Efficient Catalysts In situ Generated from Zinc, Amide and Benzyl Bromide for Epoxide/CO2 Coupling Reaction at Atmospheric Pressure

2019 ◽  
Vol 2019 (6) ◽  
pp. 1311-1316 ◽  
Author(s):  
Shuai Zhang ◽  
Feng Han ◽  
Shaorui Yan ◽  
Mingyue He ◽  
Chengxia Miao ◽  
...  
Keyword(s):  
Atmospheric Pressure ◽  
Benzyl Bromide ◽  
Coupling Reaction

Innovative Closed-Cell Reactor Permits In Situ Heating and Gas Reactions with Atomic Resolution at Atmospheric Pressure

2012 ◽  
Vol 18 (S2) ◽  
pp. 1118-1119 ◽  
Author(s):  
L. Allard ◽  
S.H. Overbury ◽  
M.B. Katz ◽  
W.C. Bigelow ◽  
D. Nackashi ◽  
...  
Keyword(s):  
Atmospheric Pressure ◽  
Atomic Resolution ◽  
Closed Cell ◽  
Cell Reactor ◽  
In Situ Heating ◽  
Gas Reactions

Extended abstract of a paper presented at Microscopy and Microanalysis 2012 in Phoenix, Arizona, USA, July 29 – August 2, 2012.

Fabrication of covalently attached conducting multilayer self-assembly film of polyaniline by in situ coupling reaction

2002 ◽  
Vol 128 (3) ◽  
pp. 305-309 ◽  
Author(s):  
Yongjun Zhang ◽  
Ying Guan ◽  
Jin Liu ◽  
Jian Xu ◽  
Weixiao Cao
Keyword(s):  
Self Assembly ◽  
Coupling Reaction

scholarly journals Efficient in situ N-heterocyclic carbene palladium(ii) generated from Pd(OAc)2 catalysts for carbonylative Suzuki coupling reactions of arylboronic acids with 2-bromopyridine under inert conditions leading to unsymmetrical arylpyridine ketones: synthesis, characterization and cytotoxic activities

RSC Advances ◽  
2018 ◽  
Vol 8 (70) ◽  
pp. 40000-40015 ◽  
Author(s):  
Nedra Touj ◽  
Abdullah S. Al-Ayed ◽  
Mathieu Sauthier ◽  
Lamjed Mansour ◽  
Abdel Halim Harrath ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Suzuki Coupling ◽  
Boronic Acids ◽  
Cytotoxic Activities ◽  
Coupling Reactions ◽  
Component System ◽  
Arylboronic Acids ◽  
Cross Coupling Reaction

The in situ prepared four component system Pd(OAc)2, 1,3-dialkylbenzimidazolium halides 2a–i and 4a–i, K2CO3 under CO atmosphere catalyses carbonylative cross-coupling reaction of 2-bromopyridine with various boronic acids to yield unsymmetrical arylpyridine ketones.

An easily prepared palladium-hydrogel nanocomposite catalyst for C–C coupling reactions

2014 ◽  
Vol 2 (44) ◽  
pp. 18952-18958 ◽  
Author(s):  
Mitasree Maity ◽  
Uday Maitra
Keyword(s):  
Palladium Nanoparticles ◽  
Room Temperature ◽  
Coupling Reaction ◽  
Coupling Reactions ◽  
Sodium Cyanoborohydride ◽  
Efficient Catalyst ◽  
Suzuki Coupling Reaction ◽  
Reaction In Water ◽  
Hydrogel Nanocomposite

Palladium nanoparticles were efficiently prepared in situ by sodium cyanoborohydride reduction of Pd(ii) at room temperature using calcium-cholate hydrogel fibers as templates. The PdNPs self-organize on the gel fibers, which supports the controlled growth as well as stabilization of PdNPs. The hybrid xerogel was used as an efficient catalyst for the Suzuki coupling reaction in water.

scholarly journals A Novel Lithium Foil Cosmic-Ray Neutron Detector for Measuring Field-Scale Soil Moisture

2021 ◽  
Vol 3 ◽  
Author(s):  
Andres Patrignani ◽  
Tyson E. Ochsner ◽  
Benjamin Montag ◽  
Steven Bellinger
Keyword(s):  
Soil Moisture ◽  
Water Content ◽  
Atmospheric Pressure ◽  
Lower Cost ◽  
Cosmic Ray ◽  
Absolute Difference ◽  
Atmospheric Conditions ◽  
Volumetric Soil Water Content ◽  
The Mean

During the past decade, cosmic-ray neutron sensing technology has enabled researchers to reveal soil moisture spatial patterns and to estimate landscape-average soil moisture for hydrological and agricultural applications. However, reliance on rare materials such as helium-3 increases the cost of cosmic-ray neutron probes (CRNPs) and limits the adoption of this unique technology beyond the realm of academic research. In this study, we evaluated a novel lower cost CRNP based on moderated ultra-thin lithium-6 foil (Li foil system) technology against a commercially-available CRNP based on BF3 (boron trifluoride, BF-3 system). The study was conducted in a cropped field located in the Konza Prairie Biological Station near Manhattan, Kansas, USA (325 m a.s.l.) from 10 April 2020 to 18 June 2020. During this period the mean atmospheric pressure was 977 kPa, the mean air relative humidity was 70%, and the average volumetric soil water content was 0.277 m3 m−3. Raw fast neutron counts were corrected for atmospheric pressure, atmospheric water vapor, and incoming neutron flux. Calibration of the CRNPs was conducted using four intensive field surveys (n > 120), in combination with continuous observations from an existing array of in situ soil moisture sensors. The time series of uncorrected neutron counts of the Li foil system was highly correlated (r2 = 0.91) to that of the BF-3 system. The Li foil system had an average of 2,250 corrected neutron counts per hour with an uncertainty of 2.25%, values that are specific to the instrument size, detector configuration, and atmospheric conditions. The estimated volumetric water content from the Li foil system had a mean absolute difference of 0.022 m3 m−3 compared to the value from the array of in situ sensors. The new Li foil detector offers a promising lower cost alternative to existing cosmic-ray neutron detection devices used for hectometer-scale soil moisture monitoring.

Sign in / Sign up

Export Citation Format

Share Document