Simultaneous Determination of Tyrosine and Histidine by Differential Pulse Cathodic Stripping Voltammetry Using H-point Standard Addition Method in Tap and Seawater

2009 ◽  
pp. NA-NA ◽  
Author(s):  
Mohsen Shahlaei ◽  
Mohammad Bagher Gholivand ◽  
Alireza Pourhossein
2009 ◽  
Vol 74 (7) ◽  
pp. 789-799 ◽  
Author(s):  
Karim Asadpour-Zeynali ◽  
Reza Majidi ◽  
Masoud Tahmasebpour

A novel net analyte signal standard addition method (NASSAM) is presented for the simultaneous determination of Cd2+ and Ni2+ in their mixture by differential pulse polarography. The method combines the advantages of the standard addition method with the net analyte signal concept, which enables the extraction of information concerning a certain analyte from voltammograms of multi-component mixtures. This method has some advantages, such as: the use of a full voltammogram, realization in a single step, therefore it does not require calibration and prediction steps and only a few measurements are required for the determination. The simultaneous determination of Cd2+ and Ni2+ was performed in Britton-Robinson buffer (pH 2.87) and 0.40 M potassium thiocyanate solution.


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