) ◽  
pp. 13679-13686 ◽  
Author(s):  
Dezhi Yang ◽  
Liang He ◽  
Yu Liu ◽  
Wenqi Yan ◽  
Shishuo Liang ◽  
...  

An acetylene black modified gel polymer electrolyte was prepared to simultaneously solve the problems of shuttle effect and lithium dendrite growth for high-performance Li–S batteries.


2018 ◽  
Vol 283 ◽  
pp. 349-356 ◽  
Author(s):  
Chaoqun Niu ◽  
Mingke Zhang ◽  
Guangping Chen ◽  
Bokai Cao ◽  
Jiwei Shi ◽  
...  

2020 ◽  
Vol 8 (16) ◽  
pp. 8033-8040 ◽  
Author(s):  
Linge Li ◽  
Mingchao Wang ◽  
Jian Wang ◽  
Fangmin Ye ◽  
Shaofei Wang ◽  
...  

An asymmetric gel polymer electrolyte is designed for regulating ions and suppressing Li dendrite growth in high-performance Li metal batteries.


2018 ◽  
Vol 6 (23) ◽  
pp. 10755-10760 ◽  
Author(s):  
Sheng S. Zhang ◽  
Xiulin Fan ◽  
Chunsheng Wang

A separator having one side coated with TiO2–Kynar composite effectively prevents Li dendrite-related electrical shorting while still providing all the benefits of a composite gel polymer electrolyte.


Polymers ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1296 ◽  
Author(s):  
Wenwen Ding ◽  
Chun Wei ◽  
Shiqi Wang ◽  
Linmin Zou ◽  
Yongyang Gong ◽  
...  

Gel polymer electrolyte (GPE) is a promising candidate for lithium-ion batteries due to its adhesion property (like a solid), diffusion property (like a liquid), and inhibition of the growth of lithium dendrite. In this paper, 2-(2-ethoxyethoxy)ethyl acrylate (EOEOEA) and LiBF4 electrolyte were mixed as precursors of gel polymer electrolytes. Through thermal curing, a thermally stable GPE with high ionic conductivity (5.60 × 10−4 s/cm at 30 °C) and wide room temperature electrochemical window (4.65 V) was prepared, and the properties of the GPE were measured by linear sweep voltammetry (LSV), AC impedance spectroscopy, Thermogravimetric analysis (TG), and X-ray diffraction (XRD) techniques. On the basis of the in-situ deep polymerization on a LiFePO4 electrode and cellulose membrane in a battery case, EOEOEA-based GPE could be derived on both LiFePO4 electrode and cellulose membrane. Meanwhile, the contact between GPE, LiFePO4 electrode, and lithium electrode was promoted. The capacity retention rate of the as-prepared LiBF4-EOEOEA 30% gel lithium battery reached 100% under the condition of 0.1 °C after 50 cycles, and the Coulombic efficiency was over 99%. Meanwhile, the growth of lithium dendrite could be effectively inhibited. GPE can be applied in high-performance lithium batteries.


Small ◽  
2018 ◽  
Vol 14 (31) ◽  
pp. 1801420 ◽  
Author(s):  
Kuirong Deng ◽  
Jiaxiang Qin ◽  
Shuanjin Wang ◽  
Shan Ren ◽  
Dongmei Han ◽  
...  

Author(s):  
Qizhi Zhong ◽  
Bao Liu ◽  
Bingjun Yang ◽  
Yali Li ◽  
Junshuai Li ◽  
...  

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