A Simple Approach to Simultaneous Electroanalytical Quantification of Acetaminophen and Tramadol Using a Boron‐doped Diamond Electrode in the Existence of Sodium Dodecyl Sulfate

2019 ◽  
Vol 32 (2) ◽  
pp. 429-436 ◽  
Author(s):  
Oruç Yunusoğlu ◽  
Shabnam Allahverdiyeva ◽  
Yavuz Yardım ◽  
Zühre Şentürk
Keyword(s):  
Sodium Dodecyl Sulfate ◽  
Sodium Dodecyl ◽  
Simple Approach ◽  
Boron Doped Diamond ◽  
Diamond Electrode ◽  
Boron Doped ◽  
Boron Doped Diamond Electrode ◽  
Dodecyl Sulfate

scholarly journals Voltammetric behavior and determination of the bronchodilator doxofylline at a boron-doped diamond electrode

2012 ◽  
Vol 31 (2) ◽  
pp. 195 ◽  
Author(s):  
Sachin Saxena ◽  
Ratnanjali Shrivastava ◽  
Soami P. Satsangee
Keyword(s):  
Sodium Dodecyl ◽  
Oxidation Mechanism ◽  
Fold Increase ◽  
Tween 20 ◽  
Boron Doped Diamond ◽  
Diamond Electrode ◽  
Boron Doped ◽  
Boron Doped Diamond Electrode ◽  
Asthma Drug ◽  
Voltammetric Behavior

The electrochemical behavior of the asthma drug doxofylline was studied at a boron-doped diamond electrode in BR buffer (pH 3.8) by square-wave voltammetry. Cyclic voltammetry revealed the oxidation of doxofylline as an irreversible diffusion-controlled process. The oxidation mechanism was proposed and the drug was studied in the presence of solubilized systems like Tween-20 (T-20), sodium dodecyl sulfate (SDS), Triton X-100 (TTN), dioxane (DO), dimethylformamide (DMF), diethyl ether (DEE), benzene and methanol (MeOH). Comparison of the current responses in the solution system explained the sensitivity of the boron-doped diamond electrode (BDDE) with a three-fold increase in the current value compared to that of a glassy carbon electrode (GCE) at a fixed concentration of doxofylline. Peak current values varied linearly with increasing concentration and the LOD and LOQ were found to be 3.48 and 10.56 µg/ml, respectively. This method was employed to investigate doxofylline in the pharmaceutical formulation.

scholarly journals Determination of tramadol in pharmaceutical forms and urine samples using a boron-doped diamond electrode

2020 ◽  
Vol 85 (7) ◽  
pp. 923-937
Author(s):  
Ertuğrul Keskin ◽  
Shabnam Allahverdiyeva ◽  
Esma Şeyho ◽  
Yavuz Yardim
Keyword(s):  
Sodium Dodecyl ◽  
Pharmaceutical Formulations ◽  
Open Circuit ◽  
Urine Samples ◽  
Oxidation Peak ◽  
Boron Doped Diamond ◽  
Diamond Electrode ◽  
Boron Doped ◽  
Boron Doped Diamond Electrode

The present work describes the electroanalytical investigation and a novel voltammetric method for the cheap, fast and simple quantification of tramadol (TRH) using a boron-doped diamond electrode. TRH displayed one well-defined, irreversible and adsorption-controlled oxidation peak at about 1.58 V (vs. Ag/AgCl) in Britton?Robinson buffer (BR, 0.1 mol L-1, pH 3.0) using the cyclic voltammetry technique. The voltammetric responses of the oxidation peaks are dependent on pH and their sensitivity was significantly enhanced in the presence of surfactant media (sodium dodecyl sulphate, SDS). Under the optimized experiment conditions, employing the square-wave stripping mode, it was found that there was an excellent correlation between oxidation peak current and the TRH concentration in the range 0.25 to 50.0 ?g mL-1 (8.34?10-7?1.67?10-4 mol L-1), with a detection limit of 0.072 ?g mL-1 (2.40?10-7 mol L-1) in 0.1 mol L-1 BR buffer (pH 3.0) solution comprising 8?10-4 mol L-1 SDS at 1.52 V (after 30 s accumulation at open-circuit conditions). The developed approach could be used for the quantification of TRH in pharmaceutical formulations and spiked human urine samples with acceptable recoveries.

Simultaneous Square-Wave Voltammetric Determination of Paracetamol, Caffeine and Orphenadrine in Pharmaceutical Formulations Using a Cathodically Pretreated Boron-Doped Diamond Electrode

2013 ◽  
Vol 25 (7) ◽  
pp. 1734-1741 ◽  
Author(s):  
Ana Paula Pires Eisele ◽  
Débora Nóbile Clausen ◽  
César Ricardo Teixeira Tarley ◽  
Luiz Henrique Dall'Antonia ◽  
Elen Romão Sartori
Keyword(s):  
Pharmaceutical Formulations ◽  
Voltammetric Determination ◽  
Boron Doped Diamond ◽  
Square Wave ◽  
Diamond Electrode ◽  
Boron Doped ◽  
Boron Doped Diamond Electrode

Fast and simultaneous determination of nimesulide and paracetamol by batch injection analysis with amperometric detection on bare boron-doped diamond electrode

2013 ◽  
Vol 39 ◽  
pp. 41-46 ◽  
Author(s):  
Polyana Fernandes Pereira ◽  
Mariana Cardoso Marra ◽  
Amanda Barbosa Lima ◽  
Wallans Torres Pio dos Santos ◽  
Rodrigo Alejandro Abarza Munoz ◽  
...  
Keyword(s):  
Simultaneous Determination ◽  
Amperometric Detection ◽  
Boron Doped Diamond ◽  
Diamond Electrode ◽  
Boron Doped ◽  
Boron Doped Diamond Electrode

scholarly journals A Comparative Analysis of 2-(Thiocyanomethylthio)-Benzothiazole Degradation Using Electro-Fenton and Anodic Oxidation on a Boron-Doped Diamond Electrode

2018 ◽  
Vol 2018 ◽  
pp. 1-9
Author(s):  
Armando Vázquez ◽  
Lucía Alvarado ◽  
Isabel Lázaro ◽  
Roel Cruz ◽  
José Luis Nava ◽  
...  
Keyword(s):  
Anodic Oxidation ◽  
Oxidation Process ◽  
Volumetric Flow Rate ◽  
Boron Doped Diamond ◽  
Aquatic Life ◽  
Diamond Electrode ◽  
Boron Doped ◽  
Boron Doped Diamond Electrode ◽  
Acidic Chloride ◽  
Anodic Oxidation Process

2-(Thiocyanomethylthio)-benzothiazole (TCMTB) is used as fungicide in the paper, tannery, paint, and coatings industries, and its study is important as it is considered toxic to aquatic life. In this study, a comparison of direct anodic oxidation (AO) using a boron-doped diamond electrode (BDD) and electro-Fenton (EF) processes for TCMTB degradation in acidic chloride and sulfate media using a FM01-LC reactor was performed. The results of the electrolysis processes studied in the FM01-LC reactor showed a higher degradation of TCMTB with the anodic oxidation process than with the electro-Fenton process, reaching 81% degradation for the former process versus 47% degradation for the latter process. This difference was attributed to the decrease in H2O2 during the EF process, due to parallel oxidation of chlorides. The degradation rate and current efficiency increased as a function of volumetric flow rate, indicating that convection promotes anodic oxidation and electro-Fenton processes. The results showed that both AO and EF processes could be useful strategies for TCMTB toxicity reduction in wastewaters.

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